34 research outputs found
Role of domain walls in the abnormal photovoltaic effect in BiFeO3
Recently, the anomalous photovoltaic (PV) effect in BiFeO3 (BFO) thin
films, which resulted in open circuit voltages (V-oc) considerably
larger than the band gap of the material, has generated a revival of the
entire field of photoferroelectrics. Here, via temperature-dependent PV
studies, we prove that the bulk photovoltaic (BPV) effect, which has
been studied in the past for many non-centrosymmetric materials, is at
the origin of the anomalous PV effect in BFO films. Moreover, we show
that irrespective of the measurement geometry, V-oc as high as 50V can
be achieved by controlling the conductivity of domain walls (DW). We
also show that photoconductivity of the DW is markedly higher than in
the bulk of BFO
Characterisation of Pyroelectric Materials
Pyroelectrics form a very broad class of materials. Any material which has a crystal structure possessing a polar point symmetry—i.e. one which both lacks a centre of symmetry and has a unique axis of symmetry—will possess an intrinsic, or spontaneous, polarisation and show the pyroelectric effect. The pyroelectric effect is a change in that spontaneous polarisation caused by a change in temperature. It is manifested as the appearance of free charge at the surfaces of the material, or a flow of current in an external circuit connected to it. The effect is a simple one, but it has been used in a range of sensing devices, most notably uncooled pyroelectric infra-red (PIR) sensors, and has thus come to be of some engineering and economic significance, enabling a wide range of sensing systems, ranging from burglar alarms through FTIR spectroscopic instruments to thermal imagers