4 research outputs found
Evidence for anthropogenic <sup>14</sup>C-enrichment in estuarine waters adjacent to the North Sea
[1] The isotopic composition (d13C and D14C) of high
molecular weight dissolved organic carbon (HMW DOC)
was studied in the Tyne and Tweed estuaries, NE England.
Despite significant removal of terrigenous HMW DOC in
the low salinity regions (S < 15), D14C remained modern
with little variation around 115%. This lack of apparent age
discrimination was attributed to either non-oxidative
removal or the absence of a significant proportion of old
refractory C in the HMW DOC pool. At S < 15, we
observed seaward increases in d13C and D14C. With no
documented local 14C inputs, we attributed non-bomb
related 14C-enrichment at S < 15 to a possible âlingering
effectâ of distal anthropogenic sources in near-coastal North
Sea HMW DOC. Given the global distribution of potential
sources, we propose that anthropogenic 14C should be
considered in assigning ages of DOC pools in near-coastal
waters and suggest its possible use as a tracer for DOC
transformations