On a systematic approach to defects in classical integrable field theories

We present an inverse scattering approach to defects in classical integrable field theories. Integrability is proved systematically by constructing the generating function of the infinite set of modified integrals of motion. The contribution of the defect to all orders is explicitely identified in terms of a defect matrix. The underlying geometric picture is that those defects correspond to Backlund transformations localized at a given point. A classification of defect matrices as well as the corresponding defect conditions is performed. The method is applied to a collection of well-known integrable models and previous results are recovered (and extended) directly as special cases. Finally, a brief discussion of the classical $r$-matrix approach in this context shows the relation to inhomogeneous lattice models and the need to resort to lattice regularizations of integrable field theories with defects.Comment: 27 pages, no figures. Final version accepted for publication. References added and section 5 amende

Electronic and transport properties of rectangular graphene macromolecules and zigzag carbon nanotubes of finite length

We study one dimensional (1D) carbon ribbons with the armchair edges and the zigzag carbon nanotubes and their counterparts with finite length (0D) in the framework of the H\"{u}ckel model. We prove that a 1D carbon ribbon is metallic if its width (the number of carbon rings) is equal to $2+3n$. We show that the dispersion law (electron band energy) of a 1D metallic ribbon or a 1D metallic carbon nanotube has a universal {\it sin-}like dependence at the Fermi energy which is independent of its width. We find that in case of metallic graphene ribbons of finite length (rectangular graphene macromolecules) or nanotubes of finite length the discrete energy spectrum in the vicinity of $\varepsilon=0$ (Fermi energy) can be obtained exactly by selecting levels from the same dispersion law. In case of a semiconducting graphene macromolecule or a semiconducting nanotube of finite length the positions of energy levels around the energy gap can be approximated with a good accuracy. The electron spectrum of 0D carbon structures often include additional states at energy $\varepsilon=0$, which are localized on zigzag edges and do not contribute to the volume conductivity.Comment: 6 pages, 5 figure

An improved adsorption method for the characterization of water-based supercapacitor electrodes

The specific surface area is a key characteristic of carbon materials used in supercapacitor electrodes. In this paper, the use of a methylene blue technique for specific surface area determination is presented. Values for the specific surface area, determined by a new method, provide better correlation with theoretical values for the specific electrical capacity of highly-porous carbon electrodes than the values measured by the common BET method. Additionally, the methylene blue adsorption method is thought to characterize carbon adsorption activity in relation to a supercapacitor electrolyte

Integrable boundary conditions for classical sine-Gordon theory

The possible boundary conditions consistent with the integrability of the classical sine-Gordon equation are studied. A boundary value problem on the half-line $x\leq 0$ with local boundary condition at the origin is considered. The most general form of this boundary condition is found such that the problem be integrable. For the resulting system an infinite number of involutive integrals of motion exist. These integrals are calculated and one is identified as the Hamiltonian. The results found agree with some recent work of Ghoshal and Zamolodchikov.Comment: 10 pages, DTP/94-3