Developing Construction Materials from Recycled Composites, Recycled Materials, and Recycling Technologies

This paper reviews the state of technology in recycling of coal fly ash, metal, glass, plastic and composite materials has been conducted. This is closely related to our daily life, as recent estimates indicate that more than 33 million tons of plastic are discarded each year, of which 6.5% are recycled and 7.7% are burned. Similar amounts of materials are discarded every year, including glass, metal and fly ash. Although much research has been performed on the recycling technologies for different common waste materials, how to apply them in constructional field and how they performed in application are quite new, with studies that are rapidly increasing in recently due to China decided not to receive any materials waste from the US, which means a high portion of discarded materials nowhere to be placed. In addition, just choosing to dispose of waste materials by landfills not only causes new environmental pollution but also wastes available resources. Therefore, from different aspects, such as the basic properties of materials, the technical means of recycling, the applications, properties, and prices after recycling, this paper comprehensively depict the circulation of these five materials

Experimental investigation of long-term performance of fiber-reinforced epoxy and polyurethane polymer composites

The primary challenge encountered by polymers and their composites when exposed to saline water is their inadequate ability to withstand wear and tear over time. With a potential to replace conventional materials the long-term performance of FRP composites is still a novice area. This manuscript thus, reports an experimental investigation and prediction of the durability of fiber-reinforced polymer composites exposed to seawater at different temperatures. E-glass/epoxy and E-glass/polyurethane samples were exposed to 23 °C, 45 °C and 65 °C seawater for up to 2700 days (90 months). Tensile tests evaluated the mechanical performance of the composite as a function of exposure time, and strength-based technique was used to assess the durability. The experimental results revealed that the tensile strength of E-glass/epoxy composite decreased by 6.3% and 48.9% after 90 months in seawater at 23 and 65 °C, respectively, whereas it declined by 37.6% and 63.6% respectively for E-glass/Polyurethane composite. The prolonged immersion in seawater results in plasticization and swelling in the composite material, which accelerates the fiber/matrix debonding. SEM micrographs indicate fiber/matrix debonding, potholing, fiber pull-out, river line marks, and matrix cracking which showcases deterioration in the tensile properties of both composites

Mechanical Properties and Non-Isothermal Crystallization Kinetics of Polylactic Acid Modified by Polyacrylic Elastomers and Cellulose Nanocrystals

In this paper, a polyacrylic elastomer latex with butyl acrylate (BA) as the core and methyl methacrylate (MMA) copolymerized with glycidyl methacrylate (GMA) as the shell, named poly(BA-MMA-GMA) (PBMG), was synthesized by seeded emulsion polymerization. Cellulose nanocrystal (CNC) was dispersed in the polyacrylic latex to prepare PBMG/CNC dispersions with different CNC contents. The dried product was mixed with polylactic acid (PLA) to fabricate PLA/PBMG/CNC blends. The addition of PBMG and PBMG/CNC improved the mechanical properties of the PLA matrix. Differential scanning calorimetry (DSC) was used to investigate the non-isothermal crystallization kinetics. The Avrami equation modified by the Jeziorny, Ozawa and Mo equations was used to analyze the non-isothermal crystallization kinetics of PLA and its blends. Analysis of the crystallization halftime of non-isothermal conditions indicated that the overall rate of crystallization increased significantly at 1 wt% content of CNC. This seemed to result from the increase of nucleation density and the acceleration of segment movement in the presence of the CNC component. This phenomenon was verified by polarizing microscope observation