Proton configurations in the hydrogen bonds of KH2PO4 as seen by resonant x-ray diffraction

KH2PO4 (KDP) belongs to the class of hydrogen-bonded ferroelectrics, whose paraelectric to ferroelectric phase transition is driven by the ordering of the protons in the hydrogen bonds. We demonstrate that forbidden reflections of KDP, when measured at an x-ray absorption edge, are highly sensitive to the asymmetry of proton configurations. The change of average symmetry caused by the "freezing" of the protons during the phase transition is clearly evidenced. In the paraelectric phase, we identify in the resonant spectra of the forbidden reflections a contribution related to the transient proton configurations in the hydrogen bonds, which violates the high average symmetry of the sites of the resonant atoms. The analysis of the temperature dependence reveals a change of relative probabilities of the different proton configurations. They follow the Arrhenius law, and the activation energies of polar and Slater configurations are 18.6 and 7.3 meV, respectively

Pushchino multibeams pulsar search. IV. Detection of new pulsars at declinations -9o < \delta < +55o

The search for pulsars in monitoring data obtained at the radio telescope Large Phased Array (LPA) at a frequency of 111 MHz was carried out. Daily round-the-clock observations were carried out for about 3,000 days. The duration of the observation session for each direction in the sky was 3.5 minutes per day. The search for pulsars was carried out using power spectra. To search for weak pulsars, power spectra were summed up. The expected increase in sensitivity was 35-40 times compared to observations in one session. In a blind search, 330 pulsars with regular radiation were detected, with periods (P) from 0.0333 to 3.7455 s and dispersion measures (DM) up to 249 pc/cm3. 39 pulsars turned out to be new. Average profiles were obtained for 6 pulsars. The DM for 7 pulsars previously detected on the LPA have been clarified.Comment: published in MNRAS, 13 pages, 4 figures, 4 tables, 4 appendixe