Vanadium in particles and sediments of the northern Saronikos Gulf, Greece

This study provides data for total and non-residual vanadium distributions in the northern Saronikos Gulf and shows that close to the Athens sewage outfall (ASO), the combined domestic and industrial wastes have resulted in a considerable increase in concentrations of vanadium in sediments and suspended solids. This appears to be the main vanadium source in the area; a second major source is a fertilizer plant (FP) near the entrance of Piraeus Harbour (PH), the impact of which is also important. Atmospheric inputs from the Piraeus industrial site and frequent crude oil spillages from ships and land-based sources seem to contribute significantly to the observed vanadium distribution, which is clearly affected by the prevailing circulation of surface waters and winds. The high percentage of the 0.5NHCl-leachable vanadium fraction in the most polluted sediments, together with positive correlation with organic carbon and certain other trace metals (i.e. Ag, Co, Cr, Fe, Zn) and negative correlation coefficients with Al and Sc, indicate that a considerable portion of the vanadium is of "anthropogenic" origin not related to lithogenous particles. It enters the system in association with relatively large organic aggregates, either authigenic or derived from sewage. © 1989

Vanadium in particles and sediments of the northern Saronikos Gulf, Greece

This study provides data for total and non-residual vanadium distributions in the northern Saronikos Gulf and shows that close to the Athens sewage outfall (ASO), the combined domestic and industrial wastes have resulted in a considerable increase in concentrations of vanadium in sediments and suspended solids. This appears to be the main vanadium source in the area; a second major source is a fertilizer plant (FP) near the entrance of Piraeus Harbour (PH), the impact of which is also important. Atmospheric inputs from the Piraeus industrial site and frequent crude oil spillages from ships and land-based sources seem to contribute significantly to the observed vanadium distribution, which is clearly affected by the prevailing circulation of surface waters and winds. The high percentage of the 0.5NHCl-leachable vanadium fraction in the most polluted sediments, together with positive correlation with organic carbon and certain other trace metals (i.e. Ag, Co, Cr, Fe, Zn) and negative correlation coefficients with Al and Sc, indicate that a considerable portion of the vanadium is of "anthropogenic" origin not related to lithogenous particles. It enters the system in association with relatively large organic aggregates, either authigenic or derived from sewage. © 1989

Neutron activation patterning of archaeological materials at the National Centre for Scientific Research ‘Demokritos’: the case of black-on-red Neolithic pottery from Macedonia

International audienceA short history of the application of NAA in the characterization of archaeological materials at the National Center for Scientific Research 'Demokritos', Athens, is presented. NAA was first applied in archaeology in 1974 at the Radioanalytical Laboratory, and since 1989 has been one of the primary analytical techniques of the 'Demokritos' archaeometry programme. A case study is also presented, concerning chemical patterning of the black-on-red Neolithic pottery class from Macedonia. Four chemical groups were identified, each corresponding to a different area of production. It is shown that this standardized concept of pottery technology and style was spread out within at least eastern Macedonia

Neutron activation and X-ray analysis of "Thapsos Class" vases. An attempt to identify their origin

Instrumental neutron activation analysis and X-ray techniques have been applied for the determination of 24 major, minor and trace elements (Al, Ca, Cc, Co, Cr, Cs, Eu, Hf, Fe, K, La, Lu, Na, Rb, Sb, Sc, Si, Sm, Ta, Tb, Th, Ti, Yb and Zn) in three or four different groups of vases (Protocorinthian, Thapsos Class, Late Geometric Corinthian and Aigion Crater). A close agreement for all elements examined between the pottery specimens of all groups was found. The matching in chemical composition of the four groups of vases strongly suggests the same origin for all of them. © 1980 Academic Press Inc. (London) Ltd