7 research outputs found
Analysis of the Reaction Rate Coefficients for Slow Bimolecular Chemical Reactions
Simple bimolecular reactions are analyzed
within the framework of the Boltzmann equation in the initial stage of a
chemical reaction with the system far from chemical equilibrium. The
Chapman-Enskog methodology is applied to determine the coefficients of the
expansion of the distribution functions in terms of Sonine polynomials for
peculiar molecular velocities. The results are applied to the reaction
, and the influence of the non-Maxwellian
distribution and of the activation-energy dependent reactive cross sections
upon the forward and reverse reaction rate coefficients are discussed.Comment: 11 pages, 5 figures, to appear in vol.42 of the Brazilian Journal of
Physic
Nonequilibrium thermodynamics and energy efficiency in weight loss diets
Carbohydrate restriction as a strategy for control of obesity is based on two effects: a behavioral effect, spontaneous reduction in caloric intake and a metabolic effect, an apparent reduction in energy efficiency, greater weight loss per calorie consumed. Variable energy efficiency is established in many contexts (hormonal imbalance, weight regain and knock-out experiments in animal models), but in the area of the effect of macronutrient composition on weight loss, controversy remains. Resistance to the idea comes from a perception that variable weight loss on isocaloric diets would somehow violate the laws of thermodynamics, that is, only caloric intake is important ("a calorie is a calorie"). Previous explanations of how the phenomenon occurs, based on equilibrium thermodynamics, emphasized the inefficiencies introduced by substrate cycling and requirements for increased gluconeogenesis. Living systems, however, are maintained far from equilibrium, and metabolism is controlled by the regulation of the rates of enzymatic reactions. The principles of nonequilibrium thermodynamics which emphasize kinetic fluxes as well as thermodynamic forces should therefore also be considered