The application of deep eutectic solvent ionic liquids for environmentally-friendly dissolution and recovery of precious metals

publisher: Elsevier articletitle: The application of deep eutectic solvent ionic liquids for environmentally-friendly dissolution and recovery of precious metals journaltitle: Minerals Engineering articlelink: http://dx.doi.org/10.1016/j.mineng.2015.09.026 content_type: article copyright: Copyright © 2015 The Authors. Published by Elsevier Ltd.© 2015 Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/)

Realistic Expanding Source Model for Invariant One-Particle Multiplicity Distributions and Two-Particle Correlations in Relativistic Heavy-Ion Collisions

We present a realistic expanding source model with nine parameters that are necessary and sufficient to describe the main physics occuring during hydrodynamical freezeout of the excited hadronic matter produced in relativistic heavy-ion collisions. As a first test of the model, we compare it to data from central Si + Au collisions at p_lab/A = 14.6 GeV/c measured in experiment E-802 at the AGS. An overall chi-square per degree of freedom of 1.055 is achieved for a fit to 1416 data points involving invariant pi^+, pi^-, K^+, and K^- one-particle multiplicity distributions and pi^+ and K^+ two-particle correlations. The 99-percent-confidence region of parameter space is identified, leading to one-dimensional error estimates on the nine fitted parameters and other calculated physical quantities. Three of the most important results are the freezeout temperature, longitudinal proper time, and baryon density along the symmetry axis. For these we find values of 92.9 +/- 4.4 MeV, 8.2 +/- 2.2 fm/c, and 0.0222 + 0.0096 / - 0.0069 fm^-3, respectively.Comment: 37 pages and 12 figures. RevTeX 3.0. Submitted to Physical Review C. Complete preprint, including device-independent (dvi), PostScript, and LaTeX versions of the text, plus PostScript files of all figures, are available at http://t2.lanl.gov/publications/publications.html or at ftp://t2.lanl.gov/publications/res

Radio observations of the planetary nebula around the OH/IR Star OH354.88-0.54 (V1018 Sco)

We present radio observations of the unique, recently formed, planetary nebula (PN) associated with a very long-period OH/IR variable star V1018 Sco that is unequivocally still in its asymptoticgiant branch phase. Two regions within the optical nebula are clearly detected in nonthermal radio continuum emission, with radio spectral indices comparable to those seen in colliding-wind Wolf-Rayet binaries. We suggest that these represent shocked interactions between the hot, fast stellar wind and the cold nebular shell that represents the PN's slow wind moving away from the central star. This same interface produces both synchrotron radio continuum and the optical PN emission. The fast wind is neither spherical in geometry nor aligned withany obvious optical or radio axis. We also report the detection of transient H2O maser emission in this nebula.Comment: 11 pages, LaTeX (mn2e.cls), incl. 9 PostScript (ps or eps) figures and 2 tables. Accepted by MNRA

School Breakfast Club Programs in Australian Primary Schools, Not Just Addressing Food Insecurity: A Qualitative Study

Background: Many Australian primary schools have established school breakfast clubs (SBCs) to address concerns about children arriving at school hungry and the subsequent impact on learning but their effectiveness is uncertain. This study aimed to identify the perceived benefits, impacts, operational practices, and challenges of running SBCs. Method: Case studies with 10 Australian primary schools from different socioeconomic and geographic areas. Focus groups or interviews were held with 142 participants including students, parents/carers, school staff, and funding body representatives between July 2016 and October 2017. Results: There were no eligibility criteria to attend SBCs with all students able to attend, regardless of household income. Thus, participating in the SBC was often reported as a matter of choice rather than a consequence of food insecurity. Participants, including children, discussed the many social benefits of SBCs (i.e., social eating, relationship building, school connection, and engagement) as well as perceived improved classroom behavior. Challenges for program delivery included resource limitations, particularly, the reliance on volunteers and sourcing food. Discussion/Conclusion: SBCs offered a range of benefits beyond their primary goal of addressing food security. SBCs were highly valued by members of the school community for their social, welfare, well-being, and educational benefits, but program sustainability is constrained by resource limitations

Low Freeze-out Temperature and High Collective Velocities in Relativistic Heavy-Ion Collisions

On the basis of a nine-parameter expanding source model that includes special relativity, quantum statistics, resonance decays, and freeze-out on a realistic hypersurface in spacetime, we analyze in detail invariant pi+, pi-, K+, and K- one-particle multiplicity distributions and pi+ and K+ two-particle correlations in nearly central collisions of Si + Au at a laboratory bombarding energy per nucleon of 14.6 GeV/c. By considering separately the one-particle data and the correlation data, we find that the central baryon density, nuclear temperature, transverse collective velocity, longitudinal collective velocity, and source velocity are determined primarily by one-particle multiplicity distributions and that the transverse radius, longitudinal proper time, width in proper time, and pion incoherence fraction are determined primarily by two-particle correlations. By considering separately the pion data and the kaon data, we find that although the pion freeze-out occurs somewhat later than the kaon freeze-out, the 99% confidence-level error bars associated with the two freeze-outs overlap. These and other detailed studies confirm our earlier conclusion based on the simultaneous consideration of the pion and kaon one-particle and correlation data that the freeze-out temperature is less than 100 MeV and that both the longitudinal and transverse collective velocities--which are anti-correlated with the temperature--are substantial. We also discuss the flaws in several previous analyses that yielded a much higher freeze-out temperature of approximately 140 MeV for both this reaction and other reactions involving heavier projectiles and/or higher bombarding energies.Comment: 14 pages. RevTeX 3.1. Submitted to Physical Review C. PostScript version available at http://t2.lanl.gov/publications/publications.html or at ftp://t2.lanl.gov/pub/publications/lf

Three-loop matching coefficients for hot QCD: Reduction and gauge independence

We perform an integral reduction for the 3-loop effective gauge coupling and screening mass of QCD at high temperatures, defined as matching coefficients appearing in the dimensionally reduced effective field theory (EQCD). Expressing both parameters in terms of a set master (sum-) integrals, we show explicit gauge parameter independence. The lack of suitable methods for solving the comparatively large number of master integrals forbids the complete evaluation at the moment. Taking one generic class of masters as an example, we highlight the calculational techniques involved. The full result would allow to improve on one of the classic probes for the convergence of the weak-coupling expansion at high temperatures, namely the comparison of full and effective theory determinations of the spatial string tension. Furthermore, the full result would also allow to determine one new contribution of order O(g**7) to the pressure of hot QCD.Comment: 19 pages, 2 figures. v2: new Section 6 discussing applications, to match journal versio

Tracing marine cryptotephras in the North Atlantic during the last glacial period: Improving the North Atlantic marine tephrostratigraphic framework

Tephrochronology is increasingly being recognised as a key tool for the correlation of disparate palaeoclimatic archives, underpinning chronological models and facilitating climatically independent comparisons of climate proxies. Tephra frameworks integrating both distal and proximal tephra occurrences are essential to these investigations providing key details on their spatial distributions, geochemical signatures, eruptive sources as well as any available chronological and/or stratigraphic information. Frameworks also help to avoid mis-correlation of horizons and provide important information on volcanic history. Here we present a comprehensive chronostratigraphic framework of 14 tephra horizons from North Atlantic marine sequences spanning 60-25 cal ka BP. Horizons previously discovered as visible or coarse-grained deposits have been combined with 11 newly recognised volcanic deposits, identified through the application of cryptotephra identification and characterisation methods to a wide network of marine sequences. Their isochronous integrity has been assessed using their physical characteristics. All horizons originated from Iceland with the vast majority having a basaltic composition sourced from the Grímsvötn, Kverkfjöll, Hekla/Vatnafjöll and Katla volcanic systems. New occurrences, improved stratigraphic placements and a refinement of the geochemical signature of the NAAZ II are reported and the range of the FMAZ IV has been extended. In addition, several significant geochemical populations that further investigations could show to be isochronous are reported. This tephra framework provides the foundation for the correlation and synchronisation of these marine records to the Greenland ice-cores and European terrestrial records to investigate the phasing, rate, timing and mechanisms controlling rapid climate changes that characterised the last glacial period

A Categorical Semantics for Inductive-Inductive Definitions

Induction-induction is a principle for defining data types in Martin-Löf Type Theory. An inductive-inductive definition consists of a set A, together with an A-indexed family B : A → Set, where both A and B are inductively defined in such a way that the constructors for A can refer to B and vice versa. In addition, the constructors for B can refer to the constructors for A. We extend the usual initial algebra semantics for ordinary inductive data types to the inductive-inductive setting by considering dialgebras instead of ordinary algebras. This gives a new and compact formalisation of inductive-inductive definitions, which we prove is equivalent to the usual formulation with elimination rules

A North Atlantic tephrostratigraphical framework for 130-60 ka b2k:new tephra discoveries, marine-based correlations, and future challenges

Building chronological frameworks for proxy sequences spanning 130–60 ka b2k is plagued by difficulties and uncertainties. Recent developments in the North Atlantic region, however, affirm the potential offered by tephrochronology and specifically the search for cryptotephra. Here we review the potential offered by tephrostratigraphy for sequences spanning 130–60 ka b2k. We combine newly identified cryptotephra deposits from the NGRIP ice-core and a marine core from the Iceland Basin with previously published data from the ice and marine realms to construct the first tephrostratigraphical framework for this time-interval. Forty-three tephra or cryptotephra deposits are incorporated into this framework; twenty three tephra deposits are found in the Greenland ice-cores, including nine new NGRIP tephras, and twenty separate deposits are preserved in various North Atlantic marine sequences. Major, minor and trace element results are presented for the new NGRIP horizons together with age estimates based on their position within the ice-core record. Basaltic tephras of Icelandic origin dominate the framework with only eight tephras of rhyolitic composition found. New results from marine core MD99-2253 also illustrate some of the complexities and challenges of assessing the depositional integrity of marine cryptotephra deposits. Tephra-based correlations in the marine environment provide independent tie-points for this time-interval and highlight the potential of widening the application of tephrochronology. Further investigations, however, are required, that combine robust geochemical fingerprinting and a rigorous assessment of tephra depositional processes, in order to trace coeval events between the two depositional realms