3 research outputs found
Multiphoton Transitions in a Spin System Driven by Strong Bichromatic Field
EPR transient nutation spectroscopy is used to measure the effective field
(Rabi frequency) for multiphoton transitions in a two-level spin system
bichromatically driven by a transverse microwave (MW) field and a longitudinal
radio-frequency (RF) field. The behavior of the effective field amplitude is
examined in the case of a relatively strong MW field, when the derivation of
the effective Hamiltonian cannot be reduced to first-order perturbation theory
in w_{1} / w_{rf} (w_{1} is the microwave Rabi frequency, w_{rf} is the RF
frequency). Experimental results are consistently interpreted by taking into
account the contributions of second and third order in w_{1} / w_{rf} evaluated
by Krylov-Bogolyubov-Mitropolsky averaging. In the case of inhomogeneously
broadened EPR line, the third-order correction modifies the nutation frequency,
while the second-order correction gives rise to a change in the nutation
amplitude due to a Bloch-Siegert shift.Comment: 7 pages, 6 figure
On the Theory of Vibronic Superradiance
The Dicke superradiance on vibronic transitions of impurity crystals is
considered. It is shown that parameters of the superradiance (duration and
intensity of the superradiance pulse and delay times) on each vibronic
transition depend on the strength of coupling of electronic states with the
intramolecular impurity vibration (responsible for the vibronic structure of
the optical spectrum in the form of vibrational replicas of the pure electronic
line) and on the crystal temperature through the Debye-Waller factor of the
lattice vibrations. Theoretical estimates of the ratios of the time delays, as
well as of the superradiance pulse intensities for different vibronic
transitions well agree with the results of experimental observations of
two-color superradiance in the polar dielectric KCl:O2-. In addition, the
theory describes qualitatively correctly the critical temperature dependence of
the superradiance effect.Comment: 8 pages, 1 figur
Effective Field and the Bloch-Siegert Shift at Bihromatic Excitation of Multiphoton EPR
The dynamics of multiphoton transitions in a two-level spin system excited by
transverse microwave and longitudinal RF fields with the frequencies w_{mw} and
w_{rf}, respectively, is analyzed. The effective time-independent Hamiltonian
describing the "dressed" spin states of the "spin + bichromatic field" system
is obtained by using the Krylov-Bogoliubov-Mitropolsky averaging method. The
direct detection of the time behavior of the spin system by the method of
nonstationary nutations makes it possible to identify the multiphoton
transitions for resonances w_{0} = w_{mw} + rw_{rf} (w_{0} is the central
frequency of the EPR line, r = 1, 2), to measure the amplitudes of the
effective fields of these transitions, and to determine the features generated
by the inhomogeneous broadening of the EPR line. It is shown that the
Bloch-Siegert shifts for multiphoton resonances at the inhomogeneous broadening
of spectral lines reduce only the nutation amplitude but do not change their
frequencies.Comment: 6 pages, 5 figure