Intelligent stimuli-responsive materials : from well-defined nanostructures to applications

Book revie

Stimuli-responsive polymer film or coating prepared by mixing in a suitable fashion a side chain liquid crystalline polymer with reactive mesogens and responsive devices:process for preparing the same

The limitation of the different classes of responsive liquid crystals such as volatility in case of low molecular weight liquid crystals (LMWLCs) can be overcome by the development of a responsive film based on polymerliquid crystals (PLCs) and reactive mesogens (RMs or reactive liquid crystal monomers) to create a responsive film or coating material which appears to be easily alignable and processable. That coating material shows a large response of which the properties can be tuned in a modular approach. In this way, the advantages of both materials, PLCs and RMs, were combined, yielding stable films, which can be aligned when desired and which stimuli- responsive properties can be tuned by the choice of RMs. Thus mixtures of PLCs with RMs open the doors to a wide variety of stimuli-responsive coating systems, without the need of time consuming trial-and-error synthesis of PLCs and closed liquid crystal cells. By choosing chiral RMs, cholesteric LC coatings can for instance be fabricated, while a light responsive RM could provide a light responsive coating. In addition, one could use similar methods as were used for LMWLCs with RMs in closed cells to prepare for example broadband reflectors or patterned coatings that change topography by a stimulus

Nano-textured polymers for future architectural needs

The rapid developments in molecular sciences like nanotechnology and self-organizing molecular systems generate a wealth of new materials and functions. In comparison to electronics the application in architecture remains somewhat underexposed. New functionalities in optics, responsive mechanics, sensing and adjustable permeation for gases and water might add to new opportunities in providing for personal comfort and energy management in houses and professional buildings. With a number of examples we demonstrate how complex but well-controlled molecular architectures provide functionalities worthwhile of being integrated in architectural designs. Optical coatings are capable of switching colors or reflectivity, creating possibilities for design but also for the control of thermal transmission through windows. They respond to temperature, light intensity, or both. Selectively-reflective thin polymer layers or paint pigments can be designed to switch between infrared and visible regions of the solar spectrum. Coatings can be designed to change their topology and thereby their appearance, of interest for in-house light management, or just for aesthetic appeal. Plastic materials can be imbued with the property of autonomous sun tracking and provided morphing behavior upon contact with moisture or exposure to light. Many of these materials need further developments to meet the requirements for building integration with respect to robustness, lifetime, and the like, which will only be accomplished after demonstration of interest from the architectural world

System comprising organic or metallo-organic energy and/or charge variable moieties

The invention relates to a system for use in an electric or optical device comprising at least two organic or metallo-organic energy and/or charge variable moieties having conjugated unsaturated bonds, wherein at least one moiety has an energy state different from another of said moieties, characterized in that the system is a H-donor-Hacceptor system comprising at least one H-donor molecule having at least two hydrogen bonding clusters, each cluster comprising at least two groups having formed a hydrogen bond, and at least two H-acceptor molecules, each having at least one hydrogen bonding cluster, each cluster comprising at least two groups having formed a hydrogen bond with the groups of the H-donor molecule, at least one of the H-donor and H-acceptor molecules 10 further comprising one or more of the organic or metallo-organic energy and/or charge variable moieties

Photonic time-temperature sensor having an embossed interpenetrating network of cholesteric liquid crystalline polymers and a secondary polymer

Photonic time-temperature sensor consisting of an embossed interpenetrating network of a cholesteric liquid crystalline polymers and a secondary polymer. Preferably in which the secondary polymer is orthogonal and is not covalently attached to the interpenetrating network, but physically interpenetrated therein. For use as food sensor for checking freshness of the food

The Potential of Static and Thermochromic Window Films for Energy Efficient Building Renovations

The type of glazing implemented in a building plays an important role in the heat management of a building. Solar heat entering through glazing causes overheating of interior spaces and increases building’s cooling load. In this work, the energy saving potential of window films based on Cholesteric Liquid Crystals (CLC) is explored. This emerging technology allows for the fabrication of static and thermochromic solar heat rejecting window films and can provide a simple renovation solution towards energy efficient buildings. Simulations on a model office showed that static CLC-based window films can save up to 29% on a building’s annual energy use in warm climates. In climates with distinct summer and winter seasons, static solar heat rejecting windows films cause an additional heating demand during winters, which reduces the annual energy savings. In these climates, the benefit of thermochromic CLC-based window films becomes evident and an annual energy saving up to 22% can be achieved.</p

Supramolecular Organization of ssDNA-Templated p-Conjugated Oligomers via Hydrogen Bonding

peer reviewedThe templated self-assembly of water-soluble p-conjugated molecules bearing a diaminotriazine moiety H-bonding to a single-strand oligothymine template leads to defined structures. We study these assemblies with molecular modeling, circular dichroism spectroscopy, and scanning probe microscopy, to get a better understanding of the factors governing the supramolecular organization and structural order

On the dimensional control of 2D hybrid nanomaterials

Thermotropic smectic liquid crystalline polymers were used as a scaffold to create organic/inorganic hybrid layered nanomaterials. Different polymers were prepared by photopolymerizing blends of a hydrogen bonded carboxylic acid derivative and a 10 % cross-linker of variable length in their liquid crystalline phase. Nanopores with dimensions close to 1 nm were generated by breaking the hydrogen bonded dimers in a high pH solution. The pores were filled with positively charged silver (Ag) ions, resulting in a layered silver(I)-polymeric hybrid material. Subsequent exposure to a NaBH4 reducing solution allowed for the formation of supported hybrid metal/organic films. In the bulk of the film the dimension of the Ag nanoparticles (NPs) was regulated with subnanometer precision by the cross-linker length. Ag nanoparticles with an average size of 0.9, 1.3, and 1.8 nm were produced inside the nanopores thanks to the combined effect of spatially confined reduction and stabilization of the nanoparticles by the polymer carboxylic groups. At the same time, strong Ag migration occurred in the surface region, resulting in the formation of a nanostructured metallic top layer composed of large (10–20 nm) NPs.</p

Affecting surface chirality via multicomponent adsorption of chiral and achiral molecules

Here we report on the apparent reduction in surface chirality upon co-assembling a chiral and achiral molecule into a physisorbed self-assembled monolayer at the liquid/solid interface as revealed by scanning tunneling microscopy (STM). Chiral OPV with achiral thymine gives rise to surface-confined supramolecular diastereomers

ssPNA templated assembly of oligo(p-phenylenevinylene)s

peer reviewe