105 research outputs found

    Ionization-induced asymmetric self-phase modulation and universal modulational instability in gas-filled hollow-core photonic crystal fibers

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    We study theoretically the propagation of relatively long pulses with ionizing intensities in a hollow-core photonic crystal fiber filled with a Raman-inactive gas. Due to photoionization, previously unknown types of asymmetric self-phase modulation and `universal' modulational instabilities existing in both normal and anomalous dispersion regions appear. We also show that it is possible to spontaneously generate a plasma-induced continuum of blueshifting solitons, opening up new possibilities for pushing supercontinuum generation towards shorter and shorter wavelengths.Comment: 5 pages, 4 figure

    ACCURACY EVALUATIONOF THE NONLINEAR STATIC ANALYSIS METHOD OF THE STRUCTURES SEISMIC RESISTANCE

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    The article considers the practical application of a technique of nonlinear static analysis of seismic resistance of buildings and structures. The calculation of one-storey steel frame, by nonlinear static and nonlinear dynamic methodsis fulfiled. As a result of analysis of the calcu- lation, results show the importance of higher vibration modes and the need to analyze their effects on the system respons

    Effects of the Carbon Support Doping with Nitrogen for the Hydrogen Production from Formic Acid over Ni Catalysts

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    Porous nitrogen-doped and nitrogen-free carbon materials possessing high specific surface areas (400–1000 m2 g−1) were used for deposition of Ni by impregnation with nickel acetate followed by reduction. The nitrogen-doped materials synthesized by decomposition of acetonitrile at 973, 1073, and 1173 K did not differ much in the total content of incorporated nitrogen (4–5 at%), but differed in the ratio of the chemical forms of nitrogen. An X-ray photoelectron spectroscopy study showed that the rise in the synthesis temperature led to a strong growth of the content of graphitic nitrogen on the support accompanied by a reduction of the content of pyrrolic nitrogen. The content of pyridinic nitrogen did not change significantly. The prepared nickel catalysts supported on nitrogen-doped carbons showed by a factor of up to two higher conversion of formic acid as compared to that of the nickel catalyst supported on the nitrogen-free carbon. This was related to stabilization of Ni in the state of single Ni2+ cations or a few atoms clusters by the pyridinic nitrogen sites. The nitrogen-doped nickel catalysts possessed a high stability in the reaction at least within 5 h and a high selectivity to hydrogen (97%)
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