High-pressure Methane Adsorption on Natural and Synthetic Zeolites

The adsorption isotherms of methane on synthetic (5A and 13X) and natural (Erionite) zeolites at different temperatures have been obtained through the use of a high-pressure volumetric adsorption apparatus over the pressure range 0–5 MPa. The isotherms have been analyzed on the basis of a statistical thermodynamic adsorption model, variation in the temperature allowing calculation of the isosteric heat of adsorption. The results show that these zeolites are highly efficient for methane storage at moderately low pressure (0.5–1 MPa)

High-Pressure Methane Adsorption on NaX and NaY Zeolites with Different Si/Al Ratios

One method of increasing the storage capacity of compressed natural gas, an alternative for vehicular fuel, is by adsorbing it on to microporous solids such as zeolites or activated carbons. NaX and NaY zeolites with different Si/Al ratios have been synthesized and characterized. Experimental adsorption isotherms for CH 4 on these zeolites have been obtained at different temperatures over a pressure range of 0–5 MPa using a high-pressure volumetric apparatus. Isosteric heats of adsorption have been estimated and the isotherms analyzed applying a statistical thermodynamic model. The efficiency of this solid as a methane storage system has been evaluated and compared with other sorbents. Encouraging results have been obtained