Electrical and Optical Properties of Flexible Transparent Silver Nanowires electrodes

AgNWs were produced by the one-pot polyol method, and it had been produced by reduction of AgNO3 by ethylene glycol in presence of polyvinylpyrrolidone (PVP) and KCl at high temperature of about 160 oC. AgNWs suspension were purified by centrifuging at 3000 rpm for three times then re-depressed in deionized water with a concentration of 1%. The purified suspension was diluted to different concentrations (2-5) mg. mL-1 using 1% of hydroxy methylcellulose to design different AgNWs transparent conductive films (AgNWs-TCFs). AgNWs suspension inks were coated on the glass and polyethylene terephthalate (PET) substrates. Different AgNWs diameters were obtained by changing the synthesis conditions. It has been observed that the wire diameter will greatly affect both the optical and electrical properties of the obtained AgNWs-TCFs. The best obtained AgNWs-TCFs had high transparency of about 91.5 %, small sheet resistance of about 14 .03 Ω and optical haze less than 2%, which met the requirements for the manufacture of optoelectronic and sensor equipment. Keywords: Silver nanowires, transparent conductive electrode, flexible electrodes, polyol method, AgNWs size control, AgNWs size-dependent and one-pot synthesis

Comparative Electrochemical Noise Study of the Corrosion of Different Alloys Exposed to Chloride Media

This paper describes the corrosion behavior of aluminum, copper, and mild steel when exposed to chloride media using both electrochemical noise analysis (ENA) and electrochemical impedance spectroscopy (EIS). Analysis of electrochemical noise (EN) data demonstrated the need for removal of drifts in both potential and current fluctuations. Statistical analysis such as noise resistance, lo-calization index, skewness and kurtosis has been evaluated. Noise resistance showed a good agreement with polarization resistance. Fast Fourier transformation (FFT) has been applied to convert EN data from the time domain to the frequency domain. Spectral noise plots showed a good agreement with impedance spectra for the different alloys determined at the same exposure time. Spectral and statistical analysis can extract useful information from EN data

Biosynthesis approach of zinc oxide nanoparticles for aqueous phosphorous removal: physicochemical properties and antibacterial activities

Abstract In this study, phosphorus (PO4 3–-P) is removed from water samples using zinc oxide nanoparticles (ZnO NPs). These nanoparticles are produced easily, quickly, and sustainably using Onion extracts (Allium cepa) at an average crystallite size of 8.13 nm using the Debye–Scherrer equation in the hexagonal wurtzite phase. The characterization and investigation of bio-synthesis ZnO NPs were carried out. With an initial concentration of 250 mg/L of P, the effects of the adsorbent dose, pH, contact time, and temperature were examined. At pH = 3 and T = 300 K, ZnO NPs achieved the optimum sorption capacity of 84 mg/g, which was superior to many other adsorbents. The isothermal study was found to fit the Langmuir model at a monolayer capacity of 89.8 mg/g, and the kinetic study was found to follow the pseudo-second-order model. The adsorption process was verified to be endothermic and spontaneous by thermodynamic characteristics. As a result of their low cost as an adsorbent and their high metal absorption, ZnO NPs were found to be the most promising sorbent in this investigation and have the potential to be used as effective sorbents for the removal of P from aqueous solutions. The antimicrobial activity results showed that ZnO NPs concentration had greater antibacterial activity than conventional Cefotaxime, which was utilized as a positive control in the inhibitory zone. However, no inhibitory zone was visible in the controlled wells that had been supplemented with onion extract and DMSO

Electrical and Optical Properties of Flexible Transparent Silver Nanowires electrodes

AgNWs were produced by the one-pot polyol method, and it had been produced by reduction of AgNO3 by ethylene glycol in presence of polyvinylpyrrolidone (PVP) and KCl at high temperature of about 160 oC. AgNWs suspension were purified by centrifuging at 3000 rpm for three times then re-depressed in deionized water with a concentration of 1%. The purified suspension was diluted to different concentrations (2-5) mg. mL-1 using 1% of hydroxy methylcellulose to design different AgNWs transparent conductive films (AgNWs-TCFs). AgNWs suspension inks were coated on the glass and polyethylene terephthalate (PET) substrates. Different AgNWs diameters were obtained by changing the synthesis conditions. It has been observed that the wire diameter will greatly affect both the optical and electrical properties of the obtained AgNWs-TCFs. The best obtained AgNWs-TCFs had high transparency of about 91.5 %, small sheet resistance of about 14 .03 Ω and optical haze less than 2%, which met the requirements for the manufacture of optoelectronic and sensor equipment. Keywords: Silver nanowires, transparent conductive electrode, flexible electrodes, polyol method, AgNWs size control, AgNWs size-dependent and one-pot synthesis