Enhanced uptake of water by oxidatively processed oleic acid

International audienceA quartz crystal microbalance apparatus has been used to measure the room temperature uptake of water vapour by thin films of oleic acid as a function of relative humidity, both before and following exposure of the films to various partial pressures of gas phase ozone. A rapid increase in the water-sorbing ability of the film is observed as its exposure to ozone is increased, followed by a plateau region in which additional water is taken up more gradually. In this fully-processed region the mass of water taken up by the film is about 4 times that of the unprocessed film. Infrared spectra of the films, measured after variable exposures to ozone, show dramatic increases in both the "free" and hydrogen-bonded O-H stretching regions, and a decrease in the intensity of olefinic features. These results are consistent with the formation of an oxygenated polymeric product or products, as well as the gas phase products previously identified

Donaldson-Thomas invariants and wall-crossing formulas

Notes from the report at the Fields institute in Toronto. We introduce the Donaldson-Thomas invariants and describe the wall-crossing formulas for numerical Donaldson-Thomas invariants.Comment: 18 pages. To appear in the Fields Institute Monograph Serie

Forward and Inverse Processing in Electromagnetic NDE Using Squid

Electromagnetic NDE has been successfully applied to the detection of surface cracks and is routinely used to locate flaws in airframes, pipelines and in steel offshore oil platforms. However, there are still many problems to be solved, particularly in the aviation industry, which require the detection of deeper flaws such as corrosion in multi-layered structures and cracks around rivet holes which are obscured by the head of the rivet. Most systems use coils as detectors (though Hall probes are occasionally used), which have low sensitivity at low frequencies due to the fact that the induced voltage is proportional to the rate of change of magnetic flux through the coil. Unfortunately it is necessary to use low frequencies to detect deep subsurface flaws on account of the skin-depth effect, otherwise the electromagnetic field cannot propagate down to the depth of the flaw. SQUID (Superconducting Quantum Interference Device) sensors are ideally suited to overcome the deficiencies of coils, because they are primarily detectors of magnetic flux which, together with their high sensitivity, makes the detection of deep flaws more likely. SQUIDs have been successfully used for measuring very low magnetic fields, particularly in the field of biomagnetism, and it is hoped to exploit this sensitivity to detect flaws at large stand-off distances for example in pipelines which are surrounded by thick layers of cladding

Khovanov homology is an unknot-detector

We prove that a knot is the unknot if and only if its reduced Khovanov cohomology has rank 1. The proof has two steps. We show first that there is a spectral sequence beginning with the reduced Khovanov cohomology and abutting to a knot homology defined using singular instantons. We then show that the latter homology is isomorphic to the instanton Floer homology of the sutured knot complement: an invariant that is already known to detect the unknot.Comment: 124 pages, 13 figure

Interactions of asbestos-activated macrophages with an experimental fibrosarcoma

Supernatants from in vivo asbestos-activated macrophages failed to show any cytostatic activity against a syngeneic fibrosarcoma cell line in vitro. UICC chrysotile-induced peritoneal exudate cells also failed to demonstrate any growth inhibitory effect on the same cells in Winn assays of tumor growth. Mixing UICC crocidolite with inoculated tumor cells resulted in a dose-dependent inhibition of tumor growth; this could, however, be explained by a direct cytostatic effect on the tumor cells of high doses of crocidolite, which was observed in vitro

I-Brane Inflow and Anomalous Couplings on D-Branes

We show that the anomalous couplings of $D$-brane gauge and gravitational fields to Ramond-Ramond tensor potentials can be deduced by a simple anomaly inflow argument applied to intersecting $D$-branes and use this to determine the eight-form gravitational coupling.Comment: 8 pages, harvmac, no figure

On semistable principal bundles over a complex projective manifold, II

Let (X, \omega) be a compact connected Kaehler manifold of complex dimension d and E_G a holomorphic principal G-bundle on X, where G is a connected reductive linear algebraic group defined over C. Let Z (G) denote the center of G. We prove that the following three statements are equivalent: (1) There is a parabolic subgroup P of G and a holomorphic reduction of the structure group of E_G to P (say, E_P) such that the bundle obtained by extending the structure group of E_P to L(P)/Z(G) (where L(P) is the Levi quotient of P) admits a flat connection; (2) The adjoint vector bundle ad(E_G) is numerically flat; (3) The principal G-bundle E_G is pseudostable, and the degree of the charateristic class c_2(ad(E_G) is zero.Comment: 15 page

Development of a new laser Doppler velocimeter for the Ames High Reynolds Channel No. 2

A new two-channel laser Doppler velocimeter developed for the Ames High Reynolds Channel No. 2 is described. Design features required for the satisfactory operation of the optical system in the channel environment are discussed. Fiber optics are used to transmit the megahertz Doppler signal to the photodetectors located outside the channel pressure vessel, and provision is made to isolate the optical system from pressure and thermal strain effects. Computer-controlled scanning mirrors are used to position the laser beams in the channel flow. Techniques used to seed the flow with 0.5-micron-diam polystyrene spheres avoiding deposition on the test-section windows and porous boundary-layer removal panels are described. Preliminary results are presented with a discussion of several of the factors affecting accuracy

Chern-Simons Solitons, Toda Theories and the Chiral Model

The two-dimensional self-dual Chern--Simons equations are equivalent to the conditions for static, zero-energy solutions of the $(2+1)$-dimensional gauged nonlinear Schr\"odinger equation with Chern--Simons matter-gauge dynamics. In this paper we classify all finite charge $SU(N)$ solutions by first transforming the self-dual Chern--Simons equations into the two-dimensional chiral model (or harmonic map) equations, and then using the Uhlenbeck--Wood classification of harmonic maps into the unitary groups. This construction also leads to a new relationship between the $SU(N)$ Toda and $SU(N)$ chiral model solutions

On the origin of the λ\lambda-transition in liquid Sulphur

Developing a novel experimental technique, we applied photon correlation spectroscopy using infrared radiation in liquid Sulphur around $T_\lambda$, i.e. in the temperature range where an abrupt increase in viscosity by four orders of magnitude is observed upon heating within few degrees. This allowed us - overcoming photo-induced and absorption effects at visible wavelengths - to reveal a chain relaxation process with characteristic time in the ms range. These results do rehabilitate the validity of the Maxwell relation in Sulphur from an apparent failure, allowing rationalizing the mechanical and thermodynamic behavior of this system within a viscoelastic scenario.Comment: 5 pages, 4 eps figures, accepted in Phys. Rev. Let