Ultrasonic and Heat Treatment of Crude Oils

One of the methods of influence on rheological properties of heavy high-viscosity crude oils is ultrasonic treatment. Ultrasonic treatment allows reducing the viscosity of crude oil and, therefore, reducing the costs of its production and transportation. In this paper, the influence of ultrasonic treatment on the rheological characteristics of crude oil (sample No. 1 API = 29.1, sample No. 2 API = 15.9) was investigated. An experimental method was developed. Experimental studies were carried out using the Physica MCR 102 rheometer. The influence of the intensity and duration of ultrasonic treatment on the viscosity of the initial crude oils was studied for 24 h. In addition, the rheological characteristics of the treated oil were investigated after its natural cooling to 293 K. The results are compared with similar results for thermal heating

Numerical Simulation of Polymer Solutions in a Single-Screw Extruder

Single-screw extruders are the most common equipment used for polymer extrusion. The study of the hydrodynamics of a polymer melts flow in the extruder channel is the basis for modeling and understanding the extrusion process. In general form, the extruder includes a straight section with a screw installed in it. In this study, the three-dimensional mathematical modeling of the polymer solutions flow in the metering zone of a single-screw extruder is performed. The influences of the screw geometry (L/D2 = 1…3) on the flow structure and the pressure drop are analyzed under a speed rotation up to 60 rpm. Aqueous solutions of 0.5% polyacrylamide (0.5% PAA) and 1.5% sodium salt of carboxymethyl cellulose (1.5% CMC) are considered as the working fluid

The Viscoelastic Swirled Flow in the Confusor

A two-dimensional mathematical model for a steady viscoelastic laminar flow in a confusor was developed under the condition of swirled flow imposed at the inlet. Low density polyethylene was considered as a working fluid. Its behavior was described by a two-mode Giesekus model. The proposed mathematical model was tested by comparing it with some special cases presented in the literature. Additionally, we propose a system of equations to find the nonlinear parameters of the multimode Giesekus model (mobility factor) based on experimental measurement. The obtained numerical results showed that in a confusor with the contraction rate of 4:1, an increase in the swirl intensity at Wi < 5.1 affects only the circumferential velocity, while the axial and radial velocities remain constant. The distribution pattern of the first normal stress difference in the confusor is qualitatively similar to the one in a channel with abrupt contraction, i.e., as the viscoelastic fluid flows in the confusor, the value of N1 increases and reaches a maximum at the end of the confusor. Dimensionless damping coefficients of swirl are used to estimate the swirl intensity. The results show that the swirl intensity decreases exponentially

Exact Solution for Viscoelastic Flow in Pipe and Experimental Validation

The development of analytical methods for viscoelastic fluid flows is challenging. Currently, this problem has been solved for particular cases of multimode differential rheological equations of media state (Giesekus, the exponential form of Phan-Tien-Tanner, eXtended Pom-Pom). We propose a parametric method that yields solutions without additional assumptions. The method is based on the parametric representation of the unknown velocity functions and the stress tensor components as a function of coordinate. Experimental flow visualization based on the SIV (smoke image velocimetry) method was carried out to confirm the obtained results. Compared to the Giesekus model, the experimental data are best predicted by the eXtended Pom-Pom model

An experimental study of sunflower husk pellets combustion

The thermogravimetric study of the sunflower husk pellets combustion was carried out at three heating rates: 5, 10, and 20 °C/min to increase the efficiency of agricultural waste disposal methods. The husk combustion process can be divided into several stages: the stage of moisture evaporation and the release of light fractions of volatile substances, the main stage of the release of volatiles and combustion, as well as the stage of the carbonaceous residue after-burning. The maximum mass loss was observed in the experiment with a heating rate of 10 °C/min, and it was equal to 91.99% of the total weight of organic matter. The average residual mass for all experiments was 3%. The higher heating value (HHV) of sunflower husk pellets was 19.2 MJ/kg. When implementing a biomass boiler with a capacity of 430 kW, the return period will be 3.43 years

The Role of <i>Pectobacterium atrosepticum</i> Exopolysaccharides in Plant–Pathogen Interactions

The phytopathogenic bacterium Pectobacterium atrosepticum (Pba), one of the members of the soft rot Pectobacteriaceae, forms biofilm-like structures known as bacterial emboli when colonizing the primary xylem vessels of the host plants. The initial extracellular matrix of the bacterial emboli is composed of the host plant’s pectic polysaccharides, which are gradually substituted by the Pba-produced exopolysaccharides (Pba EPS) as the bacterial emboli “mature”. No information about the properties of Pba EPS and their possible roles in Pba-plant interactions has so far been obtained. We have shown that Pba EPS possess physical properties that can promote the maintenance of the structural integrity of bacterial emboli. These polymers increase the viscosity of liquids and form large supramolecular aggregates. The formation of Pba EPS aggregates is provided (at least partly) by the acetyl groups of the Pba EPS molecules. Besides, Pba EPS scavenge reactive oxygen species (ROS), the accumulation of which is known to be associated with the formation of bacterial emboli. In addition, Pba EPS act as suppressors of the quantitative immunity of plants, repressing PAMP-induced reactions; this property is partly lost in the deacetylated form of Pba EPS. Overall, our study shows that Pba EPS play structural, protective, and immunosuppressive roles during Pba–plant interactions and thus should be considered as virulence factors of these bacteria

Supramolecular Structure and Mechanical Performance of &kappa;-Carrageenan&ndash;Gelatin Gel

In this work, by means of complex physicochemical methods the structural features of a composite &kappa;-carrageenan&ndash;gelatin system were studied in comparison with initial protein gel. The correlation between the morphology of hydrogels and their mechanical properties was demonstrated through the example of changes in their rheological characteristics. The experiments carried out with PXRD, SAXS, AFM and rheology approaches gave new information on the structure and mechanical performance of &kappa;-carrageenan&ndash;gelatin hydrogel. The combination of PXRD, SAXS and AFM results showed that the morphological structures of individual components were not observed in the composite protein&ndash;polysaccharide hydrogels. The results of the mechanical testing of initial gelatin and engineered &kappa;-carrageenan&ndash;gelatin gel showed the substantially denser parking of polymer chains in the composite system due to a significant increase in intermolecular protein&ndash;polysaccharide contacts. Close results were indirectly followed from the SAXS estimations&mdash;the driving force for the formation of the common supramolecular structural arrangement of proteins and polysaccharides was the increase in the density of network of macromolecular chains entanglements; therefore, an increase in the energy costs was necessary to change the conformational rearrangements of the studied system. This increase in the macromolecular arrangement led to the growth of the supramolecular associate size and the growth of interchain physical bonds. This led to an increase in the composite gel plasticity, whereas the enlargement of scattering particles made the novel gel system not only more rigid, but also more fragile

Modulation of Molecular Structure and Mechanical Properties of &kappa;-Carrageenan-Gelatin Hydrogel with Multi-Walled Carbon Nanotubes

Hydrogels, three-dimensional hydrophilic water-insoluble polymer networks having mechanical properties inherent for solids, have attracted continuous research attention over a long time period. Here, we studied the structure and properties of hydrogel based on gelatin, &kappa;-carrageenan and CNTs using the combination of SAXS, PXRD, AFM microscopy, SEM and rheology methods. We have shown that the integration of polysaccharide and protein in the composite hydrogel leads to suppression of their individual structural features and homogenization of two macromolecular components into a single structural formation. According to obtained SAXS results, we observed the supramolecular complex, which includes both polysaccharide and protein components associated with each other. It was determined that hydrogel structure formed in the initial solution state (dispersion) retains hydrogel supramolecular structure under its cooling up to gel state. The sizes of dense cores of these polyelectrolyte complexes (PEC) slightly decrease in the gel state in comparison with PEC water dispersion. The introduction of CNTs to hydrogel does not principally change the type of supramolecular structure and common structural tendencies observed for dispersion and gel states of the system. It was shown that carbon nanotubes embedded in hydrogel act as the supplementary template for formation of the three-dimensional net, giving additional mechanical strengthening to the studied system