Structure factor and dynamics of the helix-coil transition

Thermodynamical properties of the helix-coil transition were successfully described in the past by the model of Lifson, Poland and Sheraga. Here we compute the corresponding structure factor and show that it possesses a universal scaling behavior near the transition point, even when the transition is of first order. Moreover, we introduce a dynamical version of this model, that we solve numerically. A Langevin equation is also proposed to describe the dynamics of the density of hydrogen bonds. Analytical solution of this equation shows dynamical scaling near the critical temperature and predicts a gelation phenomenon above the critical temperature. In the case when comparison of the two dynamical approaches is possible, the predictions of our phenomenological theory agree with the results of the Monte Carlo simulations.Comment: 11 pages, 7 figure

Correlation inequalities for noninteracting Bose gases

For a noninteracting Bose gas with a fixed one-body Hamiltonian H^0 independent of the number of particles we derive the inequalities _N < _{N+1}, _N _N _N for i\neq j, \partial _N/\partial \beta >0 and ^+_N _N. Here N_i is the occupation number of the ith eigenstate of H^0, \beta is the inverse temperature and the superscript + refers to adding an extra level to those of H^0. The results follow from the convexity of the N-particle free energy as a function of N.Comment: a further inequality adde