Antiferromagnetism in EuCu2As2 and EuCu1.82Sb2 Single Crystals

Single crystals of EuCu2As2 and EuCu2Sb2 were grown from CuAs and CuSb self-flux, respectively. The crystallographic, magnetic, thermal and electronic transport properties of the single crystals were investigated by room-temperature x-ray diffraction (XRD), magnetic susceptibility \chi versus temperature T, isothermal magnetization M versus magnetic field H, specific heat Cp(T) and electrical resistivity \rho(T) measurements. EuCu2As2 crystallizes in the body-centered tetragonal ThCr2Si2-type structure (space group I4/mmm), whereas EuCu2Sb2 crystallizes in the related primitive tetragonal CaBe2Ge2-type structure (space group P4/nmm). The energy-dispersive x-ray spectroscopy and XRD data for the EuCu2Sb2 crystals showed the presence of vacancies on the Cu sites, yielding the actual composition EuCu1.82Sb2. The \rho(T) and Cp(T) data reveal metallic character for both EuCu2As2 and EuCu1.82Sb2. Antiferromagnetic (AFM) ordering is indicated from the \chi(T), Cp(T), and \rho(T) data for both EuCu2As2 (T_N = 17.5 K) and EuCu1.82Sb2 (T_N = 5.1 K). In EuCu1.82Sb2, the ordered-state \chi(T) and M(H) data suggest either a collinear A-type AFM ordering of Eu+2 spins S=7/2 or a planar noncollinear AFM structure, with the ordered moments oriented in the tetragonal ab plane in either case. This ordered-moment orientation for the A-type AFM is consistent with calculations with magnetic dipole interactions. The anisotropic \chi(T) and isothermal M(H) data for EuCu2As2, also containing Eu+2 spins S=7/2, strongly deviate from the predictions of molecular field theory for collinear AFM ordering and the AFM structure appears to be both noncollinear and noncoplanar.Comment: 21 pages, 22 figures, 4 Table

Metallic behavior induced by potassium doping of the trigonal antiferromagnetic insulator EuMn2As2

We report magnetic susceptibility \chi, isothermal magnetization M, heat capacity C_p and electrical resistivity \rho measurements on undoped EuMn2As2 and K-doped Eu0.96K0.04Mn2As2 and Eu0.93K0.07Mn2As2 single crystals with the trigonal CaAl2Si2-type structure as a function of temperature T and magnetic field H. EuMn2As2 has an insulating ground state with an activation energy of 52 meV and exhibits antiferromagnetic (AFM) ordering of the Eu+2 spins S=7/2 at T_N1 = 15 K from C_p(T) and \chi(T) data with a likely spin-reorientation transition at T_N2 = 5.0 K. The Mn+2 3d5 spins-5/2 exhibit AFM ordering at T_N = 142 K from all three types of measurements. The M(H) isotherm and \chi(T) data indicate that the Eu AFM structure is both noncollinear and noncoplanar. The AFM structure of the Mn spins is also unclear. A 4% substitution of K for Eu in Eu0.96K0.04Mn2As2 is sufficient to induce a metallic ground state. Evidence is found for a difference in the AFM structure of the Eu moments in the metallic crystals from that of undoped EuMn2As2 versus both T and H. For metallic Eu0.96K0.04Mn2As2 and Eu0.93K0.07Mn2As2, an anomalous S-shape T dependence of \rho related to the Mn magnetism is found. Upon cooling from 200 K, \rho exhibits a strong negative curvature, reaches maximum positive slope at the Mn T_N ~ 150 K, and then continues to decrease but more slowly below T_N. This suggests that dynamic short-range AFM order of the Mn spins above the Mn T_N strongly suppresses the resistivity, contrary to the conventional decrease of \rho that is only observed upon cooling below T_N of an antiferromagnet.Comment: 21 pages, 22 figures, 4 Table

Physical properties of EuPd2As2 single crystals

The physical properties of self-flux grown EuPd2As2 single crystals have been investigated by magnetization M, magnetic susceptibility chi, specific heat Cp, and electrical resistivity rho measurements versus temperature T and magnetic field H. The crystal structure was determined by powder x-ray diffraction measurements, which confirmed the ThCr2Si2-type body-centered tetragonal structure (space group I4/mmm) reported previously. The rho(T) data indicate that state of EuPd2As2 is metallic. Long-range antiferromagnetic (AFM) ordering is apparent from the chi(T), Cp(T), and rho(T) measurements. For H \parallel c the chi(T) indicates two transitions at TN1 = 11.0 K and TN2 = 5.5 K, whereas for H \perp c only one transition is observed at TN1 = 11.0 K. Between TN1 and TN2 the anisotropic chi(T) data suggest a planar noncollinear AFM structure, whereas at T < TN2 the chi(T) and M(H,T) data suggest a spin reorientation transition in which equal numbers of spins cant in opposite directions out of the ab plane. We estimate the critical field at 2 K at which all Eu moments become aligned with the field to be about 22 T. The magnetic entropy at 25 K estimated from the Cp(T) measurements is about $11\%$ smaller than expected, possibly due to an inaccuracy in the lattice heat capacity contribution. An upturn in rho at T < TN1 suggests superzone energy gap formation below TN1. This behavior of rho(T < TN1) is not sensitive to applied magnetic fields up to H = 12 T.Comment: 11 pages, 10 figures, 2 tables and 52 references; To appear in J. Phys.: Condens. Matte

Investigations of the effect of nonmagnetic Ca substitution for magnetic Dy on spin-freezing in Dy2Ti2O7

Physical properties of partially Ca substituted hole-doped Dy2Ti2O7 have been investigated by ac magnetic susceptibility \chi_ac(T), dc magnetic susceptibility \chi(T), isothermal magnetization M(H) and heat capacity C_p(T) measurements on Dy1.8Ca0.2Ti2O7. The spin-ice system Dy2Ti2O7 exhibits a spin-glass type freezing behavior near 16 K. Our frequency dependent \chi_ac(T) data of Dy1.8Ca0.2Ti2O7 show that the spin-freezing behavior is significantly influenced by Ca substitution. The effect of partial nonmagnetic Ca2+ substitution for magnetic Dy3+ is similar to the previous study on nonmagnetic isovalent Y3+ substituted Dy2-xYxTi2O7 (for low levels of dilution), however the suppression of spin-freezing behavior is substantially stronger for Ca than Y. The Cole-Cole plot analysis reveals semicircular character and a single relaxation mode in Dy1.8Ca0.2Ti2O7 as for Dy2Ti2O7. No noticeable change in the insulating behavior of Dy2Ti2O7 results from the holes produced by 10% Ca2+ substitution for Dy3+ ions.Comment: 9 pages, 7 figures, 1 tabl

Elliptic supersonic jet morphology manipulation using sharp-tipped lobes

Elliptic nozzle geometry is attractive for mixing enhancement of supersonic jets. However, jet dynamics, such as flapping, gives rise to high-intensity tonal sound. We experimentally manipulate the supersonic elliptic jet morphology by using two sharp-tipped lobes. The lobes are placed on either end of the minor axis in an elliptic nozzle. The design Mach number and the aspect ratio of the elliptic nozzle and the lobed nozzle are 2.0 and 1.65. The supersonic jet is exhausted into ambient at almost perfectly expanded conditions. Time-resolved schlieren imaging, longitudinal and cross-sectional planar laser Mie-scattering imaging, planar Particle Image Velocimetry, and near-field microphone measurements are performed to assess the fluidic behavior of the two nozzles. Dynamic Mode and Proper Orthogonal Decomposition (DMD and POD) analysis are carried out on the schlieren and the Mie-scattering images. Mixing characteristics are extracted from the Mie-scattering images through the image processing routines. The flapping elliptic jet consists of two dominant DMD modes, while the lobed nozzle has only one dominant mode, and the flapping is suppressed. Microphone measurements show the associated noise reduction. The jet column bifurcates in the lobed nozzle enabling a larger surface contact area with the ambient fluid and higher mixing rates in the near-field of the nozzle exit. The jet width growth rate of the two-lobed nozzle is about twice as that of the elliptic jet in the near-field, and there is a 40\% reduction in the potential core length. Particle Image Velocimetry (PIV) contours substantiate the results.Comment: 19 pages, 16 figures. Revised version submitted to Physics of Fluids for peer review. URL of the Video files (Fig. 6 & Fig. 14) are given in the text files (see in '/anc/*.txt'

A Prolific Scheme for Load Balancing Relying on Task Completion Time

In networks with lot of computation, load balancing gains increasing significance. To offer various resources, services and applications, the ultimate aim is to facilitate the sharing of services and resources on the network over the Internet. A key issue to be focused and addressed in networks with large amount of computation is load balancing. Load is the number of tasks‘t’ performed by a computation system. The load can be categorized as network load and CPU load. For an efficient load balancing strategy, the process of assigning the load between the nodes should enhance the resource utilization and minimize the computation time. This can be accomplished by a uniform distribution of load of to all the nodes. A Load balancing method should guarantee that, each node in a network performs almost equal amount of work pertinent to their capacity and availability of resources. Relying on task subtraction, this work has presented a pioneering algorithm termed as E-TS (Efficient-Task Subtraction). This algorithm has selected appropriate nodes for each task. The proposed algorithm has improved the utilization of computing resources and has preserved the neutrality in assigning the load to the nodes in the network