Development of a 1 kW Gravitational Water Vortex Hydropower Plant Prototype

A pilot testing of a Gravitational Water Vortex Hydropower Plant (GWVHP) has been done to evaluate the applicability in a real-world scenario and validate the results from the lab-scale model. A scaled-up model of a capacity of 1 kW was constructed for the evaluation purpose. The test provided data in good agreement with a lab-scale model and a proper visualization to install Gravitational Water Vortex in real-world scenarios. The project lasted for nearly four months and thus provided important information on the problems that might arise in scaling up the lab model to a micro-hydro system. The pilot testing shows an overall plant efficiency of 49%, validating the lab-based studies conducted beforehand. The information obtained from this pilot study shall be implemented in a micro-hydro project on a larger scale

Radiometric Screening of Red Phosphorus Smoke for its Obscuration Characteristics

Red phosphorus and potassium nitrate-based compositions exhibit favorable smoke screenformation with high obscuration characteristics at low oxidiser content. The rapid vaporisationof excess red phosphorus at higher flame temperature leads to quick aerodispersion. Theobscuration characteristics are due to formation of P2O5 and subsequent reaction with moisture/humidity in the atmosphere. Obscuration increases with increasing humidity. Extinction coefficient,the shadow cast per unit mass of the composition, is higher in visible and comparatively lowerin far infrared

Testing the gravitational theory with short-period stars around our Galactic Center

Motion of short-period stars orbiting the supermassive black hole in our Galactic Center has been monitored for more than 20 years. These observations are currently offering a new way to test the gravitational theory in an unexplored regime: in a strong gravitational field, around a supermassive black hole. In this proceeding, we present three results: (i) a constraint on a hypothetical fifth force obtained by using 19 years of observations of the two best measured short-period stars S0-2 and S0-38 ; (ii) an upper limit on the secular advance of the argument of the periastron for the star S0-2 ; (iii) a sensitivity analysis showing that the relativistic redshift of S0-2 will be measured after its closest approach to the black hole in 2018.Comment: 4 pages, 2 figures, proceedings of the 52nd Rencontres de Moriond, Gravitation Sessio

The Glass Transition and Liquid-Gas Spinodal Boundaries of Metastable Liquids

A liquid can exist under conditions of thermodynamic stability or metastability within boundaries defined by the liquid-gas spinodal and the glass transition line. The relationship between these boundaries has been investigated previously using computer simulations, the energy landscape formalism, and simplified model calculations. We calculate these stability boundaries semi-analytically for a model glass forming liquid, employing accurate liquid state theory and a first-principles approach to the glass transition. These boundaries intersect at a finite temperature, consistent with previous simulation-based studies.Comment: Minor text revisions. Fig.s 4, 5 update

Mesoscale convection system and occurrence of extreme low tropopause temperatures: observations over Asian summer monsoon region

The present study examines the process of how tropospheric air enters the stratosphere, particularly in association with tropical mesoscale convective systems (TMCS) which are considered to be one of the causative mechanisms for the observation of extremely low tropopause temperature over the tropics. The association between the phenomena of convection and the observation of extreme low tropopause temperature events is, therefore, examined over the Asian monsoon region using data from multiple platforms. Satellite observations show that the area of low outgoing long wave radiation (OLR), which is a proxy for the enhanced convection, is embedded with high altitude clouds top temperatures (&le;193 K). A detailed analysis of OLR and 100 hPa temperature shows that both are modulated by westward propagating Rossby waves with a period of ~15 days, indicating a close linkage between them. The process by which the tropospheric air enters the stratosphere may, in turn, be determined by how the areas of convection and low tropopause temperature (LTT) i.e. <I>T</I>&le;191 K are spatially located. In this context, the relative spatial distribution of low OLR and LTT areas is examined. Though, the locations of low OLR and LTT are noticed in the same broad area, the two do not always overlap, except for partial overlap in some cases. When there are multiple low OLR areas, the LTT area generally appears in between the low OLR areas. Implications of these observations are also discussed. The present analysis also shows that the horizontal mean winds have a role in the spatial distribution of low OLR and LTT

Hydrogen storage in carbon nanotubes and related materials

Adsorption of hydrogen at 300 K has been investigated on well-characterized samples of carbon nanotubes, besides carbon fibres by taking care to avoid many of the pitfalls generally encountered in such measurements. The nanotube samples include single- and multi-walled nanotubes prepared by different methods, as well as aligned bundles of multi-walled nanotubes. The effect of acid treatment of the nanotubes has been examined. A maximum adsorption of ca. 3.7 wt% is found with aligned multi-walled nanotubes. Electrochemical hydrogen storage measurements have also been carried out on the nanotube samples and the results are similar to those found by gas adsorption measurements

Sex-disaggregated data matters: tracking the impact of COVID-19 on the health of women and men

Sex and gender matter to health outcomes, but despite repeated commitments to sex-disaggregate data in health policies and programmes, a persistent and substantial absence of such data remains especially in lower-income countries. This represents a missed opportunity for monitoring and identifying gender-responsive, evidence-informed solutions to address a key driver of the pandemic. In this paper we review the availability of national sex-disaggregated surveillance data on COVID-19 and examine trends on the testing-to-outcome pathway. We further analyse the availability of data according to the economic status of the country and investigate the determinants of sex differences, including the national gender inequality status (according to a global index) in each country. Results are drawn from 18 months of global data collection from over 200 countries. We find differences in COVID-19 prevention behaviours and illness outcomes by sex, with lower uptake of vaccination and testing plus an elevated risk of severe disease and death among men. Supporting and maintaining the collection, collation, interpretation and presentation of sex-disaggregated data requires commitment and resources at subnational, national and global levels, but provides an opportunity for identifying and taking gender-responsive action on health inequities. As a first step the global health community should recognise, value and support the importance of sex-disaggregated data for identifying and tackling an inequitable pandemic

Synthesis, x-ray crystal structures and biological evaluation of some mono- and bi-cyclic 1,3-diazetidin-2-ones: non-natural β -lactam analogues

Mono- and bi-cyclic 1,3-diazetidin-2-ones (aza-&#946; -lactams) are synthesised and evaluated as non-natural analogues of &#946; -lactams. The aza-&#946; -lactams are designed on the principle that their reaction with active site serine hydroxy will form a carbamoyl-enzyme intermediate that is sluggish to hydrolysis. The synthesis of racemic mono- and bi-cyclic aza-&#946; -lactams is carried out starting from pyrimidinone 18 which is transformed to the densely functionalised substrate 20. The chemical reactivity of tricarbonyl 20 for selective functional group manipulation was first assessed and then it was transformed to amino alcohol 24. Cyclisation of 24 affords aza-carbapenams and its homologation followed by aldol cyclisation provides access to aza-carbacephams. The X-ray structures of aza-carbapenam 35 and aza-carbacepham 42 suggest that the structural requirements for biological activity in &#946; -lactams are fulfilled. An unexpected ozonolysis product, phenol 52 resolves spontaneously during crystallisation and its crystal structure was also determined. The biological activity of the novel mono- and bi-cyclic aza-&#946; -lactams was evaluated with potent gram-positive bacterial strain, Bacillus subtilis and compared with &#946; -lactam antibiotics, ampicillin and penicillin G. Of the 19 aza-&#946; -lactams tested, eight compounds show inhibition better than the standards while another eight are of comparable activity. This study shows that aza-&#946; -lactams represent a novel and non-natural lead towards serine peptidase inhibitors

Electrical properties of inorganic nanowire-polymer composites

Composites of nanowires of ZnO, RuO2 and Ag with polyaniline (PANI) as well as polypyrrole (PPy) have been prepared, for the first time, by an in-situ process, in order to investigate their electrical properties. Characterization by electron microscopy and IR spectroscopy indicates that there is considerable interaction between the oxide nanowires and the polymer. The room-temperature resistivity of the composites prepared in-situ varies in the 0.01-400 Ω cm range depending on the composition. While the resistivities of the PANI-ZnONW and PPy-ZnONW composites prepared by the in-situ process are generally higher than that of PANI/PPy, those of PANI-RuO2NW and PANI-AgNW are lower. Composites of ZnONW with polyaniline prepared by an ex-situ process exhibit a resistivity close to that of polyaniline