Near-field thermal upconversion and energy transfer through a Kerr medium : Theory

We present an approach for achieving large Kerr $\chi^{(3)}$--mediated thermal energy transfer at the nanoscale that exploits a general coupled-mode description of triply resonant, four-wave mixing processes. We analyze the efficiency of thermal upconversion and energy transfer from mid- to near-infrared wavelengths in planar geometries involving two slabs supporting far-apart surface plasmon polaritons and separated by a nonlinear $\chi^{(3)}$ medium that is irradiated by externally incident light. We study multiple geometric and material configurations and different classes of interveening mediums---either bulk or nanostructured lattices of nanoparticles embedded in nonlinear materials---designed to resonantly enhance the interaction of the incident light with thermal slab resonances. We find that even when the entire system is in thermodynamic equilibrium (at room temperature) and under typical drive intensities $\sim\mathrm{W}/\mu\mathrm{m}^2$, the resulting upconversion rates can approach and even exceed thermal flux rates achieved in typical symmetric and non-equilibrium configurations of vacuum-separated slabs. The proposed nonlinear scheme could potentially be exploited to achieve thermal cooling and refrigeration at the nanoscale, and to actively control heat transfer between materials with dramatically different resonant responses

Thermal bistability through coupled photonic resonances

We present a scheme for achieving thermal bistability based on the selective coupling of three optical resonances. This approach requires one of the resonant frequencies to be temperature dependent, which can occur in materials exhibiting strong thermo-optic effects. For illustration, we explore thermal bistability in two different passive systems, involving either a periodic array of Si ring resonators or parallel GaAs thin films separated by vacuum and exchanging heat in the near field. Such a scheme could prove useful for thermal memory devices operating with transition times $\lesssim$ hundreds of milliseconds

Enhanced nonlinear frequency conversion and Purcell enhancement at exceptional points

We derive analytical formulas quantifying radiative emission from subwavelength emitters embedded in triply resonant nonlinear $\chi^{(2)}$ cavities supporting exceptional points (EP) made of dark and leaky modes. We show that the up-converted radiation rate in such a system can be greatly enhanced---by up to two orders of magnitude---compared to typical Purcell factors achievable in non-degenerate cavities, for both monochromatic and broadband emitters. We provide a proof-of-concept demonstration by studying an inverse-designed 2D photonic-crystal slab that supports an EP formed out of a Dirac cone at the emission frequency and a phase-matched, leaky-mode resonance at the second harmonic frequency

Radiative heat transfer in nonlinear Kerr media

We obtain a fluctuation--dissipation theorem describing thermal electromagnetic fluctuation effects in nonlinear media that we exploit in conjunction with a stochastic Langevin framework to study thermal radiation from Kerr ($\chi^{(3)}$) photonic cavities coupled to external environments at and out of equilibrium. We show that that in addition to thermal broadening due to two-photon absorption,the emissivity of such cavities can exhibit asymmetric,non-Lorentzian lineshapes due to self-phase modulation. When the local temperature of the cavity is larger than that of the external bath, we find that the heat transfer into the bath exceeds the radiation from a corresponding linear black body at the same local temperature. We predict that these temperature-tunable thermal processes can be observed in practical, nanophotonic cavities operating at relatively small temperatures

Fluctuational Electrodynamics in Atomic and Macroscopic Systems: van der Waals Interactions and Radiative Heat Transfer

We present an approach to describing fluctuational electrodynamic (FED) interactions, particularly van der Waals (vdW) interactions as well as radiative heat transfer (RHT), between material bodies of vastly different length scales, allowing for going between atomistic and continuum treatments of the response of each of these bodies as desired. Any local continuum description of electromagnetic (EM) response is compatible with our approach, while atomistic descriptions in our approach are based on effective electronic and nuclear oscillator degrees of freedom, encapsulating dissipation, short-range electronic correlations, and collective nuclear vibrations (phonons). While our previous works using this approach have focused on presenting novel results, this work focuses on the derivations underlying these methods. First, we show how the distinction between "atomic" and "macroscopic" bodies is ultimately somewhat arbitrary, as formulas for vdW free energies and RHT look very similar regardless of how the distinction is drawn. Next, we demonstrate that the atomistic description of material response in our approach yields EM interaction matrix elements which are expressed in terms of analytical formulas for compact bodies or semianalytical formulas based on Ewald summation for periodic media; we use this to compute vdW interaction free energies as well as RHT powers among small biological molecules in the presence of a metallic plate as well as between parallel graphene sheets in vacuum, showing strong deviations from conventional macroscopic theories due to the confluence of geometry, phonons, and EM retardation effects. Finally, we propose formulas for efficient computation of FED interactions among material bodies in which those that are treated atomistically as well as those treated through continuum methods may have arbitrary shapes, extending previous surface-integral techniques.Comment: 25 pages, 5 figures, 2 appendice

Thermal radiation from optically driven Kerr (χ(3)\chi^{(3)}) photonic cavities

We study thermal radiation from nonlinear ($\chi^{(3)}$) photonic cavities coupled to external channels and subject to incident monochromatic light. Our work extends related work on nonlinear mechanical oscillators [Phys. Rev. Lett. 97, 110602 (2006)] to the problem of thermal radiation, demonstrating that bistability can enhance thermal radiation by orders of magnitude and result in strong lineshape alternations, including "super-narrow spectral peaks" occurring at the onset of kinetic phase transitions. We show that when the cavities are designed so as to have perfect linear absorptivity (rate matching), such thermally activated transitions can be exploited to dramatically tune the output power and radiative properties of the cavity, leading to a kind of Kerr-mediated thermo-optic effect. Finally, we demonstrate that in certain parameter regimes, the output radiation exhibits Stokes and anti-Stokes side peaks whose relative magnitudes can be altered by tuning the internal temperature of the cavity relative to its surroundings, a consequence of strong correlations and interference between the emitted and reflected radiation

Near-field refrigeration and tunable heat exchange through four-wave mixing

We modify and extend a recently proposed four-wave mixing scheme [Opt. Express 25 (19),23164 (2017)] for achieving near-field thermal upconversion and energy transfer, to demonstrate efficient thermal refrigeration at low intensities $\sim 10^{-9}$W/m$^2$ over a wide range of gap sizes (from tens to hundreds of nanometers) and operational temperatures (from tens to hundreds of Kelvins). We further exploit the scheme to achieve magnitude and directional tunability of near-field heat exchange between bodies held at different temperatures

Temperature control of thermal radiation from heterogeneous bodies

We demonstrate that recent advances in nanoscale thermal transport and temperature manipulation can be brought to bear on the problem of tailoring thermal radiation from compact emitters. We show that wavelength-scale composite bodies involving complicated arrangements of phase-change chalcogenide (GST) glasses and metals or semiconductors can exhibit large emissivities and partial directivities at mid-infrared wavelengths, a consequence of temperature localization within the GST. We consider multiple object topologies, including spherical, cylindrical, and mushroom-like composites, and show that partial directivity follows from a complicated interplay between particle shape, material dispersion, and temperature localization. Our calculations exploit a recently developed fluctuating-volume current formulation of electromagnetic fluctuations that rigorously captures radiation phenomena in structures with both temperature and dielectric inhomogeneities.Comment: 17 pages, 7 figuer