35 research outputs found
The Role of Cognitive Factors in Childhood Social Anxiety: Social Threat Thoughts and Social Skills Perception
Full text linkReactions of d(0) alkylidene and amide complexes with silanes
No full textReactions of silanes with d(o) Ta alkylidene and Group 4 amide complexes were found to involve the initial attack on silicon atoms in the silanes by nucleophilic alkylidene carbon or amide nitrogen atoms. The reaction of (Me3SiCH2)(3)Ta(PMe3)[=CHSiMe3] (1) with H2SiR'Ph (R' = Me, Ph) gave (Me3SiCH2)(3)Ta[=C(SiMe3)SiHR'Ph] (2a-b). Similar reactions of these two silanes and (H2PhSi)(2)CH2 with (Me3SiCH2)Ta(PMe3)(2)[=CHR](2) (R = SiMe3, 3; CMe3, 4) yielded novel metallasilacyclobutadienes and a metalladisilacyclohexadiene, respectively. In comparison, the reactions between M(NMe2)(4) (M = Ti, Zr, Hf) and silanes were found to give aminosilanes and metal amide hydride species which were perhaps involved in the formation of titanium-silicon-nitride (Ti-Si-N) ternary materials
Knowing the Promises, Facing the Challenges: The Role of the Internet in Development and Human Rights Campaigns and Movements in the Arab Middle East
No full textAnother (methodological) look at knowledge gaps and the Internet’s potential for closing them
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When do traumatic experiences alter risk-taking behavior? A machine learning analysis of reports from refugees
No full textPhysical symptoms in very young children assessed for sexual abuse: a mixed method analysis from the ASAC study
No full textThe bereavement experience of adolescents and early young adults with cancer: Peer and parental loss due to death is associated with increased risk of adverse psychological outcomes
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