295 research outputs found

    Genome sequence of Acetomicrobium hydrogeniformans OS1

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    Acetomicrobium hydrogeniformans, an obligate anaerobe of the phylum Synergistetes, was isolated from oil production water. It has the unusual ability to produce almost 4 molecules H2/molecule glucose. The draft genome of A. hydrogeniformans OS1 (DSM 22491T) is 2,123,925 bp, with 2,068 coding sequences and 60 RNA genes

    DNA-Linker-Induced Surface Assembly of Ultra Dense Parallel Single Walled Carbon Nanotube Arrays

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    Ultrathin film preparations of single-walled carbon nanotube (SWNT) allow economical utilization of nanotube properties in electronics applications. Recent advances have enabled production of micrometer scale SWNT transistors and sensors but scaling these devices down to the nanoscale, and improving the coupling of SWNTs to other nanoscale components, may require techniques that can generate a greater degree of nanoscale geometric order than has thus far been achieved. Here, we introduce linker-induced surface assembly, a new technique that uses small structured DNA linkers to assemble solution dispersed nanotubes into parallel arrays on charged surfaces. Parts of our linkers act as spacers to precisely control the internanotube separation distance down to <3 nm and can serve as scaffolds to position components such as proteins between adjacent parallel nanotubes. The resulting arrays can then be stamped onto other substrates. Our results demonstrate a new paradigm for the self-assembly of anisotropic colloidal nanomaterials into ordered structures and provide a potentially simple, low cost, and scalable route for preparation of exquisitely structured parallel SWNT films with applications in high-performance nanoscale switches, sensors, and meta-materials

    Optically triggered Q-switched photonic crystal laser

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    An optically triggered liquid crystal infiltrated Q-switched photonic crystal laser is demonstrated. A photonic crystal laser cavity was designed and fabricated to support two orthogonally polarized high-Q cavity modes after liquid crystal infiltration. By controlling the liquid crystal orientation via a layer of photoaddressable polymer and a writing laser, the photonic crystal lasing mode can be reversibly switched between the two modes which also switches the laser’s emission polarization and wavelength. The creation of the Q-switched laser demonstrates the benefits of customizing photonic crystal cavities to maximally synergize with an infiltrated material and illustrates the potential of integrating semiconductor nanophotonics with optical materials

    Self-assembly of carbon nanotubes into two-dimensional geometries using DNA origami templates

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    A central challenge in nanotechnology is the parallel fabrication of complex geometries for nanodevices. Here we report a general method for arranging single-walled carbon nanotubes in two dimensions using DNA origami—a technique in which a long single strand of DNA is folded into a predetermined shape. We synthesize rectangular origami templates (~75 nm × 95 nm) that display two lines of single-stranded DNA ‘hooks’ in a cross pattern with ~6 nm resolution. The perpendicular lines of hooks serve as sequence-specific binding sites for two types of nanotubes, each functionalized non-covalently with a distinct DNA linker molecule. The hook-binding domain of each linker is protected to ensure efficient hybridization. When origami templates and DNA-functionalized nanotubes are mixed, strand displacement-mediated deprotection and binding aligns the nanotubes into cross-junctions. Of several cross-junctions synthesized by this method, one demonstrated stable field-effect transistor-like behaviour. In such organizations of electronic components, DNA origami serves as a programmable nanobreadboard; thus, DNA origami may allow the rapid prototyping of complex nanotube-based structures

    Valley-spin blockade and spin resonance in carbon nanotubes

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    Manipulation and readout of spin qubits in quantum dots made in III-V materials successfully rely on Pauli blockade that forbids transitions between spin-triplet and spin-singlet states. Quantum dots in group IV materials have the advantage of avoiding decoherence from the hyperfine interaction by purifying them with only zero-spin nuclei. Complications of group IV materials arise from the valley degeneracies in the electronic bandstructure. These lead to complicated multiplet states even for two-electron quantum dots thereby significantly weakening the selection rules for Pauli blockade. Only recently have spin qubits been realized in silicon devices where the valley degeneracy is lifted by strain and spatial confinement. In carbon nanotubes Pauli blockade can be observed by lifting valley degeneracy through disorder. In clean nanotubes, quantum dots have to be made ultra-small to obtain a large energy difference between the relevant multiplet states. Here we report on low-disorder nanotubes and demonstrate Pauli blockade based on both valley and spin selection rules. We exploit the bandgap of the nanotube to obtain a large level spacing and thereby a robust blockade. Single-electron spin resonance is detected using the blockade.Comment: 31 pages including supplementary informatio

    Fast Ion Conduction of Sintered Glass-Ceramic Lithium Ion Conductors Investigated by Impedance Spectroscopy and Coaxial Reflection Technique

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    As the ionic conductivity of solid-state lithium ion conductors rises, knowledge of the detailed conductivity mechanisms is harder to obtain due to the limited frequency resolution of the traditional impedance spectrometers. Moreover, the data is easily affected by the local microstructure (i.e. pores, grain-boundaries) and the preparation conditions. The aim of this work is to demonstrate the feasibility of the coaxial reflection technique as a reliable tool to study fast ionic conductors (i.e. σ > 10⁻⁴ S cm⁻¹). Especially the relative permittivity can be determined more accurately at room temperature. For the first time the electrical performance of LATP and LLZO manufactured via a scalable top-down glass-ceramic route is evaluated. The density turns out to be a key parameter influencing both relative permittivity and resulting conductivities. For a 100% dense LATP sample the coaxial reflection technique reveals a high grain-core conductivity of 6 × 10⁻³ S cm⁻¹ similar to the conductivity of ideal single crystals

    An addressable quantum dot qubit with fault-tolerant control fidelity

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    Exciting progress towards spin-based quantum computing has recently been made with qubits realized using nitrogen-vacancy (N-V) centers in diamond and phosphorus atoms in silicon, including the demonstration of long coherence times made possible by the presence of spin-free isotopes of carbon and silicon. However, despite promising single-atom nanotechnologies, there remain substantial challenges in coupling such qubits and addressing them individually. Conversely, lithographically defined quantum dots have an exchange coupling that can be precisely engineered, but strong coupling to noise has severely limited their dephasing times and control fidelities. Here we combine the best aspects of both spin qubit schemes and demonstrate a gate-addressable quantum dot qubit in isotopically engineered silicon with a control fidelity of 99.6%, obtained via Clifford based randomized benchmarking and consistent with that required for fault-tolerant quantum computing. This qubit has orders of magnitude improved coherence times compared with other quantum dot qubits, with T_2* = 120 mus and T_2 = 28 ms. By gate-voltage tuning of the electron g*-factor, we can Stark shift the electron spin resonance (ESR) frequency by more than 3000 times the 2.4 kHz ESR linewidth, providing a direct path to large-scale arrays of addressable high-fidelity qubits that are compatible with existing manufacturing technologies

    Dispersively detected Pauli Spin-Blockade in a Silicon Nanowire Field-Effect Transistor

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    We report the dispersive readout of the spin state of a double quantum dot formed at the corner states of a silicon nanowire field-effect transistor. Two face-to-face top-gate electrodes allow us to independently tune the charge occupation of the quantum dot system down to the few-electron limit. We measure the charge stability of the double quantum dot in DC transport as well as dispersively via in-situ gate-based radio frequency reflectometry, where one top-gate electrode is connected to a resonator. The latter removes the need for external charge sensors in quantum computing architectures and provides a compact way to readout the dispersive shift caused by changes in the quantum capacitance during interdot charge transitions. Here, we observe Pauli spin-blockade in the high-frequency response of the circuit at finite magnetic fields between singlet and triplet states. The blockade is lifted at higher magnetic fields when intra-dot triplet states become the ground state configuration. A lineshape analysis of the dispersive phase shift reveals furthermore an intradot valley-orbit splitting Δvo\Delta_{vo} of 145 μ\mueV. Our results open up the possibility to operate compact CMOS technology as a singlet-triplet qubit and make split-gate silicon nanowire architectures an ideal candidate for the study of spin dynamics

    Who goes there? Social surveillance as a response to intergroup conflict in a primitive termite

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    This is the final version. Available on open access from the Royal Society via the DOI in this recordIntergroup conflict has been suggested as a major force shaping the evolution of social behaviour in animal groups. A long-standing hypothesis is that groups at risk of attack by rivals should become more socially cohesive, to increase resilience or protect against future attack. However, it is usually unclear how cohesive behaviours (such as grooming or social contacts) function in intergroup conflict. We performed an experiment in which we exposed young colonies of the dampwood termite, Zootermopsis angusticollis, to a rival colony while preventing physical combat with a permeable barrier. We measured social contacts, allogrooming, and trophallaxis before, during, and after exposure. Termites showed elevated rates of social contacts during exposure to a rival compared to the pre-exposure phase, but rates returned to pre-exposure levels after colonies were separated for nine days. There was evidence of a delayed effect of conflict on worker trophallaxis. We suggest that social contacts during intergroup conflict function as a form of social surveillance, to check individual identity and assess colony resource holding potential. Intergroup conflict may increase social cohesion in both the short and the long term, improving the effectiveness of groups in competition.Natural Environment Research Council (NERC
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