5 research outputs found
Threshold photoelectron photoion coincidence spectroscopy of trichloroethene and tetrachloroethene
The threshold photoelectron, the threshold photoelectron photoion coincidence and ion breakdown spectra of trichloroethene and tetrachloroethene have been recorded from 9 – 22 eV. Comparisons with the equivalent data for the three dichloroethene molecules and theoretical calculations highlight the nature of the orbitals involved during photoionisation in this energy range. The ground electronic state of CHCl (CCl) is bound, with excited valence states dissociating to CHCl (CCl) and CHCl (CCl). Appearance energies suggest that CHCl forms from CHCl by loss of two chlorine atoms, whereas CCl forms from CCl by loss of a Cl molecule. The translational kinetic energy release into CHCl (CCl) + Cl is determined as a function of energy. In both cases, the fraction of the available energy released into translational energy of the two products decreases as the photon energy increases