Liquid Crystalline Aryltriazene-1-Oxides with Two Ester Units: Synthesis, Characterisation, Structure and Thermal Properties

A new series of mesogenic triazene-1-oxides, C6H5-N(O)=N-NH-C6H4-C(O)-O- C6H4-O-(O)C-C6H4-OR (1, R=n-alkyl group from CH3 to C14H29), was designed and synthesised. All members of this new series were characterised on the basis of spectral and analytical data. The thermotropic liquid crystalline behaviour of the compounds was observed over a wide temperature range using optical microscopy. The mesophase structure was confirmed by a small-angle X-ray diffraction study of a representative member (1k). The molecular structure of compound 1i was determined using the single crystal X-ray diffraction method as a representative case. Dimer formation in the solid state occurs due to intermolecular N-H...O and C-H...O interactions. Intermolecular C-H...&pi interactions were also detected in 1i. The intermolecular hydrogen bonding and intermolecular C-H...p interactions arrange the phenyl triazene-1-oxide fragments of the molecules in layers within the molecular assembly

Structure of Liquid Crystalline 1-Phenyl-3-{4-[4-(4-Octyloxybenzoyloxy) Phenyloxycarbonyl]phenyl}triazene-1-Oxide At Low Temperature

The molecular structure of 1-phenyl-3-{4-[4-(4-octyloxybenzoyloxy)- phenyloxycarbonyl]phenyl}triazene-1-oxide, a member of newly developed liquid crystalline homologous series, has been investigated by crystal X-ray crystallography at low temperature (100K). The title compound crystallizes in the triclinic crystal class in the space group P[image omitted] with cell parameters a=5.766(5), b=12.151(10), c=21.751(17), =79.089(13), =88.646(14), =84.278(14), V=1489(2)3 for Z=2. It establishes the N-oxide form of the triazene-1-oxide moiety. The overall molecule is not planar, the dihedral angles between pairs of adjacent benzene rings are 14.00 (10), 52.36 (07), and 50.57 (07). Intramolecular N-HO hydrogen-bonding is present within the triazene-1-oxide moiety of the title compound. The compound forms inversion dimer via an intermolecular N-HO and an intermolecular C-HO links. The dimers are then linked into chains in a parallel fashion by C-HO hydrogen bonds. The crystal packing is further stabilized by C-H interactions