A Series of [MnMo₉O₃₂]^6– Based Solids: Homochiral Transferred from Adjacent Polyoxoanions to One-, Two-, and Three-Dimensional Frameworks

Five new compounds based on the Waugh-type polyoxoanion [MnMo₉O₃₂]^6– Na₄Mn­[MnMo₉O₃₂]·11.5H₂O (<b>1</b>), KNa₃Mn­[MnMo₉O₃₂]·9H₂O (<b>2</b>), Na₂Ni₂[MnMo₉O₃₂]·12H₂O (<b>3</b>), l-Mn₃[MnMo₉O₃₂]·13H₂O (<b>4a</b>), d-Mn₃[MnMo₉O₃₂]·13H₂O (<b>4b</b>), and l-Ni₃[MnMo₉O₃₂]·11.5H₂O (<b>5a</b>) have been synthesized. In these compounds, with the changes of Na⁺/TM (TM = Mn²⁺, Ni²⁺) in the crystal, the homochiral interactions were extended from two adjacent [MnMo₉O₃₂]^6– to one-dimensional (compounds <b>1</b> and <b>2</b>), two-dimensional (compound <b>3</b>), and three-dimensional (compounds <b>4</b> and <b>5</b>) systems, respectively