Application of MFI-UF fouling index with NOM fouling under various operating conditions

Fouling research with polymeric membranes has demonstrated that various natural organic matter (NOM) fractions contribute differentially to membrane fouling behavior. However, limited studies exist analyzing the sensitivity of the MFI-UF to be used as a tool to differentiate NOM fouling components. The results here indicate that MFI-UF is a suitable tool for assessing NOM fouling. Specifically, NOM fouling potential was in the order of organic proteins (as BSA), polymers (alginate), and humic acid, respectively. Further, a mixed solution containing BSA, alginate and humic acid fouled similarly to the BSA solution indicating the high fouling potential of organic proteins in membrane systems. The MFI-UF value was found to increase by > 30% with increasing pressure (1–3 bar) and decreasing temperature (35°C–5°C). The filtered water volume was found to correlate with the MFI-UF values indicating the dependency of the method on testing conditions. Incorporating water viscosity and pressure values against normalized conditions (20°C and 2 bar) with the standard MFI-UF equation was found to be useful to estimate MFI-UF values at variable operating conditions, thus, enhances the potential application range of MFI-UF as a fouling index for NOM

Effects of feed water temperature on irreversible fouling of ceramic ultrafiltration membranes

Temperature is known to influence the filtration performance of membrane systems through its direct impact on water viscosity. This research demonstrates that the changes in natural organic matter (NOM) fouling behavior with temperature are over and beyond simple viscosity changes in water. Constant flux experiments were performed in a tubular ceramic ultrafiltration (UF) system at 5, 20, and 35 °C. The unified membrane fouling index (UMFI) was used to identify NOM reversible and irreversible fouling mechanisms; while the modified UF fouling index (MFI-UF) was used to predict the fouling potential of NOM. The results showed that after correcting for viscosity to standard 20 °C compared to 5 °C, UMFI values were higher than expected and reflected the higher fouling irreversibility observed at the lower temperature. The lower water temperature resulted in an increase in NOM retention along with decrease in backwash and chemical cleaning effectiveness as determined by the UMFI and FEEM analyses. However, increased water temperature did not adversely impact existing backwash or chemical cleaning protocols. In addition, The MFI-UF exhibited the same trend as UMFI for establishing NOM fouling and retention, and therefore, the MFI-UF method is suitable for use as fouling predictor with ceramic membrane systems

Comparisons of NOM fouling and cleaning of ceramic and polymeric membranes during water treatment

This research examines the effect of various NOM fractions on ceramic and polymeric UF membranes performance in terms of fouling and cleaning. Fouling experiments were performed using five model solutions, humic acid, protein as bovine serum albumin (BSA), alginate with and without calcium, and a combined NOM mixture. Two chemical agents were selected: an oxidant (NaOCl) and caustic (NaOH). Fouling and cleaning behavior were assessed using the resistance in series (RIS) model, membrane permeability, carbon mass balance, and fluorescence excitation and emission matrix (FEEM) analysis. The results demonstrated that NOM fouling order of the ceramic UF was similar to polymeric UF with the following trend: NOM mixture ≈BSA > alginate ±Ca+2 > humic acid. However, the backwash efficiency was 1.5×–2× higher for the ceramic UF in comparison to the polymeric UF, indicating a much higher hydraulic reversibility for the ceramic UF. A carbon mass balance in compliment with FEEM plots determined that NOM removal by the ceramic UF was ≈ 10% higher than the polymeric UF. Chemical cleaning was found to be effective for both membrane types. Thus, it was not possible to conclude, that the ceramic membrane demonstrated an advantage for chemical cleaning under the conditions studied

Chemical cleaning of ceramic ultrafiltration membranes – Ozone versus conventional cleaning chemicals

This study investigates chemical cleaning mechanisms of a tubular ceramic UF membrane. The effect of cleaner type (ozone (O 3 ), sodium hypochlorite (NaOCl) and sodium hydroxide (NaOH)), clean in place (CIP) pH (11 vs. 12), and cleaning sequence on the removal of irreversible fouling of hydrophobic (humic acids) and hydrophilic (alginate with and without calcium (alginate + Ca +2 and alginate - Ca +2 , respectively)) NOM fractions were investigated. Results showed that different NOM types responded differently to chemical cleaning. Alginate-Ca +2 and humic acids were equivalently removed by NaOCl or NaOH whereas a lower cleaning efficiency of alginate + Ca +2 was observed. Increasing the pH of NaOCl and NaOH CIP increased the removal of the chemically reversible fouling index (UMFI cr ). The efficiency of NaOCl was always lower than that of NaOH at the same pH, which was attributed to surface tension (λ) differences in the CIP water and potential differences in cleaning mechanism. The ceramic UF CIP cleaning using O 3 (0.50 mg O 3 /mgC) for 1 h demonstrated higher cleaning efficiency for humic acids and alginate ± Ca +2 , (%UMFI cr > 98%), than NaOCl or NaOH alone (%UMFI cr >80%). The O 3 CIP was as effective as 4 h cleaning using a sequential NaOH/NaOCl or combined NaOCl + NaOH CIP