Hydrogen adsorption and phase transitions in fullerite

Hydrogen desorption and adsorption properties of the fullerene materials C60, C70, and fullerite (a mixture of C60 and C70) were measured volumetrically using a Sievert's apparatus. Over several cycles of isotherm measurements at 77 K, the hydrogen storage capacities of one of the fullerite samples increased from an initial value of 0.4 wt % for the first cycle to a capacity of 4.4 wt % for the fourth cycle. Correspondingly, the surface area of this sample increased from 0.9 to 11 m^2/g, and there were changes in its x-ray powder diffraction pattern. In comparison, two other fullerite samples, prepared by a different procedure showed no such behavior. Pure C60 and pure C70 were also cycled and exhibited small and constant capacities of 0.7 and 0.33 wt %, respectively, as a function of number of cycles. The enhanced storage capacity of fullerite material is tentatively attributed to the presence of C60 oxide

Hydrogen desorption and adsorption measurements on graphite nanofibers

Graphite nanofibers were synthesized and their hydrogen desorption and adsorption properties are reported for 77 and 300 K. Catalysts were made by several different methods including chemical routes, mechanical alloying, and gas condensation. The nanofibers were grown by passing ethylene and H2 gases over the catalysts at 600 °C. Hydrogen desorption and adsorption were measured using a volumetric analysis Sieverts' apparatus, and the graphite nanofibers were characterized by transmission electron microscopy and Brunauer–Emmett–Teller surface area analysis. The absolute level of hydrogen desorption measured from these materials was typically less than the 0.01 H/C atom, comparable to other forms of carbon

The Operator Product Expansion of the Lowest Higher Spin Current at Finite N

For the N=2 Kazama-Suzuki(KS) model on CP^3, the lowest higher spin current with spins (2, 5/2, 5/2,3) is obtained from the generalized GKO coset construction. By computing the operator product expansion of this current and itself, the next higher spin current with spins (3, 7/2, 7/2, 4) is also derived. This is a realization of the N=2 W_{N+1} algebra with N=3 in the supersymmetric WZW model. By incorporating the self-coupling constant of lowest higher spin current which is known for the general (N,k), we present the complete nonlinear operator product expansion of the lowest higher spin current with spins (2, 5/2, 5/2, 3) in the N=2 KS model on CP^N space. This should coincide with the asymptotic symmetry of the higher spin AdS_3 supergravity at the quantum level. The large (N,k) 't Hooft limit and the corresponding classical nonlinear algebra are also discussed.Comment: 62 pages; the footnotes added, some redundant appendices removed, the presentations in the whole paper improved and to appear in JHE

Meta-Stable Brane Configurations with Seven NS5-Branes

We present the intersecting brane configurations consisting of NS-branes, D4-branes(and anti D4-branes) and O6-plane, of type IIA string theory corresponding to the meta-stable nonsupersymmetric vacua in four dimensional N=1 supersymmetric SU(N_c) x SU(N_c') x SU(N_c'') gauge theory with a symmetric tensor field, a conjugate symmetric tensor field and bifundamental fields. We also describe the intersecting brane configurations of type IIA string theory corresponding to the nonsupersymmetric meta-stable vacua in the above gauge theory with an antisymmetric tensor field, a conjugate symmetric tensor field, eight fundamental flavors and bifundamentals. These brane configurations consist of NS-branes, D4-branes(and anti D4-branes), D6-branes and O6-planes.Comment: 34pp, 9 figures; Improved the draft and added some footnotes; Figure 1, footnote 7 and captions of Figures 7,8,9 added or improved and to appear in CQ

The Large N 't Hooft Limit of Kazama-Suzuki Model

We consider N=2 Kazama-Suzuki model on CP^N=SU(N+1)/SU(N)xU(1). It is known that the N=2 current algebra for the supersymmetric WZW model, at level k, is a nonlinear algebra. The N=2 W_3 algebra corresponding to N=2 was recovered from the generalized GKO coset construction previously. For N=4, we construct one of the higher spin currents, in N=2 W_5 algebra, with spins (2, 5/2, 5/2, 3). The self-coupling constant in the operator product expansion of this current and itself depends on N as well as k explicitly. We also observe a new higher spin primary current of spins (3, 7/2, 7/2, 4). From the behaviors of N=2, 4 cases, we expect the operator product expansion of the lowest higher spin current and itself in N=2 W_{N+1} algebra. By taking the large (N, k) limit on the various operator product expansions in components, we reproduce, at the linear order, the corresponding operator product expansions in N=2 classical W_{\infty}^{cl}[\lambda] algebra which is the asymptotic symmetry of the higher spin AdS_3 supergravity found recently.Comment: 44 pages; the two typos in the first paragraph of page 23 corrected and to appear in JHE