Canonical Discretization. I. Discrete faces of (an)harmonic oscillator

A certain notion of canonical equivalence in quantum mechanics is proposed. It is used to relate quantal systems with discrete ones. Discrete systems canonically equivalent to the celebrated harmonic oscillator as well as the quartic and the quasi-exactly-solvable anharmonic oscillators are found. They can be viewed as a translation-covariant discretization of the (an)harmonic oscillator preserving isospectrality. The notion of the $q-$deformation of the canonical equivalence leading to a dilatation-covariant discretization preserving polynomiality of eigenfunctions is also presented.Comment: 29 pages, LaTe

One-electron atomic-molecular ions containing Lithium in a strong magnetic field

The one-electron Li-containing Coulomb systems of atomic type $(li, e)$ and molecular type $(li, li, e)$, $(li, \alpha, e)$ and $(li, p, e)$ are studied in the presence of a strong magnetic field $B \leq 10^{7}$ a.u. in the non-relativistic framework. They are considered at the Born-Oppenheimer approximation of zero order (infinitely massive centers) within the parallel configuration (molecular axis parallel to the magnetic field). The variational and Lagrange-mesh methods are employed in complement to each other. It is demonstrated that the molecular systems ${\rm LiH}^{3+}$, ${\rm LiHe}^{4+}$ and ${\rm Li}_{2}^{5+}$ can exist for sufficiently strong magnetic fields $B \gtrsim 10^{4}$ a.u. and that ${\rm Li}_{2}^{5+}$ can even be stable at magnetic fields typical of magnetars.Comment: 22 pages, 9 figures, 4 table

On polynomial solutions of differential equations

A general method of obtaining linear differential equations having polynomial solutions is proposed. The method is based on an equivalence of the spectral problem for an element of the universal enveloping algebra of some Lie algebra in the "projectivized" representation possessing an invariant subspace and the spectral problem for a certain linear differential operator with variable coefficients. It is shown in general that polynomial solutions of partial differential equations occur; in the case of Lie superalgebras there are polynomial solutions of some matrix differential equations, quantum algebras give rise to polynomial solutions of finite--difference equations. Particularly, known classical orthogonal polynomials will appear when considering $SL(2,{\bf R})$ acting on ${\bf RP_1}$. As examples, some polynomials connected to projectivized representations of $sl_2 ({\bf R})$, $sl_2 ({\bf R})_q$, $osp(2,2)$ and $so_3$ are briefly discussed.Comment: 12p

Particular Integrability and (Quasi)-exact-solvability

A notion of a particular integrability is introduced when two operators commute on a subspace of the space where they act. Particular integrals for one-dimensional (quasi)-exactly-solvable Schroedinger operators and Calogero-Sutherland Hamiltonians for all roots are found. In the classical case some special trajectories for which the corresponding particular constants of motion appear are indicated.Comment: 13 pages, typos correcte

The HeH+HeH^+ molecular ion in a magnetic field

A detailed study of the low-lying electronic states {}^1\Si,{}^3\Si,{}^3\Pi,{}^3\De of the $\rm{HeH}^+$ molecular ion in parallel to a magnetic field configuration (when \al-particle and proton are situated on the same magnetic line) is carried out for $B=0-4.414\times 10^{13}$ G in the Born-Oppenheimer approximation. The variational method is employed using a physically adequate trial function. It is shown that the parallel configuration is stable with respect to small deviations for \Si-states. The quantum numbers of the ground state depend on the magnetic field strength. The ground state evolves from the spin-singlet {}^1\Si state for small magnetic fields $B\lesssim 0.5$ a.u. to the spin-triplet {}^3\Si unbound state for intermediate fields and to the spin-triplet strongly bound $^3\Pi$ state for $B \gtrsim 15$ a.u. When the $\rm{HeH}^+$ molecular ion exists, it is stable with respect to a dissociation.Comment: 13 pages, 5 figures, 4 table

A note about the ground state of the H3+{\rm H}_3^+ hydrogen molecular ion

Three simple $7-, (7+3)-, 10-$parametric trial functions for the ${\rm H}_3^+$ molecular ion are presented. Each of them provides subsequently the most accurate approximation for the Born-Oppenheimer ground state energy among several-parametric trial functions. These trial functions are chosen following a criterion of physical adequacy and includes the electronic correlation in the exponential form $\sim\exp{(\gamma r_{12})}$, where $\gamma$ is a variational parameter. The Born-Oppenheimer energy is found to be $E=-1.340 34, -1.340 73, -1.341 59$\,a.u., respectively, for optimal equilateral triangular configuration of protons with the equilibrium interproton distance $R=1.65$\,a.u. The variational energy agrees in three significant digits (s.d.) with most accurate results available at present as well as for major expectation values.Comment: 12 pages, 1 figure, 3 table

Two electrons in an external oscillator potential: hidden algebraic structure

It is shown that the Coulomb correlation problem for a system of two electrons (two charged particles) in an external oscillator potential possesses a hidden $sl_2$-algebraic structure being one of recently-discovered quasi-exactly-solvable problems. The origin of existing exact solutions to this problem, recently discovered by several authors, is explained. A degeneracy of energies in electron-electron and electron-positron correlation problems is found. It manifests the first appearence of hidden $sl_2$-algebraic structure in atomic physics.Comment: 7 pages (plus one figure avaliable via direct request), LaTeX, Preprint IFUNAM FT 94-4

H3++H_3^{++} molecular ions can exist in strong magnetic fields

Using the variational method it is shown that for magnetic fields $B\geq 10^{11}$ G there can exist a molecular ion $H_3^{++}$.Comment: LaTeX, 7 pp, 1 table, 4 figures. Title modified. Consideration of the longitudinal size of the system was adde

Energy Reflection Symmetry of Lie-Algebraic Problems: Where the Quasiclassical and Weak Coupling Expansions Meet

We construct a class of one-dimensional Lie-algebraic problems based on sl(2) where the spectrum in the algebraic sector has a dynamical symmetry E -> - E. All 2j+1 eigenfunctions in the algebraic sector are paired, and inside each pair are related to each other by simple analytic continuation x -> ix, except the zero mode appearing if j is integer. At j-> infinity the energy of the highest level in the algebraic sector can be calculated by virtue of the quasiclassical expansion, while the energy of the ground state can be calculated as a weak coupling expansion. The both series coincide identically.Comment: Latex, 16 pages, 3 figures. Minor styllistic changes made, typos corrected, a remark on the energy-reflection symmetry in the quantum-algebraic Hamiltonians emerging in finite-difference problems added. Final version, to be published in Physical Review

The H2+_2^+ molecular ion: a solution

Combining the WKB expansion at large distances and Perturbation Theory at small distances it is constructed a compact uniform approximation for eigenfunctions. For lowest states 1s\si_{g} and 2p\si_{u} this approximation provides the relative accuracy $\lesssim 10^{-5}$ (5 s.d.) for any real $x$ in eigenfunctions and for total energy $E(R)$ it gives 10-11 s.d. for internuclear distances $R \in [0,50]$. Corrections to proposed approximations are evaluated. Separation constants and the oscillator strength for the transition 1s\si_{g} \rar 2p\si_{u} are calculated and compared with existing data.Comment: 16 pages, 4 figures, 6 tables, typos are corrected and small additions are inserted, to be published at JPB (fast track comm