34 research outputs found
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The Effect of Ion Implanting on Hydrogen Entry into Metals
The effectiveness of platinum ion implanting in mitigating hydrogen entry into 4340 steel is measured and quantified. Data are presented to compare the extent of hydrogen absorption by the substrate during electrolytic hydrogen charging of platinum ion-implanted and unimplanted 4340 steel substrates. Several implanting conditions were used in processing the samples, and the surface-limited mass-transfer coefficient was calculated for each case and used to quantify the effectiveness of each treatment in reducing hydrogen absorption. It is shown that the underlying mechanism for reducing hydrogen absorption by platinum ion-implanted substrates is the catalytic effect of platinum that favors hydrogen evolution at the steel\u27s surface over hydrogen absorption by the metal. Although scattering experiments with low energy helium ions suggest that the platinum content in the first monolayer of platinum-implanted steels is small, the ability of Pt to catalyze the hydrogen evolution reaction is still strong enough to significantly reduce the quantity of hydrogen that enters the metal
The effects of cold working on sensitization and intergranular corrosion behavior of AISI 304 stainless steel
The effects of prior cold rolling of up to an 80 pct reduction in thickness on the sensitization-desensitization behavior of Type AISI 304 stainless steel and its susceptibility to intergranular corrosion have been studied by electrochemical potentiokinetic reactivation (EPR) and Strauss-test methods. The results indicate that the prior deformation accelerated the sensitization as compared to the undeformed stainless steel. The deformed Type 304 stainless steel experienced desensitization at higher temperatures and times, and it was found to be enhanced by increased cold deformation. This could be attributed to the increased long-range chromium diffusion, possibly brought on by increasing pipe diffusion and vacancies. The role of the deformation-induced martensite (DIM) and texture, introduced by uniaxial cold rolling, on the sensitization-desensitization kinetics has also been discussed. This study could not reveal any systematic relationship between texture and the degree of sensitization (DOS) obtained. The effect of DIM on DOS seems to be pronounced at 500 °C when the steel retained significant amounts of DIM; however, the retained DIM is insignificant at higher sensitization times and temperatures