Design of a Large Deployable Reflector Opening System

Large Deployable Reflectors (LDR) are receiving considerable attention from aerospace government companies and researchers. In this paper, the design of the opening system of a LDR is presented. Starting from an elementary cell, a first ideal kinematic model is discussed. Then, a more complex “design model” including feasible design solutions for joints and links is developed. The final design avoids collisions between links while maintaining the original kinematic features

Bis(oxalato)borate and difluoro(oxalato)borate-based ionic liquids as electrolyte additives to improve the capacity retention in high voltage lithium batteries

Two ionic liquids (ILs), which are functionalized with bis(oxalato)borate (BOB) and difluoro(oxalato)borate (DFOB) as the anion, have been synthesized and applied as additives for the battery grade electrolyte 1 M LiPF6 in an equivolume mixture of EC-DEC-DMC (LP71). When 0.3 M IL was added to LP71,peaks attributed to the formation of solid electrolyte interface (SEI) were observed during cyclic voltammetry for both cathodic and anodic sides. The presence of peaks during anodic scans suggests thatthe ILs possess the ability to form SEI on cathode surfaces. The high voltage LiNi0.5Mn1.5O4 (LNMO) cells, employing the integrated electrolytes, exhibited a discharge capacity of around 120 mAh g-1. The retention rates of discharge capacity after 100 cycles were found to be 99.2% and 98.1% for the solution with 0.3 M of BOB-IL and DFOB-IL, respectively. By means of impedance analysis during the galvanostatic cycling, the growth of SEI was confirmed when BOB-IL was used as the additive. In this case, in the infrared spectra of the cycled LNMO electrodes, peaks related to borate compounds and polycarbonate were observed. This confirms that the BOB-IL promotes the formation of stable interfaces between the electrolyte and LNMO