Charge Transport and Quantum Phase Transitions in Singlet Superconductor - Ferromagnet - Singlet Superconductor Junctions

We study the Josephson current, I_J, in a junction consisting of two s-wave superconductors that are separated by a ferromagnetic barrier possessing a magnetic and non-magnetic scattering potential, g and Z, respectively. We discuss the general dependence of I_J on g, Z, and the phase difference \phi between the two superconductors. Moreover, we compute the critical current, I_c for given g and Z, and show that it possesses two lines of non-analyticity in the (g, Z)-plane. We identify those regions in the (g, Z)-plane where the Josephson current changes sign with increasing temperature without a change in the relative phase between the two superconductors, i.e., without a transition between a 0 and \pi state of the junction. Finally, we show that by changing the relative phase \phi, it is possible to tune the junction through a first-order quantum phase transition in which the spin polarization of the two superconductors' combined ground state changes from =0 to =1/2.Comment: final version, published in Phys. Rev.

Diffusion based degradation mechanisms in giant magnetoresistive spin valves

Spin valve systems based on the giant magnetoresistive (GMR) effect as used for example in hard disks and automotive applications consist of several functional metallic thin film layers. We have identified by secondary ion mass spectrometry (SIMS) two main degradation mechanisms: One is related to oxygen diffusion through a protective cap layer, and the other one is interdiffusion directly at the functional layers of the GMR stack. By choosing a suitable material as cap layer (TaN), the oxidation effect can be suppressed.Comment: 3 pages, 3 figures. to be published in Appl. Phys. Let

Controlled oxygen vacancy induced p-type conductivity in HfO{2-x} thin films

We have synthesized highly oxygen deficient HfO$_{2-x}$ thin films by controlled oxygen engineering using reactive molecular beam epitaxy. Above a threshold value of oxygen vacancies, p-type conductivity sets in with up to 6 times 10^{21} charge carriers per cm3. At the same time, the band-gap is reduced continuously by more than 1 eV. We suggest an oxygen vacancy induced p-type defect band as origin of the observed behavior.Comment: 4 pages, 3 figure

{001}-textured Pb(Zr, Ti)O₃ thin films on stainless steel by pulsed laser deposition

In this work, we report nearly single oriented {001}-textured ferroelectric PbZr0.52Ti0.48O3 thin films grown by pulsed laser deposition onto AISI 304 stainless steel substrates. Pt, Al2O3, and LaNiO3 buffer layers promote the PbZr0.52Ti0.48O3 {001} texture and protect the substrate against oxidation during deposition. The dominant {001} texture of the PbZr0.52Ti0.48O3 layer was confirmed using x-ray and electron backscatter diffraction. Before poling, the films exhibit a permittivity of about 350 at 1 kHz and a dielectric loss below 5%. The films display a remanent polarization of about 16.5 μC cm⁻² and a high coercive field of up to Ec ¼ 135.9 kV cm⁻¹. The properties of these PbZr0.52Ti0.48O3 thin films on stainless steel are promising for various MEMS applications such as transducers or energy harvesters

The importance of self-consistency in determining interface properties of S-I-N and D-I-N structures

We develop a method to solve the Bogoliubov de Gennes equation for superconductors self-consistently, using the recursion method. The method allows the pairing interaction to be either local or non-local corresponding to $s$ and $d$--wave superconductivity, respectively. Using this method we examine the properties of various $S-I-N$ and $D-I-N$ interfaces. In particular we self-consistently calculate the spatially varying density of states and the superconducting order parameter. We see that changing the strength of the insulating barrier, at the interface, does not, in the case of an $s$--wave superconductor, dramatically, change the low energy local density of states, in the superconducting region near the interface. This is in stark contrast to what we see in the case of a $D-I-N$ interface where the local particle density of states is changed dramatically. Hence we deduce that in calculating such properties as the conductance of $S-I-N$ and $D-I-N$ structures it is far more important to carry out a self-consistent calculations in the $d$--wave case.Comment: 14 pages, 8 figures, submitted to special issue of "Superlattices and Microstructures

Optical Properties of Highly Conductive SrMoO₃ Oxide Thin Films in the THz Band and Beyond

Strontium molybdate (SrMoO₃) thin films are grown epitaxially by pulsed laser deposition onto gadolinium scandate (GdScO₃) substrates and characterized in the terahertz (THz) and visible part of the electromagnetic spectrum. X-ray diffraction measurements prove a high crystallinity and phase-pure growth of the thin films. The high-quality SrMoO₃ thin films feature a room temperature DC conductivity of around 3 1/μΩm. SrMoO₃ is characterized in the THz frequency range by time domain spectroscopy. The resulting AC conductivity is in excellent agreement with the DC value. A Lorentz-Drude oscillator approach models the THz and visible conductivity of SrMoO₃ very well. We compare the results of the SrMoO₃ thin films to a standard, sputtered gold film, with a resulting THz conductivity of 8 1/μΩm. The comparison demonstrates that oxide thin film–based devices can play an important role in future THz technology

On the origin of incoherent magnetic exchange coupling in MnBi/Fex_xCo1−x_{1-x} bilayer system

In this study we investigate the exchange coupling between the hard magnetic compound MnBi and the soft magnetic alloy FeCo including the interface structure between the two phases. Exchange spring MnBi-Fe$_x$Co$_{1-x}$ (x = 0.65 and 0.35) bilayers with various thicknesses of the soft magnetic layer were deposited onto quartz glass substrates in a DC magnetron sputtering unit from alloy targets. Magnetic measurements and density functional theory (DFT) calculations reveal that a Co-rich FeCo layer leads to more coherent exchange coupling. The optimum soft layer thickness is about 1 nm. In order to take into account the effect of incoherent interfaces with finite roughness, we have combined a cross-sectional High Resolution Transmission Electron Microscopy (HR-TEM) analysis with DFT calculations and micromagnetic simulations. The experimental results can be consistently described by modeling assuming a polycrystalline FeCo layer consisting of crystalline (110) and amorphous grains as confirmed by HR-TEM. The micromagnetic simulations show in general how the thickness of the FeCo layer and the interface roughness between the hard and soft magnetic phases both control the effectiveness of exchange coupling in an exchange spring system

Impact of Non‐Stoichiometric Phases and Grain Boundaries on the Nanoscale Forming and Switching of HfOₓ Thin Films

HfO₂ is one of the most common memristive materials and it is widely accepted that oxygen vacancies are prerequisite to reduce the forming voltage of the respective memristive devices. Here, a series of six oxygen engineered substoichiometric HfO₂₋ₓ thin films with varying oxygen deficiency is investigated by conductive atomic force microscopy (c‐AFM) and the switching process of substoichiometric films is observed on the nanoscale. X‐ray diffractometry (XRD) exhibits a phase transition from stoichiometric, monoclinic HfO₂ toward oxygen deficient, rhombohedral HfO₁.₇. The conductance of HfO₂₋ₓ is increasing with increasing oxygen deficiency, which is consistent with the increasing prevalence of the highly conductive rhombohedral phase. Simultaneously, c‐AFM reveals significant local conductivity differences between grains and grain boundaries, regardless of the level of oxygen deficiency. Single grains of highly oxygen deficient samples are formed at significant lower voltages. The mean forming voltage is reduced from (7.0 ± 0.6) V for HfO₂ to (1.9 ± 0.8) V for HfO₁.₇. Resistive switching on the nanoscale is established for single grains for the highest deficient thin film samples. The final resistance state is thereby dependent on the initial conductivity of the grains. These studies offer valuable insights into the switching behavior of memristive polycrystalline HfO₂

Gradual reset and set characteristics in yttrium oxide based resistive random access memory

This paper addresses the resistive switching behavior in yttrium oxide based resistive random access memory (RRAM) (TiN/yttrium oxide/Pt) devices. We report the coexistence of bipolar and unipolar resistive switching within a single device stack. For bipolar DC operation, the devices show gradual set and reset behavior with resistance ratio up to two orders of magnitude. By using nanosecond regime pulses (20 to 100 ns pulse width) of constant voltage amplitude, this gradual switching behavior could be utilized in tuning the resistance during set and reset spanning up to two orders of magnitude. This demonstrates that yttrium oxide based RRAM devices are alternative candidates for multibit operations and neuromorphic applications