The Chemical Composition of Cernis 52 (BD+31 640)

We present an abundance analysis of the star Cernis 52 in whose spectrum we recently reported the napthalene cation in absorption at 6707.4 {\AA}. This star is on a line of sight to the Perseus molecular complex. The analysis of high-resolution spectra using a chi^2-minimization procedure and a grid of synthetic spectra provides the stellar parameters and the abundances of O, Mg, Si, S, Ca, and Fe. The stellar parameters of this star are found to be T_{eff} = 8350 +- 200 K, logg= 4.2 +- 0.4 dex. We derived a metallicity of [Fe/H] = -0.01 +- 0.15. These stellar parameters are consistent with a star of $\sim 2$ \Msun in a pre-main-sequence evolutionary stage. The stellar spectrum is significantly veiled in the spectral range 5150-6730 {\AA} up to almost 55 per cent of the total flux at 5150 {\AA} and decreasing towards longer wavelengths. Using Johnson-Cousins and 2MASS photometric data, we determine a distance to Cernis 52 of 231$^{+135}_{-85}$ pc considering the error bars of the stellar parameters. This determination places the star at a similar distance to the young cluster IC 348. This together with its radial velocity, v_r=13.7+-1 km/s, its proper motion and probable young age support Cernis 52 as a likely member of IC 348. We determine a rotational velocity of v\sin i=65 +- 5 km/s for this star. We confirm that the stellar resonance line of \ion{Li}{1} at 6707.8 {\AA} is unable to fit the broad feature at 6707.4 {\AA}. This feature should have a interstellar origin and could possibly form in the dark cloud L1470 surrounding all the cluster IC 348 at about the same distance.Comment: Accepted for publication in The Astrophysical Journa

An expert-curated global database of online newspaper articles on spiders and spider bites

Mass media plays an important role in the construction and circulation of risk perception associated with animals. Widely feared groups such as spiders frequently end up in the spotlight of traditional and social media. We compiled an expert-curated global database on the online newspaper coverage of human-spider encounters over the past ten years (2010– 2020). This database includes information about the location of each human-spider encounter reported in the news article and a quantitative characterisation of the content—location, presence of photographs of spiders and bites, number and type of errors, consultation of experts, and a subjective assessment of sensationalism. In total, we collected 5348 unique news articles from 81 countries in 40 languages. The database refers to 211 identified and unidentified spider species and 2644 unique human-spider encounters (1121 bites and 147 as deadly bites). To facilitate data reuse, we explain the main caveats that need to be made when analysing this database and discuss research ideas and questions that can be explored with it. Co-authors include: Stefano Mammola 1,2 ✉, Jagoba Malumbres-Olarte 1,3,61, Valeria A rabesky4,5, Diego Alejandro Barrales-Alcalá 6, Aimee Lynn Barrion-Dupo 7, Marco A ntonio Benamú 8,9,10, Tharina L. Bird 11,12, Maria Bogomolova13, Pedro C ardoso 1, Maria C hatzaki 14, Ren-Chung C heng 15, Tien-Ai C hu 15, Leticia M. C lassen-Rodríguez 16, Iva Čupić17, Naufal Urfi Dhiya’ulhaq 18, André-Philippe Drapeau P icard 19, Hisham K. E l-Hennawy20, Mert Elverici 21, Caroline S. Fukushima 1, Zeana Ganem22,23, Efrat Gavish-Regev 22, Naledi T . Gonnye24, Axel Hacala 25, Charles R. Haddad 26, Thomas Hesselberg 27, Tammy A i Tian Ho 28, Thanakorn I nto29, Marco I saia30, Dharmaraj Jayaraman 31, Nanguei Karuaera32, Rajashree Khalap33, Kiran Khalap33, Dongyoung Kim 34, Tuuli Korhonen1, Simona Kralj-Fišer 35, Heidi Land36, Shou-Wang Lin 36, Sarah Loboda 37, Elizabeth Lowe 38, Yael Lubin 5,39, Alejandro Martínez 2, Zingisile Mbo26, Marija Miličić 1,40, Grace Mwende Kioko41, Veronica Nanni 30,42, Yusoff Norma- Rashid 43, Daniel Nwankwo44, Christina J. P ainting 45, Aleck P ang46, Paolo Pantini47, Martina P avlek17,48, Richard P earce49, Booppa P etcharad29, Julien P étillon 25,50, Onjaherizo C hristian R aberahona51, Joni A . Saarinen1, Laura Segura-Hernández 52, Lenka Sentenská 53, Gabriele Uhl 36, Leilani Walker54,55, Charles M. Warui56, Konrad Wiśniewski 57, Alireza Zamani58, Catherine Scott 37,61 & Angela C huang 59,60,6

Caracterización de la durabilidad del hormigón sometido a ciclos hielo deshielo mediante modelos micromecánicos

En este trabajo se exponen los resultados previos de la caracterización de la durabilidad del hormigón frente a los ciclos hielo-deshielo mediante la micromecánica. Los modelos micromecánicos permiten estudiar las propiedades globales del material en función de las propiedades microestructurales de las fases constituyentes: propiedades elásticas, fracción de volumen, distribución y orientación de las heterogeneidades así como su geometría. El trabajo se divide en dos partes, un estudio teórico y una posterior validación experimental. En el estudio teórico se aborda el comportamiento de la velocidad a partir de la variación de las características microestructurales por este tipo de deterioro. Estas predicciones se han comparado con las medidas de velocidad ultrasónica, mostrando buenos resultados

The structure relaxation of carbon nanotube

A simple macroscopic continuum elasticity theory (CET) is used to calculate the structure relaxation of single-wall carbon nanotube (SWNT), an analytic formula is obtained. We also expand an atomic scale three-parameter empirical model [ T. Lenosky {\emph et al.} Nature 355, 333(1992)] in order to correctly describe the bond-length change effects. The structure relaxation of SWNT expected by the model is good in agreement with our CET results, and very well consistent with the previous calculation from a first principles local density function approximation. Using the expanded Lenosky model, we calculate the strain energy of bending tube. The obtained results are good in agreement with the previous theoretical expectation. It shows the model may be a good simple replacement of some more sophisticated methods on determining carbon networks deformations.Comment: 9 pages, 4 eps figure

Deterministic variational inference for robust Bayesian neural networks

Bayesian neural networks (BNNs) hold great promise as a flexible and principled solution to deal with uncertainty when learning from finite data. Among approaches to realize probabilistic inference in deep neural networks, variational Bayes (VB) is theoretically grounded, generally applicable, and computationally efficient. With wide recognition of potential advantages, why is it that variational Bayes has seen very limited practical use for BNNs in real applications? We argue that variational inference in neural networks is fragile: successful implementations require careful initialization and tuning of prior variances, as well as controlling the variance of Monte Carlo gradient estimates. We provide two innovations that aim to turn VB into a robust inference tool for Bayesian neural networks: first, we introduce a novel deterministic method to approximate moments in neural networks, eliminating gradient variance; second, we introduce a hierarchical prior for parameters and a novel Empirical Bayes procedure for automatically selecting prior variances. Combining these two innovations, the resulting method is highly efficient and robust. On the application of heteroscedastic regression we demonstrate good predictive performance over alternative approaches

Direct Optofluidic Measurement of the Lipid Permeability of Fluoroquinolones.

Quantifying drug permeability across lipid membranes is crucial for drug development. In addition, reduced membrane permeability is a leading cause of antibiotic resistance in bacteria, and hence there is a need for new technologies that can quantify antibiotic transport across biological membranes. We recently developed an optofluidic assay that directly determines the permeability coefficient of autofluorescent drug molecules across lipid membranes. Using ultraviolet fluorescence microscopy, we directly track drug accumulation in giant lipid vesicles as they traverse a microfluidic device while exposed to the drug. Importantly, our measurement does not require the knowledge of the octanol partition coefficient of the drug - we directly determine the permeability coefficient for the specific drug-lipid system. In this work, we report measurements on a range of fluoroquinolone antibiotics and find that their pH dependent lipid permeability can span over two orders of magnitude. We describe various technical improvements for our assay, and provide a new graphical user interface for data analysis to make the technology easier to use for the wider community.The work was supported by an ERC Consolidator grant “DesignerPores” awarded to UFK. JC acknowledges support from the BBSRC. MS was supported by the Friedrich Naumann Foundation for Freedom and the Swiss- European Mobility Programme. KAN was supported by the Erasmus Plus student exchange programme. SHA is supported by a Herchel Smith Postdoctoral Fellowship. SP acknowledges support from the Leverhulme Trust through an Early Career Fellowship (ECF-2013-444).This is the final version of the article. It first appeared from Nature Publishing Group at http://dx.doi.org/10.1038/srep32824

Evaluation offreeze-thaw damage in concrete by ultrasonic imaging

This work studies the use of ultrasonic imaging as an evaluation tool in concrete subjected to freeze–thaw (F–T) cycles. To evaluate the damage in this deterioration process, ultrasonic velocity and attenuation images have been generated from concrete specimens with and without air-entraining agents. Two parameters have been proposed from these ultrasonic images according to our experimental setup: the non-assessable area proportion (NAAP) and a weighted average velocity in terms of the NAAP. The proposed parameters have been compared with the recommended failure criteria of the ASTM and Rilem standards, which employ ultrasonic contact measurements. The principal advantage of the use of ultrasonic images and the proposed methodology in comparison with the ultrasonic velocity measurements by contact is the possibility of detection of incipient damage caused by accelerated freeze–thaw cycles

Inhibition of bacterial degradation of EtG by collection as dried urine spots (DUS)

Ethyl glucuronide (EtG) and ethyl sulfate (EtS) are direct alcohol consumption markers widely used nowadays for clinical and forensic applications. They are detectable in blood and urine even after consumption of trace amounts of ethanol and for a longer time frame, being detectable even when no more ethanol is present. The instability of EtG against bacterial degradation in contaminated urine samples and/or the possible postcollection synthesis of this metabolite in samples containing, e.g., Escherichia coli and ethanol, may cause false identification of alcohol uptake. Therefore, it is of paramount importance to constrict these error sources by inhibition of any bacterial growth causing hydrolization or synthesis of EtG. This study evaluates a new method of collecting urine samples on filter paper, dried urine spots (DUS), for simultaneous detection of EtG, EtS and creatinine, having the great advantage of inhibiting bacterial activity. In addition, a method validation for the determination of EtG and EtS in DUS was performed according to the FDA guidelines. Sterile-filtered urine was spiked with EtG and EtS, inoculated with E. coli and incubated. Liquid and dried urine samples were collected after various time intervals up to 96h. Liquid samples were frozen immediately after collection, whereas aliquots for DUS were pipetted onto filter paper, allowed to dry and stored at RT until analysis 1week after. The specimens were analyzed by LC-ESI-MS/MS. As expected, degradation of EtG, but not of EtS, was observed in contaminated liquid urine samples. However, the specimens collected on filter paper and stored at RT showed no degradation during storage. Therefore, collecting urine samples on filter paper for EtG and EtS analysis turns out to be a reliable method to avoid bacterial degradation of EtG and EtS, and consequently, stabilization of these ethanol metabolites is achieved. In addition, simultaneous measurement of creatinine content as an indicator of urine dilution helps to interpret the results. Method validation for EtG and EtS in DUS was satisfactory, showing the linearity of the calibration curves in the studied concentration range, good precision, accuracy and selectivit

Biokerosene from coconut, babassu, camelina and palm kernel oils: production and properties of their blends with fossil kerosene

On December 20th 2006 the European Commission approved a law proposal to include the civil aviation sector in the European market of carbon dioxide emission rights [European Union Emissions Trading System, EUETS). On July 8th 2009, the European Parliament and Conseil agreed that all flights leaving or landing in the EU airports starting from January 1st 2012 should be included in the EUETS. On November 19th 2008, the EU Directive 2008/101/CE [1] included the civil aviation activities in the EUETS, and this directive was transposed by the Spanish law 13/2010 of July 5th 2010 [2]. Thus, in 2012 the aviation sector should reduce their emissions to 97 % of the mean values registered in the period 2004-2006, and for 2013 these emission reductions should reach 95 % of the mean values for that same period. Trying to face this situation, the aviation companies are planning seriously the use of alternative jet fuels to reduce their greenhouse gas emissions and to lower their costs. However, some US airlines have issued a lawsuit before the European Court of Justice based in that this EU action violates a long standing worldwide aviation treaty, the Chicago convention of 1944, and also the Chinese aviation companies have rejected to pay any EU carbon dioxide tax [3]. Moreover, the USA Departments of Agriculture and Energy and the Navy will invest a total of up to $150 million over three years to spur production of aviation and marine biofuels for commercial and military applications [4]. However, the jet fuels should fulfill a set of extraordinarily sensitive properties to guarantee the safety of planes and passengers during all the flights

Chemical abundances of late-type pre-main sequence stars in the σ\sigma-Orionis cluster

The young $\sigma$-Orionis cluster is an important location for understanding the formation and evolution of stars, brown dwarfs, and planetary-mass objects. Its metallicity, although being a fundamental parameter, has not been well determined yet. We present the first determination of the metallicity of nine young late-type stars in $\sigma$-Orionis. Using the optical and near-infrared broadband photometry available in the literature we derive the effective temperatures for these nine cluster stars, which lie in the interval 4300--6500 K (1--3 \Msuno). These parameters are employed to compute a grid of synthetic spectra based on the code MOOG and Kurucz model atmospheres. We employ a $\chi^2$-minimization procedure to derive the stellar surface gravity and atmospheric abundances of Al, Ca, Si, Fe, Ni and Li, using multi-object optical spectroscopy taken with WYFFOS+AF2 at at the William Herschel Telescope ($\lambda/\delta\lambda\sim7500$). The average metallicity of the $\sigma$-Orionis cluster is [Fe/H] $= -0.02\pm0.09\pm0.13$ (random and systematic errors). The abundances of the other elements, except lithium, seem to be consistent with solar values. Lithium abundances are in agreement with the "cosmic" $^7$Li abundance, except for two stars which show a $\log \epsilon(\mathrm{Li})$ in the range 3.6--3.7 (although almost consistent within the error bars). There are also other two stars with $\log \epsilon(\mathrm{Li})\sim 2.75$. We derived an average radial velocity of the $\sigma$-Orionis cluster of $28\pm4$km/s. The $\sigma$-Orionis metallicity is roughly solar.Comment: Accepted for publication in Astronomy and Astrophysic