Semitransparent Perovskite Solar Cells with Ultrathin Protective Buffer Layers

Semitransparent perovskite solar cells (ST-PSCs) are increasingly important in a range of applications, including top cells in tandem devices and see-through photovoltaics. Transparent conductive oxides (TCOs) are commonly used as transparent electrodes, with sputtering being the preferred deposition method. However, this process can damage exposed layers, affecting the electrical performance of the devices. In this study, an indium tin oxide (ITO) deposition process that effectively suppresses sputtering damage was developed using a transition metal oxides (TMOs)-based buffer layer. An ultrathin (<10 nm) layer of evaporated vanadium oxide or molybdenum oxide was found to be effective in protecting against sputtering damage in ST-PSCs for tandem applications, as well as in thin perovskite-based devices for building-integrated photovoltaics. The identification of minimal parasitic absorption, the high work function and the analysis of oxygen vacancies denoted that the TMO layers are suitable for use in ST-PSCs. The highest fill factor (FF) achieved was 76%, and the efficiency (16.4%) was reduced by less than 10% when compared with the efficiency of gold-based PSCs. Moreover, up-scaling to 1 cm2-large area ST-PSCs with the buffer layer was successfully demonstrated with an FF of ∼70% and an efficiency of 15.7%. Comparing the two TMOs, the ST-PSC with an ultrathin V2Ox layer was slightly less efficient than that with MoOx, but its superior transmittance in the near infrared and greater light-soaking stability (a T80 of 600 h for V2Ox compared to a T80 of 12 h for MoOx) make V2Ox a promising buffer layer for preventing ITO sputtering damage in ST-PSCs

Enhancing Photovoltaic Performance of Hybrid Perovskite Solar Cells Utilizing GaP Nanowires

GaP-based nanomaterials is a powerful tool for modern optoelectronic device fabrication owing to their excellent electrophysical properties, low optical losses, light localization, and optimal thermal conductivity. In our work, we incorporate GaP nanowires into perovskite solar cells to improve charge extraction from a perovskite layer without changing a total solar cell thickness. As a result, we improve the MAPbI3 perovskite solar cell efficiency up to 18.8% by VOC and JSC enhancement. The provided multiphysical theoretical simulations of the solar cells with the incorporated GaP nanowires describe the mechanism of charge extraction and optical absorption improvement. The developed method can be employed in various thin-film solar cells with different compositions of active material, as well as in other optoelectronic devices