Effect of production conditions of the size distribution of particles of ultrafine cobalt

Translated from Russian (Fiz. Khim. Obra. Mater. 1998 (3) 108-112)Available from British Library Document Supply Centre-DSC:9023.190(10076)T / BLDSC - British Library Document Supply CentreSIGLEGBUnited Kingdo

X-ray Fluorescence Spectroscopy Features of Micro- and Nanoscale Copper and Nickel Particle Compositions

The study is devoted to X-ray fluorescence spectroscopy (XRF) features of micro- and nanosized powder mixtures of copper and nickel. XRF is a high accuracy method that allows for both qualitative and quantitative analysis. However, the XRF measurement error due to the size of the studied particles is not usually taken into account, which limits the use of the method in some cases, such as analysis of Ni-Cu mixtures and coatings. In this paper, a method for obtaining copper and nickel nanoparticles was investigated, and the XRF of powder compositions was considered in detail. The initial micro- and nanoparticles of copper and nickel were studied in detail using SEM, TEM, XRD, and EDX. Based on experimental data, calibration curves for copper-nickel powder compositions of various sizes were developed. According to the results, it was experimentally established that the calibration curves constructed for nanoscale and microscale powders differ significantly. The presented approach can be expanded for other metals and particle sizes

Characterization of Multiphase Oxide Layer Formation on Micro and Nanoscale Iron Particles

The article presents a detailed study and characterization of the oxide layers on the surface of iron particles of various sizes. Ten iron samples with a size range from a few nm to 50 µm were studied in detail using SEM, TEM, XRD, and TGA analysis. The composition of the multiphase oxide layers on the powder surface was investigated. The main components of the oxide layer were FeO, Fe3O4, and Fe2O3. By the obtained data, a model for the calculation of a multiphase oxide layer thickness on the surface of iron particles was proposed. The proposed model was validated and can be used for the characterization and certification of micro– and nanoscale iron particles