3,471 research outputs found
Magnetic form factor of SrFeAs
Neutron diffraction measurements have been carried out to investigate the
magnetic form factor of the parent SrFe2As2 system of the iron-based
superconductors. The general feature is that the form factor is approximately
isotropic in wave vector, indicating that multiple d-orbitals of the iron atoms
are occupied as expected based on band theory. Inversion of the diffraction
data suggests that there is some elongation of the spin density toward the As
atoms. We have also extended the diffraction measurements to investigate a
possible jump in the c-axis lattice parameter at the structural phase
transition, but find no detectable change within the experimental
uncertainties
Evolution of the bulk properties, structure, magnetic order, and superconductivity with Ni doping in CaFe2-xNixAs2
Magnetization, susceptibility, specific heat, resistivity, neutron and x-ray
diffraction have been used to characterize the properties of single crystalline
CaFe2-xNixAs2 as a function of Ni doping for x varying from 0 to 0.1. The
combined first-order structural and magnetic phase transitions occur together
in the undoped system at 172 K, with a small decrease in the area of the a-b
plane along with an abrupt increase in the length of the c-axis in the
orthorhombic phase. With increasing x the ordered moment and transition
temperature decrease, but the transition remains sharp at modest doping while
the area of the a-b plane quickly decreases and then saturates. Warming and
cooling data in the resistivity and neutron diffraction indicate hysteresis of
~2 K. At larger doping the transition is more rounded, and decreases to zero
for x=0.06. The susceptibility is anisotropic for all values of x. Electrical
resistivity for x = 0.053 and 0.06 shows a superconducting transition with an
onset of nearly 15 K which is further corroborated by substantial diamagnetic
susceptibility. For the fully superconducting sample there is no long range
magnetic order and the structure remains tetragonal at all temperature, but
there is an anomalous increase in the area of the a-b plane in going to low T.
Heat capacity data show that the density of states at the Fermi level increases
for x > 0.053 as inferred from the value of Sommerfeld coefficient. The regime
of superconductivity is quite restrictive, with a maximum TC of 15 K and an
upper critical field Hc2=14 T. Superconductivity disappears in the overdoped
region.Comment: 14 pages, 12 figures. Submitted to Phys. Rev.
Short-range incommensurate magnetic order near the superconducting phase boundary in Fe(1+d)Te(1-x)Se(x)
We performed elastic neutron scattering and magnetization measurements on
Fe(1.07)Te(0.75)Se(0.25) and FeTe(0.7)Se(0.3). Short-range incommensurate
magnetic order is observed in both samples. In the former sample with higher Fe
content, a broad magnetic peak appears around (0.46,0,0.5) at low temperature,
while in FeTe(0.7)Se(0.3) the broad magnetic peak is found to be closer to the
antiferromagnetic (AFM) wave-vector (0.5,0,0.5). The incommensurate peaks are
only observed on one side of the AFM wave-vector for both samples, which can be
modeled in terms of an imbalance of ferromagnetic/antiferromagnetic
correlations between nearest-neighbor spins. We also find that with higher Se
(and lower Fe) concentration, the magnetic order becomes weaker while the
superconducting temperature and volume increase.Comment: Version as appeared in PR
First-order nature of the ferromagnetic phase transition in (La-Ca)MnO_3 near optimal doping
Neutron scattering has been used to study the nature of the ferromagnetic
transition in single crystals of La_0.7Ca_0.3MnO_3 and La_0.8Ca_0.2MnO_3, and
polycrystalline samples of La_0.67Ca_0.33MnO_3 and La_5/8Ca_3/8MnO_3 where the
naturally occurring O-16 can be replaced with the O-18 isotope. Small angle
neutron scattering on the x=0.3 single crystal reveals a discontinuous change
in the scattering at the Curie temperature for wave vectors below ~0.065 A^-1.
Strong relaxation effects are observed for this domain scattering, for the
magnetic order parameter, and for the quasielastic scattering, demonstrating
that the transition is not continuous in nature. There is a large oxygen
isotope effect observed for the T_C in the polycrystalline samples. For the
optimally doped x=3/8 sample we observed T_C(O-16)=266.5 K and T_C(O-18)=261.5
K at 90% O-18 substitution. The temperature dependence of the spin-wave
stiffness is found to be identical for the two samples despite changes in T_C.
Hence, T_C is not solely determined by the magnetic subsystem, but instead the
ferromagnetic phase is truncated by the formation of polarons which cause an
abrupt transition to the paramagnetic, insulating state. Application of
uniaxial stress in the x=0.3 single crystal sharply enhances the polaron
scattering at room temperature. Measurements of the phonon density-of-states
show only modest differences above and below T_C and between the two different
isotopic samples.Comment: 13 pages, 16 figures, submitted to Phys. Rev.
Neel to Spin-Glass-like Phase Transition versus Dilution in Geometrically Frustrated ZnCr_{2-2x}Ga_{2x}O_4
ZnCr2O4 undergoes a first order spin-Peierls-like phase transition at 12.5 K
from a cubic spin liquid phase to a tetragonal Neel state. Using powder
diffraction and single crystal polarized neutron scattering, we determined the
complex spin structure of the Neel phase. This phase consisted of several
magnetic domains with different characteristic wave vectors. This indicates
that the tetragonal phase of ZnCr2O4 is very close to a critical point
surrounded by many different Neel states. We have also studied, using elastic
and inelastic neutron scattering techniques, the effect of nonmagnetic dilution
on magnetic correlations in ZnCr_{2-2x}Ga_{2x}O_4 (x=0.05 and 0.3). For x=0.05,
the magnetic correlations do not change qualitatively from those in the pure
material, except that the phase transition becomes second order. For x= 0.3,
the spin-spin correlations become short range. Interestingly, the spatial
correlations of the frozen spins in the x=0.3 material are the same as those of
the fluctuating moments in the pure and the weakly diluted materials
Legacy Vehicle Fuel System Testing with Intermediate Ethanol Blends
The effects of E10 and E17 on legacy fuel system components from three common mid-1990s vintage vehicle models (Ford, GM, and Toyota) were studied. The fuel systems comprised a fuel sending unit with pump, a fuel rail and integrated pressure regulator, and the fuel injectors. The fuel system components were characterized and then installed and tested in sample aging test rigs to simulate the exposure and operation of the fuel system components in an operating vehicle. The fuel injectors were cycled with varying pulse widths during pump operation. Operational performance, such as fuel flow and pressure, was monitored during the aging tests. Both of the Toyota fuel pumps demonstrated some degradation in performance during testing. Six injectors were tested in each aging rig. The Ford and GM injectors showed little change over the aging tests. Overall, based on the results of both the fuel pump testing and the fuel injector testing, no major failures were observed that could be attributed to E17 exposure. The unknown fuel component histories add a large uncertainty to the aging tests. Acquiring fuel system components from operational legacy vehicles would reduce the uncertainty
Spectroscopy with random and displaced random ensembles
Due to the time reversal invariance of the angular momentum operator J^2, the
average energies and variances at fixed J for random two-body Hamiltonians
exhibit odd-even-J staggering, that may be especially strong for J=0. It is
shown that upon ensemble averaging over random runs, this behaviour is
reflected in the yrast states. Displaced (attractive) random ensembles lead to
rotational spectra with strongly enhanced BE2 transitions for a certain class
of model spaces. It is explained how to generalize these results to other forms
of collectivity.Comment: 4 pages, 4 figure
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