34,257 research outputs found
Locating transition states using double-ended classical trajectories
In this paper we present a method for locating transition states and
higher-order saddles on potential energy surfaces using double-ended classical
trajectories. We then apply this method to 7- and 8-atom Lennard-Jones
clusters, finding one previously unreported transition state for the 7-atom
cluster and two for the 8-atom cluster.Comment: Journal of Chemical Physics, 13 page
Magnetization of La(2-x)Sr(x)NiO(4+ delta) (0 < x < 0.5) and observation of novel memory effects
We have studied the magnetization of a series of spin-charge ordered
La(2-x)Sr(x)NiO(4+delta) single crystals with 0 < x < 0.5. For fields applied
parallel to the ab plane there is a large irreversibility below a temperature
T(F1) ~ 50 K and a smaller irreversibility that persists up to near the charge
ordering temperature. We observed a novel memory effect in the thermo-remnant
magnetization across the entire doping range. We found that these materials
retain a memory of the temperature at which an external field was removed, and
that there is a pronounced increase in the thermo-remnant magnetization when
the system is warmed through a spin reorientation transition.Comment: 11 pages, 12 figure
Resistivity network and structural model of the oxide cathode for CRT application
In this paper, the electrical properties of oxide cathode
and oxide cathode plus, supplied by LG Philips Displays, have been
investigated in relation to different cathode activation regimes and
methods. Oxide cathode activation treatment for different durations
has been investigated. The formations of the compounds associated
to the diffusion of reducing elements (Mg, Al, and W) to the Ni cap surface of oxide cathode were studied by a new suggestion method. Scanning electron microscopy (SEM) coupled with energy dispersive X-ray spectroscopy (EDX) was used as analytical techniques.
Al, W, and Mg doping elements take place during heating to 1080 K (Ni-Brightness) under a rich controlled Ba–SrO atmosphere through an acceleration life test. The chemical transport of these elements was occurred mainly by the Ni cap grain boundary mechanism with significant pile-up of Mg compounds. Al and W show a superficial concentrations and distribution.
A new structural and resistivity network model of oxide cathode plus are suggested. The new structural model shows a number of metallic and metallic oxide pathways are exist at the interface or extended through the oxide coating. The effective values of the resistances
and the type of the equivalent circuit in the resistivity network
model are temperature and activation time dependent.</p
Magnetic groundstate and Fermi surface of bcc Eu
Using spin-spiral technique within the full potential linearized
augmented-plane-waves (LAPW) electronic structure method we investigate the
magnon spectrum and N\'eel temperature of bcc Eu. Ground state corresponding to
an incommensurate spin-spiral is obtained in agreement with experiment and
previous calculations. We demonstrate that the magnetic coupling is primarily
through the intra-atomic and exchange and
Ruderman-Kittel-Kasuya-Yosida mechanism. We show that the existence of this
spin-spiral is closely connected to a nesting feature of the Fermi surface
which was not noticed before.Comment: 6 pages 8 figure
Magnetically Mediated Transparent Conductors: InO doped with Mo
First-principles band structure investigations of the electronic, optical and
magnetic properties of Mo-doped InO reveal the vital role of magnetic
interactions in determining both the electrical conductivity and the
Burstein-Moss shift which governs optical absorption. We demonstrate the
advantages of the transition metal doping which results in smaller effective
mass, larger fundamental band gap and better overall optical transmission in
the visible -- as compared to commercial Sn-doped InO. Similar behavior
is expected upon doping with other transition metals opening up an avenue for
the family of efficient transparent conductors mediated by magnetic
interactions
Phase changes in selected Lennard-Jones X_{13-n}Y_n clusters
Detailed studies of the thermodynamic properties of selected binary
Lennard-Jones clusters of the type X_{13-n}Y_n (where n=1,2,3) are presented.
The total energy, heat capacity and first derivative of the heat capacity as a
function of temperature are calculated by using the classical and path integral
Monte Carlo methods combined with the parallel tempering technique. A
modification in the phase change phenomena from the presence of impurity atoms
and quantum effects is investigated.Comment: 14 pages, 13 figures. submitted to J. Chem. Phy
The Temperature Evolution of the Out-of-Plane Correlation Lengths of Charge-Stripe Ordered La(1.725)Sr(0.275)NiO(4)
The temperature dependence of the magnetic order of stripe-ordered
La(1.725)Sr(0.275)NiO(4) is investigated by neutron diffraction. Upon cooling,
the widths if the magnetic Bragg peaks are observed to broaden. The degree of
broadening is found to be very different for l = odd-integer and l =
even-integer magnetic peaks. We argue that the observed behaviour is a result
of competition between magnetic and charge order.Comment: 3 figure
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