5 research outputs found
Magnetic Field Effects on the Far-Infrared Absorption in Mn_12-acetate
We report the far-infrared spectra of the molecular nanomagnet Mn_12-acetate
(Mn_12) as a function of temperature (5-300 K) and magnetic field (0-17 T). The
large number of observed vibrational modes is related to the low symmetry of
the molecule, and they are grouped together in clusters. Analysis of the mode
character based on molecular dynamics simulations and model compound studies
shows that all vibrations are complex; motion from a majority of atoms in the
molecule contribute to most modes. Three features involving intramolecular
vibrations of the Mn_12 molecule centered at 284, 306 and 409 cm-1 show changes
with applied magnetic field. The structure near 284 cm displays the
largest deviation with field and is mainly intensity related. A comparison
between the temperature dependent absorption difference spectra, the gradual
low-temperature cluster framework distortion as assessed by neutron diffraction
data, and field dependent absorption difference spectra suggests that this mode
may involve Mn motion in the crown.Comment: 5 pages, 4 figures, PRB accepte
Enhancement of the upper critical field by nonmagnetic impurities in dirty two-gap superconductors
Quasiclassic Uzadel equations for two-band superconductors in the dirty limit
with the account of both intraband and interband scattering by nonmagnetic
impurities are derived for any anisotropic Fermi surface. From these equations
the Ginzburg-Landau equations, and the critical temperature are obtained.
An equation for the upper critical field, which determines both the temperature
dependence of and the orientational dependence of
as a function of the angle between and the c-axis is
obtained. It is shown that the shape of the curve essentially
depends on the ratio of the intraband electron diffusivities and ,
and can be very different from the standard one-gap dirty limit theory. In
particular, the value can considerably exceed ,
which can have important consequences for applications of . A scaling
relation is proposed which enables one to obtain the angular dependence of
from the equation for at . It is shown
that, depending on the relation between and , the ratio of the upper
critical field for and can both increase and decrease as the temperature decreases. Implications
of the obtained results for are discussed