33 research outputs found

    The generalized Clapeyron equation and its application to confined ice growth

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    Most theoretical descriptions of stresses induced by freezing are rooted in the (generalized) Clapeyron equation, which predicts the pressure that a solid can exert as it cools below its melting temperature. This equation is central for topics ranging beyond glaciology to geomorphology, civil engineering, food storage, and cryopreservation. However, it has inherent limitations, requiring isotropic solid stresses and conditions near bulk equilibrium. Here, we examine when the Clapeyron equation is applicable by providing a rigorous derivation that details all assumptions. We demonstrate the natural extension for anisotropic stress states, and we show how the temperature and pressure ranges for validity depend on well-defined material properties. Finally, we demonstrate how the range of applicability of the (linear) Clapeyron equation can be extended by adding higher-order terms, yielding results that are in good agreement with experimental data for the pressure melting of ice.Comment: 2 Figure

    Topographic signatures and a general transport law for deep-seated landslides in a landscape evolution model

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    A fundamental goal of studying earth surface processes is to disentangle the complex web of interactions among baselevel, tectonics, climate, and rock properties that generate characteristic landforms. Mechanistic geomorphic transport laws can quantitatively address this goal, but no widely accepted law for landslides exists. Here we propose a transport law for deep-seated landslides in weathered bedrock and demonstrate its utility using a two-dimensional numerical landscape evolution model informed by study areas in the Waipaoa catchment, New Zealand, and the Eel River catchment, California. We define a non-dimensional landslide number, which is the ratio of the horizontal landslide flux to the vertical tectonic flux, that characterizes three distinct landscape types. One is dominated by stochastic landsliding, whereby discrete landslide events episodically erode material at rates exceeding the long-term uplift rate. Another is characterized by steady landsliding, in which the landslide flux at any location remains constant through time and is greatest at the steepest locations in the catchment. The third is not significantly affected by landsliding. In both the “stochastic landsliding” and “steady landsliding” regimes, increases in the non-dimensional landslide number systematically reduce catchment relief and widen valley spacing, producing long, low angle hillslopes despite high uplift rates. The stochastic landsliding regime captures the frequent observation that deep-seated landslides produce large sediment fluxes from small areal extents while being active only a fraction of the time. We suggest that this model is adaptable to a wide range of geologic settings and is useful for interpreting climate-driven changes in landslide behavior

    Frost for the trees: Did climate increase erosion in unglaciated landscapes during the late Pleistocene?

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    Understanding climatic influences on the rates and mechanisms of landscape erosion is an unresolved problem in Earth science that is important for quantifying soil formation rates, sediment and solute fluxes to oceans, and atmospheric CO2 regulation by silicate weathering. Glaciated landscapes record the erosional legacy of glacial intervals through moraine deposits and U-shaped valleys, whereas more widespread unglaciated hillslopes and rivers lack obvious climate signatures, hampering mechanistic theory for how climate sets fluxes and form. Today, periglacial processes in high-elevation settings promote vigorous bedrock-to-regolith conversion and regolith transport, but the extent to which frost processes shaped vast swaths of low- to moderate-elevation terrain during past climate regimes is not well established. By combining a mechanistic frost weathering model with a regional Last Glacial Maximum (LGM) climate reconstruction derived from a paleo-Earth System Model, paleovegetation data, and a paleoerosion archive, we propose that frost-driven sediment production was pervasive during the LGM in our unglaciated Pacific Northwest study site, coincident with a 2.5 times increase in erosion relative to modern rates. Our findings provide a novel framework to quantify how climate modulates sediment production over glacial-interglacial cycles in mid-latitude unglaciated terrain

    Intrinsic Evaporative Cooling by Hygroscopic Earth Materials

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    The phase change of water from liquid to vapor is one of the most energy-intensive physical processes in nature, giving it immense potential for cooling. Diverse evaporative cooling strategies have resulted worldwide, including roof ponds and sprinklers, courtyard fountains, wind catchers with qanats, irrigated green roofs, and fan-assisted evaporative coolers. These methods all require water in bulk liquid form. The evaporation of moisture that has been sorbed from the atmosphere by hygroscopic materials is equally energy-intensive, however, yet has not been examined for its cooling potential. In arid and semi-arid climates, hygroscopic earth buildings occur widely and are known to maintain comfortable indoor temperatures, but evaporation of moisture from their walls and roofs has been regarded as unimportant since water scarcity limits irrigation and rainfall; instead, their cool interiors are attributed to well-established mass effects in delaying the transmission of sensible gains. Here, we investigate the cooling accomplished by daily cycles of moisture sorption and evaporation which, requiring only ambient humidity, we designate as “intrinsic” evaporative cooling. Connecting recent soil science to heat and moisture transport studies in building materials, we use soils, adobe, cob, unfired earth bricks, rammed earth, and limestone to reveal the effects of numerous parameters (temperature and relative humidity, material orientation, thickness, moisture retention properties, vapor diffusion resistance, and liquid transport properties) on the magnitude of intrinsic evaporative cooling and the stabilization of indoor relative humidity. We further synthesize these effects into concrete design guidance. Together, these results show that earth buildings in diverse climates have significant potential to cool themselves evaporatively through sorption of moisture from humid night air and evaporation during the following day’s heat. This finding challenges the perception of limited evaporative cooling resources in arid climates and greatly expands the applicability of evaporative cooling in contemporary buildings to water-stressed regions

    Frost Resilience of Stabilized Earth Building Materials

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    Earth-based building materials are increasingly valued in green design for their low embodied energy, humidity-buffering ability, and thermal stability. These materials perform well in warm dry climates, but greater understanding of long-term durability is needed for successful adoption in colder and/or wetter climates. The presence of stabilizers dramatically improves resistance to surface erosion from wind and rain, compared to unstabilized adobe and cob counterparts, and the influences of soil composition, fiber type, and diverse binders, on rain and wind surface erosion have been investigated in detail. Frost and freeze-thaw resistance, however, have been less well-studied, despite strong interest in stabilized earth materials in northern North America, Europe, and Asia. In particular, recent studies have relied on a widespread misunderstanding of the mechanism by which frost damage occurs in porous materials that will impede efforts to create valid models for material design and improvement. In addition, the influence of radiative thermal stresses on wall surfaces has been overlooked in favor of focus on ambient air temperatures. Here, we apply contemporary understanding of cracking by segregated ice growth to develop a macroscopic damage index that enables comparison between performance of different materials subject to different weather patterns. An examination of predicted damage patterns for two stabilized earth building materials and two conventional materials in twelve cities over two time periods reveals the dominant factors that govern frost vulnerability. We find that the frost resilience of earth building materials is comparable to that of the conventional materials we examined, and that assessments that neglect expected variations in water content by assuming full saturation are likely to yield misleading results. Over recent years, increased winter temperatures in several cities we examined predict reduced material vulnerability to frost damage, but we also find that accompanying increases in humidity levels have made some cities much more vulnerable

    pressure beneath glaciers

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    effective stress variations forced by changes in condui

    Effective stress profiles and seepage flows beneath glaciers and ice sheets

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