69 research outputs found
Thermal properties comparison of hybrid CF/FF and BF/FF cyanate ester-based composites
[EN] Insights within thermal expansion, conductivity, and decomposition dependencies with temperature on symmetrical and
unsymmetrical layered carbon (CF) or basalt (BF) fabrics in combination with flax fibers (FF) were approached. Driven by
commercial application and environmental concerns, the paper draws attention on a modified formula of cyanate ester with
a common epoxy resin under an optimized ratio of 70:30 (vol%) as well as on the hybrid reinforcements stacking
sequences. Synergetic effects were debated in terms of the CF and BF stacking sequences and corresponding volume
fraction followed by comparisons with values predicted by the deployment of hybrid mixtures rules (RoHM/iRoHM). CF
hybrid architectures revealed enhanced effective thermophysical properties over their BF counterparts and both over the
FF-reinforced polymer composite considered as a reference. Thermal conductivities spread between 0.116 and
0.299 W m-1 K-1 from room temperature up to 250 C on all hybrid specimens, giving rise to an insulator character.
Concerning the coefficient of thermal expansion, CF hybrid architectures disclosed values of 1.236 10-6 K-1 and
3.102 10-6 K-1 compared with BF affine exhibiting 4.794 10-6 K-1 and 6.245 10-6 K-1, respectively, with an increase
in their volume fraction.The corresponding author gratefully acknowledges the financial assistance of German Academic Exchange Service-DAAD that enabled and supported the internship with Fraunhofer Research Institution for Polymeric Materials and Composites-PYCO, Germany. Many thanks go to Dr. Christian Dreyer and Dr. Maciej Gwiazda for the resin formula and access to the composite manufacturing technology.Motoc, DL.; FerrĂĄndiz Bou, S.; Balart, R. (2018). Thermal properties comparison of hybrid CF/FF and BF/FF cyanate ester-based composites. Journal of Thermal Analysis and Calorimetry. 133(1):509-518. https://doi.org/10.1007/s10973-018-7222-yS5095181331Assarar M, Zouari W, Sabhi H, Ayad R, Berthelot J-M. Evaluation of the damping of hybrid carbonâflax reinforced composites. Compos Struct. 2015;132:148â54.Duc F, Bourban PE, Plummer CJG, MĂ„nson JAE. Damping of thermoset and thermoplastic flax fibre composites. Compos A Appl Sci Manuf. 2014;64:115â23.Saba N, Jawaid M, Alothman OY, Paridah MT. A review on dynamic mechanical properties of natural fibre reinforced polymer composites. Constr Build Mater. 2016;106:149â59.Tian H, Zhang S, Ge X, Xiang A. Crystallization behaviors and mechanical properties of carbon fiber-reinforced polypropylene composites. J Therm Anal Calorim. 2017;128(3):1495â504.Alvarez V, Rodriguez E, VĂĄzquez A. Thermaldegradation and decomposition of jute/vinylester composites. J Therm Anal Calorim. 2006;85(2):383â9.Manfredi LB, RodrĂguez ES, Wladyka-Przybylak M, VĂĄzquez A. Thermal degradation and fire resistance of unsaturated polyester, modified acrylic resins and their composites with natural fibres. Polym Degrad Stab. 2006;91(2):255â61.Lazko J, Landercy N, Laoutid F, Dangreau L, Huguet MH, Talon O. Flame retardant treatments of insulating agro-materials from flax short fibres. Polym Degrad Stab. 2013;98(5):1043â51.Bar M, Alagirusamy R, Das A. Flame retardant polymer composites. Fibers Polym. 2015;16(4):705â17.Kollia E, Loutas T, Fiamegkou E, Vavouliotis A, Kostopoulos V. Degradation behavior of glass fiber reinforced cyanate ester composites under hydrothermal ageing. Polym Degrad Stab. 2015;121:200â7.Jawaid M, Abdul Khalil HPS. Cellulosic/synthetic fibre reinforced polymer hybrid composites: a review. Carbohyd Polym. 2011;86(1):1â18.Azwa ZN, Yousif BF, Manalo AC, Karunasena W. A review on the degradability of polymeric composites based on natural fibres. Mater Des. 2013;47:424â42.H-y Cheung, M-p Ho, K-t Lau, Cardona F, Hui D. Natural fibre-reinforced composites for bioengineering and environmental engineering applications. Compos B Eng. 2009;40(7):655â63.Dittenber DB, GangaRao HVS. Critical review of recent publications on use of natural composites in infrastructure. Compos A Appl Sci Manuf. 2012;43(8):1419â29.Faruk O, Bledzki AK, Fink H-P, Sain M. Biocomposites reinforced with natural fibers: 2000â2010. Prog Polym Sci. 2012;37(11):1552â96.Praveen RS, Jacob S, Murthy CRL, Balachandran P, Rao YVKS. Hybridization of carbonâglass epoxy composites: an approach to achieve low coefficient of thermal expansion at cryogenic temperatures. Cryogenics. 2011;51(2):95â104.Jawaid M, Abdul Khalil HPS, Alattas OS. Woven hybrid biocomposites: dynamic mechanical and thermal properties. Compos A Appl Sci Manuf. 2012;43(2):288â93.Swolfs Y, Gorbatikh L, Verpoest I. Fibre hybridisation in polymer composites: a review. Compos A Appl Sci Manuf. 2014;67:181â200.Rojo E, Alonso MV, Oliet M, Del Saz-Orozco B, Rodriguez F. Effect of fiber loading on the properties of treated cellulose fiber-reinforced phenolic composites. Compos B Eng. 2015;68:185â92.LeGault M. Natural fiber composites: market share, one part at the time. Compos World. 2016;5(2):68â75.Joshi SV, Drzal LT, Mohanty AK, Arora S. Are natural fiber composites environmentally superior to glass fiber reinforced composites? Compos A Appl Sci Manuf. 2004;35(3):371â6.Wambua P, Ivens J, Verpoest I. Natural fibres: can they replace glass in fibre reinforced plastics? Compos Sci Technol. 2003;63(9):1259â64.Bertomeu D, GarcĂa-Sanoguera D, Fenollar O, Boronat T, Balart R. Use of eco-friendly epoxy resins from renewable resources as potential substitutes of petrochemical epoxy resins for ambient cured composites with flax reinforcements. Polym Compos. 2012;33(5):683â92.Alam M, Akram D, Sharmin E, Zafar F, Ahmad S. Vegetable oil based eco-friendly coating materials: a review article. Arab J Chem. 2014;7(4):469â79.Bakare FO, Ramamoorthy SK, Ă
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Low-energy particle events associated with sector boundaries
Onsets of some 40 to 45 low-energy proton events during the years 1957â1969 coincided in time with transits of well-defined sector boundaries across the Earth. These events can be interpreted as long-lived proton streams filling up some of the magnetic sectors, indicating an acceleration of protons which is not associated with typical proton-producing flares. The sharp onsets of these particle streams, as well as a deficiency of flare-associated particle events shortly before the boundary transit, indicate that in some cases magnetic sector boundaries can inhibit transverse propagation of low-energy particles in the solar corona or in interplanetary space.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/43744/1/11207_2004_Article_BF00155310.pd
Increased epithelial cell proliferation in the ileal pouch mucosa of patients with familial adenomatous polyposis
To eliminate the risk of colorectal cancer in patients with familial adenomatous polyposis (FAP), reconstructive proctocolectomy is performed. Although most colonic mucosa is resected during the ileal pouch anal anastomosis, adenomas and carcinomas may develop in the pouch. This may be caused by altered cell kinetics due to intraluminal changes in the pouch. In 32 patients with FAP, biopsy specimens from the mucosa of the pouch and also of the afferent ileal loop were taken. Tissue sections were immunohistochemically processed with the monoclonal antibodies M30 and MIB-1 to assess apoptotic and proliferative indices, respectively. Cell proliferation was also assessed by a modified sign test. There were no significant differences in apoptotic rates between the mucosa of the pouch and the mucosa of the afferent ileal loop. However, cell proliferation was significantly higher in the mucosa of the pouch vs afferent ileal loop, both by using the quantitative (68.3% vs 61.6%, pâ=â0.001) and semiquantitative methods (pâ<â0.05). Our newly developed semiquantitative approach outperformed previously described methods. The higher cell proliferation in the pouch as compared to the afferent ileal loop may contribute to the increased risk for adenomas and carcinomas in the pouch of patients with FAP and emphasizes the need for regular endoscopic surveillance
Interaction management between social agents and human
In this paper we address the problem of managing social interactions between a human user and a set of social agents in structured environments. These agents have to regulate a measurable characteristic of the user. Our study focuses mainly therapeutic, caring for elderly people and assessment applications. The agent concept considered in this study is suitable for multi-robot systems (physical, service, mobile or not), but also to virtual agents (avatars) in a virtual reality (VR) application. The proposed approach has been adapted for an application of social phobia treatment using virtual reality. Thus, we conducted a case study to show the effectiveness of our contribution
Measurement of thermal properties of brick materials based on clay mixtures
International audienceThermal properties of building materials such as clay used in construction are measured using transient and steady state hot-plate and flash methods. The experimental methods are applied to measure the thermal properties of clay samples. The estimation of these thermal characteristics is based on a one dimensional model. A tridimensional model of the heat transfer in the system is considered to determine the validity conditions of the one dimensional model used to represent the center temperature. The use of a brick as a thermal insulating material requires prior knowledge of all its thermal properties. For that purpose, we have conducted an experimental study in order to characterize the thermal properties of brick samples, coming from the Moroccan Slaouiâs factory. The thermal diffusivity ââaââ, specific heat ââcââ and thermal conductivity ââλââ of this clay are experimentally obtained and their values are reported for design purposes. Finally, a comparative study based on different experimental methods is performed and the measurements are compared. The error estimations are found less than 3%
Modified AM2 with the hydrolysis step and the ammonium consideration
We have introduced a hydrolysis step to the AM2 which is considered as an important phase in the anaerobic digestion process when particulate organic substrates are to be degraded. Furthermore, we have considered ammonium as an additional state variable and its contribution to the alkalinity of the solution, while preserving the simplicity of the model. Simulations and comparisons with the ADM1 show satisfactory results. In the following we will call the modified model AM2 as the AM2H and the AM2HN to distinguish between the model with the introduction of the hydrolysis step and the one with the ammonium consideration respectively
Chemical Composition and Antibacterial Activity of the Essential Oil of Spirulina platensis from Morocco
Samples of Spirulina platensis were collected from Lake Foum Elouad, Laayoune (South of Morocco) and cultivated using ZarroukÂżs synthetic medium in the laboratory. The essential oil was isolated by hydrodistillation and analysed by GC/FID and GC/MS. The average yield oil obtained was 0.9%. A total of 66 compounds, amounting 96.7 % of the essential oils, were identified. The major components of S. platensis essential oils were heptadecane (41.7 %), tetradecane (25.3 %), ethyl benzene (5.5 %) and 6-methyl-5-hepten-2- one (3.7 %). Interestingly, it has been reported for the first time in the Moroccan Spirulina, the presence of geosmin, which is a very important component of odour in cyanobacteria. To our knowledge, the geosmin was not found in any S. platensis essential oils before. The antibacterial activity of the essential oil was evaluated against six strains. The most potent effect of the essential oil was obtained against two Gram (+) bacteria: B. antharcis, S. epidermidis and the Gram (-) bacteria E. coli (with the higher inhibition zone as 28 mm). The MICs were respectively 16.37, 19.13 and 17.81 ÂżL/mL. A total inhibition was shown for S. aureus. Thus the essential oil of S. platensis possess effective antimicrobial properties.The authors thank the Moroccan Foundation forAdvanced Science Innovation and Research(MAScIR) for the characterization and theidentification of the strain
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