Removal of nutrients from pulp and paper biorefinery effluent : operation, kinetic modelling and optimization by response surface methodology

This study investigated the effectiveness of extended aeration system (EAS) and rice straw activated carbon-extended aeration system (RAC-EAS) in the treatment of pulp and paper biorefinery effluent (PPBE). RAC-EAS focused on the efficient utilization of lignocellulosic biomass waste (rice straw) as a biosorbent in the treatment process. The experiment was designed by response surface methodology (RSM) and conducted using a bioreactor that operated at 1–3 days hydraulic retention times (HRT) with PPBE concentrations at 20, 60 and 100%. The bioreactor was fed with real PPBE having initial ammonia-N and total phosphorus (TP) concentrations that varied between 11.74 and 59.02 mg/L and 31–161 mg/L, respectively. Findings from the optimized approach by RSM indicated 84.51% and 91.71% ammonia-N and 77.62% and 84.64% total phosphorus reduction in concentration for EAS and RAC-EAS, respectively, with high nitrification rate observed in both bioreactors. Kinetic model optimization indicated that modified stover models was the best suited and were statistically significant (R 2 ≥ 0.98) in the analysis of substrate removal rates for ammonia-N and total phosphorus. Maximum nutrients elimination was attained at 60% PPBE and 48 h HRT. Therefore, the model can be utilized in the design and optimization of EAS and RAC-EAS systems and consequently in the prediction of bioreactor behavior

Effect of Operating Parameters on the Performance of Integrated Fixed-Film Activated Sludge for Wastewater Treatment

Integrated fixed-film activated sludge (IFAS) is a hybrid wastewater treatment process that combines suspended and attached growth. The current review provides an overview of the effect of operating parameters on the performance of IFAS and their implications for wastewater treatment. The operating parameters examined include hydraulic retention time (HRT), solids retention time (SRT), dissolved oxygen (DO) levels, temperature, nutrient loading rates, and aeration. Proper control and optimization of these parameters significantly enhance the treatment efficiency and pollutant removal. Longer HRT and appropriate SRT contribute to improved organic matter and nutrient removal. DO levels promote the growth of aerobic microorganisms, leading to enhanced organic matter degradation. Temperature influences microbial activity and enzymatic reactions, impacting treatment efficiency. Nutrient loading rates must be carefully managed to avoid system overload or inhibition. Effective aeration ensures uniform distribution of wastewater and biofilm carriers, optimizing contact between microorganisms and pollutants. IFAS has been used in water reuse applications, providing a sustainable and reliable water source for non-potable uses. Overall, IFAS has proven to be an effective and efficient treatment process that can provide high-quality effluent suitable for discharge or reuse. Understanding the effects of these operating parameters helps to optimize the design and operation for efficient wastewater treatment. Further research is needed to explore the interactions between different parameters, evaluate their impact under varying wastewater characteristics, and develop advanced control strategies for improved performance and sustainability

Biochar-based geopolymer nanocomposite for COD and phenol removal from agro-industrial biorefinery wastewater : kinetic modelling, microbial community, and optimization by response surface methodology

Agro-industrial biorefinery effluent (AIBW) is considered a highly polluting source responsible for environmental contamination. It contains high loads of chemical oxygen demand (COD), and phenol, with several other organic and inorganic constituents. Thus, an economic treatment approach is required for the sustainable discharge of the effluent. The long-term process performance, contaminant removal and microbial response of AIBW to rice straw-based biochar (RSB) and biochar-based geopolymer nanocomposite (BGC) as biosorbents in an activated sludge process were investigated. The adsorbents operated in an extended aeration system with a varied hydraulic retention time of between 0.5 and 1.5 d and an AIBW concentration of 40–100% for COD and phenol removal under standard conditions. Response surface methodology was utilised to optimize the process variables of the bioreactor system. Process results indicated a significant reduction of COD (79.51%, 98.01%) and phenol (61.94%, 74.44%) for BEAS and GEAS bioreactors respectively, at 1 d HRT and AIBW of 70%. Kinetic model analysis indicated that the Stover-Kincannon model best describes the system functionality, while the Grau model was better in predicting substrate removal rate and both with a precision of between R 2 (0.9008–0.9988). Microbial communities examined indicated the abundance of genera, following the biosorbent addition, while RSB and BGC had no negative effect on the bioreactor's performance and bacterial community structure of biomass. Proteobacteria and Bacteroidetes were abundant in BEAS. While the GEAS achieved higher COD and phenol removal due to high Nitrosomonas, Nitrospira, Comamonas, Methanomethylovorans and Acinetobacter abundance in the activated sludge. Thus, this study demonstrated that the combination of biosorption and activated sludge processes could be promising, highly efficient, and most economical for AIBW treatment, without jeopardising the elimination of pollutants or the development of microbial communities

Trend and current practices of coagulation-based hybrid systems for pulp and paper mill effluent treatment : mechanisms, optimization techniques and performance evaluation

This paper presents an overview of pulp and paper mills (PPM) production processes, the resulting release of wastewater effluent loaded with wide range of pollutants and associated environmental impacts. The review highlighted the different types of functional materials and their modified forms employed as coagulants for pulp and paper mills industries effluent (PPME) treatment that have been intensively studied as a promising strategy for PPM to achieve cleaner and sustainable treatments in accordance with sustainable development goals (SDGs) “6-Clean water and sanitation”, “9-Industry, innovation, and infrastructure”, and “12-Responsible consumption and production”. Standalone coagulation treatment processes are inherently ineffective towards meeting the increasingly stringent discharge requirements, coupled with their higher energy demand, and increased operational and maintenance costs. Owing to the recalcitrant nature of PPME contaminants, this review explored the effectiveness of the coagulation processes for decontamination of PPME. Furthermore, the review provides a state-of-the-art coagulation-based hybrid systems employed for enhanced PPME treatment. The process limitations, influencing factors and optimization techniques are highlighted. The review also highlights how sustained research in the subject area impacts on achieving cleaner production. The review also discusses coagulant classifications and the synergistic, antagonistic and shock load toxic effects of hybrid coagulants on toxicant biodegradation and their associated system efficiency. Moreover, it offers a guide for the development and application of sustainable hybrid-based coagulants for PPME treatment. The findings presented herein provide a vital theoretical foundation for sustainable solutions to improve coagulation-based hybrid systems efficiency and their scale-up towards potential commercialization