Pressure exerted by a vesicle on a surface

Several recent works have considered the pressure exerted on a wall by a model polymer. We extend this consideration to vesicles attached to a wall, and hence include osmotic pressure. We do this by considering a two-dimensional directed model, namely that of area-weighted Dyck paths. Not surprisingly, the pressure exerted by the vesicle on the wall depends on the osmotic pressure inside, especially its sign. Here, we discuss the scaling of this pressure in the different regimes, paying particular attention to the crossover between positive and negative osmotic pressure. In our directed model, there exists an underlying Airy function scaling form, from which we extract the dependence of the bulk pressure on small osmotic pressures.Comment: 10 pages, 7 figure

Pseudo-First-Order Transition in Interacting Self-avoiding Walks and Trails

The coil-globule transition of an isolated polymer has been well established to be a second-order phase transition described by a standard tricritical O(0) field theory. We present Monte-Carlo simulations of interacting self-avoiding walks and interacting self-avoiding trails in four dimensions which provide compelling evidence that the approach to this (tri)critical point is dominated by the build-up of first-order-like singularities masking the second-order nature of the coil-globule transition.Comment: 4 pages with 2 figures included, CCP2001 submissio