Allene oxidation in jet-stirred reactor : a kinetic modeling study

Allene oxidation was modeled using a comprehensive kinetic reaction mechanism including the most recent findings concerning the kinetics of the reactions involved in the oxidation of allene. The proposed mechanism is able to reproduce experimental data (molecular species concentration profiles) obtained in our jet stirred reactor at 1 atm, for temperatures extending from 1030 to 1070K and equivalence ratios of 0.2 to 2. The proposed oxidation mechanism is also able to correctly reproduce ignition delay times measured in shock tube and molecular species concentrations measured in our jet stirred reactor for the oxidation of propyne