Effects of storm events on mobilisaton and in-stream processing of dissolved organic matter (DOM) in a Welsh peatland catchment.

Peatlands are important contributors of dissolved organic matter (DOM) to downstream aquatic systems. We investigated the effects of storm events on dissolved organic carbon (DOC) concentrations and DOM quality in a stream draining a Welsh peatland catchment. Intensive stream samples were collected and analysed for pH, DOC, dissolved organic nitrogen (DON), absorbance and fluorescence. Soil water samples and samples of sphagnum pore water were also collected, and a simple end-member mixing model was applied to account for changes occurring during the events. Fluorescence data were interpreted using parallel factor analysis (PARAFAC). DOC concentrations increased and pH decreased during the storm events. The soil water data and the mixing model indicated that this was due to a change of flow paths and draining of the DOC-rich acrotelm. Absorbance indices and the DOC/DON ratio suggested that the DOM released during events was less degraded. There was a striking, inversely related diurnal pattern in absorbance and fluorescence after the discharge peak. The diurnal pattern and a lack of fit with the mixing model suggested that fluorescing DOM was mainly produced in-stream. Fluorescence has been found to peak in the morning and decline during day-time due to photo-bleaching. We hypothesise that the input of additional DOM during events causes a change in the diurnal pattern, giving a peak at mid-day, when the processing of the additional DOM is highest

Hypogenic Caves in the UK

The UK has a wide variety of hypogenic caves, including transverse maze caves, relict hydrothermal caves, gypsum mazes and hypogenic karst associated with water rising up deep thrust faults. While few of these are particularly extensive, they offer insights into the mechanisms of speleogenesis and mineralisation. The best developed hypogenic caves in the UK are in the Carboniferous limestones of northern England where at least nine network maze caves with plan lengths exceeding 1 km are known, almost all of which are accessible only via disused mine workings. In South Wales, relict hypogenic cave networks have been documented from cave systems surrounding the South Wales Coalfield. Hydrothermal cave systems are also known in the Bristol region in southern England, the Derbyshire Peak District and North Wales where they are associated with Pb–Zn mineralisation. In all three of these areas, active deep phreatic groundwater circulation is ongoing. Elsewhere in the UK, transverse artesian groundwater flow through Permo-Triassic gypsum in the Ripon area has led to the development of hypogenic cave systems and numerous sinkholes. This chapter documents for the first time all the known hypogenic cave systems found in the UK, discusses their modes of formation and outlines the potential for future discoveries