Tectonothermal evolution of the continental crust beneath the Yakutian diamondiferous province (Siberian craton) : U–Pb and Hf isotopic evidence on zircons from crustal xenoliths of kimberlite pipes

U–Pb age and Hf-isotope data were collected on zircons from crustal xenoliths from the Late Devonian kimberlite pipes of Markha terrane. The xenoliths include mafic garnet granulites (Gt+Pl+Cpx±Opx±Amp±Bt±Scp) and garnet–biotite gneisses (Grt+Bt+Pl+Kfs+Qtz±Scp). The data from this study demonstrate that the crust of the Markha terrane experienced several tectonothermal events. Zircons with Archean Hf model ages (TDM = 3.13–2.5 Ga) are predominant in all xenoliths with one exception. These data imply that most of the lower and middle crust beneath the Markha terrane was produced in the Archean time. Later this Paleoarchean crust was significantly reworked in several tectonothermal events, including a Neoarchean stage (2.9–2.5 Ga), and several Paleoproterozoic metamorphic stages (1.98, 1.9 and 1.8 Ga). There is very little evidence for generation of juvenile crust associated with these metamorphic events. Importantly, crustal xenoliths from kimberlite pipes of the Markha terrane record all the same events that occurred in the adjacent Daldyn and Magan terranes.20 page(s

Ore-bearing fluids of the Eldorado gold deposit (Yenisei Ridge, Russia)

Текст статьи не публикуется в открытом доступе в соответствии с политикой журнала.The Eldorado low-sulfide gold-quartz deposit, with gold reserves of more than 60 tons, is located in the damage zone of the Ishimba Fault in the Yenisei Ridge and is hosted by Riphean epidote-amphibolite metamorphic rocks (Sukhoi Pit Group). Orebodies occur in four roughly parallel heavily fractured zones where rocks were subject to metamorphism under stress and heat impacts. They consist of sulfide-bearing schists with veins of gray or milky-white quartz varieties. Gray quartz predominating in gold-bearing orebodies contains graphite and amorphous carbon identified by Raman spectroscopy; the contents of gold and amorphous carbon are in positive correlation. As inferred from thermobarometry, gas chromatography, gas chromatography-mass spectrometry, and Raman spectroscopy of fluid inclusions in sulfides, carbonates, and gray and white quartz, gold mineralization formed under the effect of reduced H2O-CO2-HC fluids with temperatures of 180 to 490 °C, salinity of 9 to 22 wt.% NaCl equiv, and pressures of 0.1 to 2.3 kbar. Judging by the presence of 11% mantle helium (3He) in fluid inclusions from quartz and the sulfur isotope composition (7.1-17.4‰ δ34S) of sulfides, ore-bearing fluids ascended from a mantle source along shear zones, where they “boiled”. While the fluids were ascending, the metalliferous S- and N-bearing hydrocarbon (HC) compounds they carried broke down to produce crystalline sulfides, gold, and disseminated graphite and amorphous carbon (the latter imparts the gray color to quartz). Barren veins of milky-white quartz formed from oxidized mainly aqueous fluids with a salinity of 30 wt.% NaCl equiv) at 150-260 °C impregnated the gold-bearing quartz veins and produced the lower strata of the hydrothermal-granitoid section. The gold mineralization (795-710 Ma) was roughly coeval to local high-temperature stress metamorphism (836-745 Ma) and intrusion of the Kalama multiphase complex (880-752 Ma)

Cr-rich rutile : a powerful tool for diamond exploration

Mineralogical studies and U–Pb dating have been carried out on rutile included in peridotitic and eclogitic garnets from the Internatsionalnaya pipe, Mirny field, Siberian craton. We also describe a unique peridotitic paragenesis (rutile + forsterite + enstatite + Cr-diopside + Cr-pyrope) preserved in diamond from the Mir pipe, Mirny field. Compositions of rutile from the heavy mineral concentrates of the Internatsionalnaya pipe and rutile inclusions in crustal almandine-rich garnets from the Mayskaya pipe (Nakyn field), as well as from a range of different lithologies, are presented for comparison. Rutile from cratonic mantle peridotites shows characteristic enrichment in Cr, in contrast to lower-Cr rutile from crustal rocks and off-craton mantle. Rutile with Cr₂O₃ > 1.7 wt% is commonly derived from cratonic mantle, while rutiles with lower Cr₂O₃ may be both of cratonic and off-cratonic origin. New analytical developments and availability of standards have made rutile accessible to in situ U–Pb dating by laser ablation ICP-MS. A U–Pb age of 369 ± 10 Ma for 9 rutile grains in 6 garnets from the Internatsionalnaya pipe is consistent with the accepted eruption age of the pipe (360 Ma). The equilibrium temperatures of pyropes with rutile inclusions calculated using Ni-in-Gar thermometer range between ~ 725 and 1030°C, corresponding to a depth range of ca ~ 100–165 km. At the time of entrainment in the kimberlite, garnets with Cr-rich rutile inclusions resided at temperatures well above the closure temperature for Pb in rutile, and thus U–Pb ages on mantle-derived rutile most likely record the emplacement age of the kimberlites. The synthesis of distinctive rutile compositions and U–Pb dating opens new perspectives for using rutile in diamond exploration in cratonic areas.8 page(s