Aloe Vera Functionalized Magnetic Nanoparticles Entrapped Ca Alginate Beads as Novel Adsorbents for Cu(II) Removal from Aqueous Solutions

UIDP/5006/2020. Publisher Copyright: © 2022 by the authors.CABs (Ca alginate beads), AVCABs (Aloe vera Ca alginate beads), and AVMNCABs (Aloe-vera functionalized magnetic nanoparticles entrapped Ca alginate beads) were developed as adsorbents for the removal of Cu(II) from aqueous solutions. The materials were characterized using Fourier-transform infrared (FTIR) spectroscopy, high-resolution scanning electron microscopic (HR-SEM) analysis, X-ray diffraction (XRD), energy-dispersive X-ray (EDX) spectroscopy, and a vibrating-sample magnetometer (VSM). The effect of several parameters, such as pH, time, temperature, adsorbent dose, etc., were investigated. The adsorption isotherm of Cu(II) was adjusted best to the Langmuir model. The maximum adsorption capacities were 111.11 mg/g, 41.66 mg/g, and 15.38 mg/g for AVMNCABs, AVCABs, and CABs, respectively. The study of the adsorption kinetics for Cu(II) ions on beads followed a pseudo-second-order kinetic model, with a very good correlation in all cases. The adsorption studies used a spectrophotometric method, dealing with the reaction of Cu(II) with KSCN and variamine blue.publishersversionpublishe

The admissible tsunamigenic source region of 24 September 2013 land-based earthquake application of backward ray tracing technique

A minor tsunami of about 50 cm was generated along the coast of Qurayat near Makran subduction zone in the Arabian Sea due to the 24 September 2013 Pakistan earthquake of magnitude 7.6 Mw(mB),although its source was ~200 km far inland of the Makran trench. The real time sea level observation network in the Arabian Sea recorded minor tsunami arrivals. In an attempt to explain the mechanism of this unusual tsunami, we use backward ray tracing technique to map the admissible region of tsunamigenic source. Basically, in this technique the ray equations are integrated starting from the specific locations of tsunami observations, in all possible directions. The known travel time of the initial waves to the respective tide gauges and tsunami buoys is used in this method. Backward wave front is constructed by joining all endpoints of the rays from each of the locations. The region where the envelope of all backward wave fronts converges is considered as the source of the tsunami, which is ~470 km from the earthquake epicentre with the location at 24.8 N and 61.5E. The admissible region identified is an undersea section between Chabahar and Gwadar, where a mud island had appeared subsequent to this earthquake. Convergence of the tsunami source zone and location of the mud island suggest that the sudden uplift must have caused the tsunam

Novel glycine-functionalized magnetic nanoparticles entrapped calcium alginate beads for effective removal of lead

The magnetic Fe3O4 nanoparticles were functionalized with glycine at pH 6. The glycine functionalized magnetic nanoparticles (GFMNPS) were then entrapped into alginate polymer as beads and used as adsorbent for the re- moval of Pb(II) ions. The developed adsorbents were characterized by Fourier transform infrared spectroscopy, vibrating sample magnetometer and scanning electron microscopic analysis. The surface of beads contain amino and carboxylate groups which make them effective adsorbents for the removal of Pb(II) ions. The adsorp- tion of Pb(II) ions from aqueous solution was found to be highly pH dependent. 92.8% Pb(II) was removed just in 10 min. The kinetic data fitted well with pseudo second order model and the equilibrium was reached in 100 min with 99.8% removal of Pb(II) ions from aqueous solution. The adsorption isotherm strictly followed Langmuir model with the maximum adsorption capacity of 555.5 mg/g of the adsorbent. The thermodynamic study con- firmed that the adsorption was spontaneous and endothermic in nature. The adsorbent could be regenerated four times simply by 0.2 M HNO3 retaining 90% of the adsorption capacity. The synthesized adsorbent was found to be eco-friendly, cost-effective, efficient and superior over other polymer based adsorbents for removal of Pb(II) ions from aqueous solution

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Not AvailablePlants are constantly threatened by a virus infection, i.e., Potyviruses, the second largest genus of plant viruses which results in several million-dollar losses in various essential crops globally. Yam bean (Pachyrhizus erosus) is considered to be one of the essential tuberous legume crops holding a great potential source of starch. Yam Bean Mosaic Virus (YBMV) of Potyvirus group belonging to the family potyviridae affects Yam bean and several angiosperms both in the tropical and sub-tropical regions causing large economical losses in crops. In this study, we attempted to understand the sequence-structure relationship and mode of RNA binding mechanism in YBMV CP using in silico integrative modeling and allatoms molecular dynamics (MD) simulations. The assembly of coat protein (CP) subunits from YBMV and the plausible mode of RNA binding were compared with the experimental structure of CP from Watermelon mosaic virus potyvirus (5ODV). The transmembrane helix region is present in the YBMV CP sequence ranging from 76 to 91 amino acids. Like the close structural-homolog, 24 CPs monomeric sub-units formed YBMV a conserved fold. Our computational study showed that ARG124, ARG155 , and TYR151 orient towards the inner side of the virion, while, THR122, GLN125, SER92, ASP94 reside towards the outer side of the virion. Despite sharing very low sequence similarity with CPs from other plant viruses, the strongly conserved residues Ser, Arg, and Asp within the RNA binding pocket of YBMV CP indicate the presence of a highly conserved RNA binding site in CPs from different families. Using several bioinformatics tools and comprehensive analysis from MD simulation, our study has provided novel insights into the RNA binding mechanism in YBMV CP. Thus, we anticipate that our findings from this study will be useful for the development of new therapeutic agents against the pathogen, paving the way for researchers to better control this destructive plant virus.Not Availabl

Structural insights into the RNA interaction with Yam bean Mosaic virus (coat protein) from Pachyrhizus erosus using bioinformatics approach.

Plants are constantly threatened by a virus infection, i.e., Potyviruses, the second largest genus of plant viruses which results in several million-dollar losses in various essential crops globally. Yam bean (Pachyrhizus erosus) is considered to be one of the essential tuberous legume crops holding a great potential source of starch. Yam Bean Mosaic Virus (YBMV) of Potyvirus group belonging to the family potyviridae affects Yam bean and several angiosperms both in the tropical and sub-tropical regions causing large economical losses in crops. In this study, we attempted to understand the sequence-structure relationship and mode of RNA binding mechanism in YBMV CP using in silico integrative modeling and all-atoms molecular dynamics (MD) simulations. The assembly of coat protein (CP) subunits from YBMV and the plausible mode of RNA binding were compared with the experimental structure of CP from Watermelon mosaic virus potyvirus (5ODV). The transmembrane helix region is present in the YBMV CP sequence ranging from 76 to 91 amino acids. Like the close structural-homolog, 24 CPs monomeric sub-units formed YBMV a conserved fold. Our computational study showed that ARG124, ARG155, and TYR151 orient towards the inner side of the virion, while, THR122, GLN125, SER92, ASP94 reside towards the outer side of the virion. Despite sharing very low sequence similarity with CPs from other plant viruses, the strongly conserved residues Ser, Arg, and Asp within the RNA binding pocket of YBMV CP indicate the presence of a highly conserved RNA binding site in CPs from different families. Using several bioinformatics tools and comprehensive analysis from MD simulation, our study has provided novel insights into the RNA binding mechanism in YBMV CP. Thus, we anticipate that our findings from this study will be useful for the development of new therapeutic agents against the pathogen, paving the way for researchers to better control this destructive plant virus