The role of attractive forces in viscous liquids

We present evidence from computer simulation that the slowdown of relaxation of a standard Lennard-Jones glass-forming liquid and that of its reduction to a model with truncated pair potentials without attractive tails is quantitatively and qualitatively different in the viscous regime. The pair structure of the two models is however very similar. This finding, which appears to contradict the common view that the physics of dense liquids is dominated by the steep repulsive forces between atoms, is characterized in detail, and its consequences are explored. Beyond the role of attractive forces themselves, a key aspect in explaining the differences in the dynamical behavior of the two models is the truncation of the interaction potentials beyond a cutoff at typical interatomic distance. This leads us to question the ability of the jamming scenario to describe the physics of glass-forming liquids and polymers.Comment: 13 pages, 12 figure

The viscous slowing down of supercooled liquids as a temperature-controlled superArrhenius activated process: a description in terms of frustration-limited domains

We propose that the salient feature to be explained about the glass transition of supercooled liquids is the temperature-controlled superArrhenius activated nature of the viscous slowing down, more strikingly seen in weakly-bonded, fragile systems. In the light of this observation, the relevance of simple models of spherically interacting particles and that of models based on free-volume congested dynamics are questioned. Finally, we discuss how the main aspects of the phenomenology of supercooled liquids, including the crossover from Arrhenius to superArrhenius activated behavior and the heterogeneous character of the $\alpha$ relaxation, can be described by an approach based on frustration-limited domains.Comment: 13 pages, 4 figures, accepted in J. Phys.: Condensed Matter, proceedings of the Trieste workshop on "Unifying Concepts in Glass Physics

Microphase Separation and modulated phases in a Coulomb frustrated Ising ferromagnet

We study a 3-dimensional Ising model in which the tendency to order due to short-range ferromagnetic interactions is frustrated by competing long-range (Coulombic) interactions. Complete ferromagnetic ordering is impossible for any nonzero value of the frustration parameter, but the system displays a variety of phases characterized by periodically modulated structures. We have performed extensive Monte-Carlo simulations which provide strong evidence that the microphase separation transition between paramagnetic and modulated phases is a fluctuation-induced first-order transition. Additional transitions to various commensurate phases may also occur when further lowering the temperature.Comment: 6 pages, 4 figures, accepted in Europhys. Letter

A unified picture of ferromagnetism, quasi-long range order and criticality in random field models

By applying the recently developed nonperturbative functional renormalization group (FRG) approach, we study the interplay between ferromagnetism, quasi-long range order (QLRO) and criticality in the $d$-dimensional random field O(N) model in the whole ($N$, $d$) diagram. Even though the "dimensional reduction" property breaks down below some critical line, the topology of the phase diagram is found similar to that of the pure O(N) model, with however no equivalent of the Kosterlitz-Thouless transition. In addition, we obtain that QLRO, namely a topologically ordered "Bragg glass" phase, is absent in the 3--dimensional random field XY model. The nonperturbative results are supplemented by a perturbative FRG analysis to two loops around $d=4$.Comment: 4 pages, 4 figure

Two-loop Functional Renormalization Group of the Random Field and Random Anisotropy O(N) Models

We study by the perturbative Functional Renormalization Group (FRG) the Random Field and Random Anisotropy O(N) models near $d=4$, the lower critical dimension of ferromagnetism. The long-distance physics is controlled by zero-temperature fixed points at which the renormalized effective action is nonanalytic. We obtain the beta functions at 2-loop order, showing that despite the nonanalytic character of the renormalized effective action, the theory is perturbatively renormalizable at this order. The physical results obtained at 2-loop level, most notably concerning the breakdown of dimensional reduction at the critical point and the stability of quasi-long range order in $d<4$, are shown to fit into the picture predicted by our recent non-perturbative FRG approach.Comment: 19 pages, 20 figures. Minor correction

Nonperturbative Functional Renormalization Group for Random Field Models. III: Superfield formalism and ground-state dominance

We reformulate the nonperturbative functional renormalization group for the random field Ising model in a superfield formalism, extending the supersymmetric description of the critical behavior of the system first proposed by Parisi and Sourlas [Phys. Rev. Lett. 43, 744 (1979)]. We show that the two crucial ingredients for this extension are the introduction of a weighting factor, which accounts for ground-state dominance when multiple metastable states are present, and of multiple copies of the original system, which allows one to access the full functional dependence of the cumulants of the renormalized disorder and to describe rare events. We then derive exact renormalization group equations for the flow of the renormalized cumulants associated with the effective average action.Comment: 28 page

Glass transition in granular media

In the framework of schematic hard spheres lattice models for granular media we investigate the phenomenon of the ``jamming transition''. In particular, using Edwards' approach, by analytical calculations at a mean field level, we derive the system phase diagram and show that ``jamming'' corresponds to a phase transition from a ``fluid'' to a ``glassy'' phase, observed when crystallization is avoided. Interestingly, the nature of such a ``glassy'' phase turns out to be the same found in mean field models for glass formers.Comment: 7 pages, 4 figure

Geometrical Frustration and Static Correlations in Hard-Sphere Glass Formers

We analytically and numerically characterize the structure of hard-sphere fluids in order to review various geometrical frustration scenarios of the glass transition. We find generalized polytetrahedral order to be correlated with increasing fluid packing fraction, but to become increasingly irrelevant with increasing dimension. We also find the growth in structural correlations to be modest in the dynamical regime accessible to computer simulations.Comment: 21 pages; part of the "Special Topic Issue on the Glass Transition