General Analysis of BB Meson Decay into Two Fermions

We study how to measure the current structure of the process that $B$ meson decays into two unstable fermions $\bar f_a$ and $f_b$ in model independent way. We use the momentum distributions of subsequent decay products affected by $\bar f_a f_b$ spin correlation. We have found the following: (1) We can extract the absolute values of two effective coupling constants from the opening angle between the particles decayed from $\bar f_a$ and $f_b$ (2) We can extract the real part of the interference from the energy distribution of one of the decayed particles from $\bar f_a$ or $f_b$. (3) No new information can be obtained from the energy distribution of two decayed particles from $\bar f_a$ and $f_b$. (4) The imaginary part of interference is extracted from the azimuthal angle asymmetry of final-state decay products. (5) If only one of two fermions is unstable, we can extract the real part of interference from each of the energy distribution and opening angle distribution. We show several simple examples.Comment: 27 pages, 20 figure

A Derivation of the Fermi Function in Perturbative Quantum Field Theory

We postulate that the Fermi function should be derived from the amplitude, not from the solution of the Dirac equation, in the quantum field theory. Then, we obtain the following results. 1, We give the amplitude and the width of the neutron beta decay, $n \to p + e^- + \bar \nu_e$ to one loop order. It is carried out by the Feynman parameter integration. 2, As the result, we find the terms which can be interpreted as the Fermi function expanded to order $\alpha$. 3, We also give the same result using complex analysis. 4, We check that there are no such terms in the similar process, $\bar \nu_e + p \to e^+ + n$. 5, We perform the Fermi function expanded to order $\alpha^2$ using complex analysis.Comment: 8 page

Lepton Flavor Violating tau --> 3mu Decay in Type-III Two Higgs Doublet Model

We study the current structure of the lepton flavor violating $\tau\to3\mu$ decay in Type-III 2HDM. This model has many coupling constants which affect this decay. We find that each coupling constant corresponds to the different final-state momenta distribution and vice versa. Using this fact, we suggest how to determine the current structure. We also find the upper limit $|\eta_{23}^E\eta_{22}^E|<0.00022$ in the case that all Higgs bosons except for the lighter CP even neutral one $h^0$ are decoupled, $M_{h^0}=115$GeV and $\cos\beta=1/\sqrt{2}$. The observable difference between the MSSM and type-III 2HDM is also discussed.Comment: 28 pages, 11 figure

Photoelectron detection from transient species in organic semiconducting thin films by dual laser pulse irradiation

An Nd3+:YAG pulsed laser was employed as a light source for two-photon photoemission from organic semiconducting thin films in low vacuum and air. Photoionization by the two-photon process was confirmed in both the environments by measuring photoemission current. By constructing a pump–probe system, photoemissions from transient species formed by the pump light irradiation were detected by probe light irradiation as a result of a linear increase in the photocurrent with the pump power via a one-photon process. Thus, we propose a novel method called two-photon photoelectron yield spectroscopy to determine the excited-state energy levels in ambient environments

Unveiling charge dynamics of visible light absorbing oxysulfide for efficient overall water splitting

Oxysulfide semiconductor, Y2Ti2O5S2, has recently discovered its exciting potential for visible-light-induced overall water splitting, and therefore, imperatively requires the probing of unknown fundamental charge loss pathways to engineer the photoactivity enhancement. Herein, transient diffuse reflectance spectroscopy measurements are coupled with theoretical calculations to unveil the nanosecond to microsecond time range dynamics of the photogenerated charge carriers. In early nanosecond range, the pump-fluence-dependent decay dynamics of the absorption signal is originated from the bimolecular recombination of mobile charge carriers, in contrast, the power-law decay kinetics in late microsecond range is dominated by hole detrapping from exponential tail trap states of valence band. A well-calibrated theoretical model estimates various efficiency limiting material parameters like recombination rate constant, n-type doping density and tail-states parameters. Compared to metal oxides, longer effective carrier lifetime ~6 ns is demonstrated. Different design routes are proposed to realize efficiency beyond 10% for commercial solar-to-hydrogen production from oxysulfide photocatalysts

Evidence and mechanism of efficient thermally activated delayed fluorescence promoted by delocalized excited states

The design of organic compounds with nearly no gap between the first excited singlet (S1) and triplet (T1) states has been demonstrated to result in an efficient spin-flip transition from the T1 to S1 state, that is, reverse intersystem crossing (RISC), and facilitate light emission as thermally activated delayed fluorescence (TADF). However, many TADF molecules have shown that a relatively appreciable energy difference between the S1 and T1 states (~0.2 eV) could also result in a high RISC rate. We revealed from a comprehensive study of optical properties of TADF molecules that the formation of delocalized states is the key to efficient RISC and identified a chemical template for these materials. In addition, simple structural confinement further enhances RISC by suppressing structural relaxation in the triplet states. Our findings aid in designing advanced organic molecules with a high rate of RISC and, thus, achieving the maximum theoretical electroluminescence efficiency in organic light-emitting diodes

Origin of the overall water splitting activity of Ta3N5 revealed by ultrafast transient absorption spectroscopy

Tantalum nitride (Ta3N5) is one of the few visible light absorbing photocatalysts capable of overall water splitting (OWS), by which the evolution of both H2 and O2 is possible. Despite favourable energetics, realizing the OWS or efficient H2 evolution in Ta3N5 prepared by the nitridation of tantalum oxide (Ta2O5) or Ta foil remains a challenge even after 15 years of intensive research. Recently our group demonstrated OWS in Ta3N5 when prepared by the short time nitridation of potassium tantalate (KTaO3). To obtain a mechanistic insight on the role of Ta precursor and nitridation time in realizing OWS, ultrafast dynamics of electrons (3435 nm probe) and holes (545 nm probe) is investigated using transient absorption spectroscopy. Electrons decay majorly by trapping in Ta3N5 prepared by the nitridation of Ta2O5, which do not show OWS. However, OWS activity in Ta3N5 prepared by 0.25 hour nitridation of KTaO3 is particularly favoured by the virtually absent electron and hole trapping. On further increasing the nitridation time of KTaO3 from 0.25 to 10 hour, trapping of both electron and hole is enhanced which concurrently results in a reduction of the OWS activity. Insights from correlating the synthesis conditions—structural defects—carrier dynamics—photocatalytic activity is of importance in designing novel photocatalysts to enhance solar fuel production