Probing the geometry and motion of AGN coronae through accretion disc emissivity profiles

To gain a better understanding of the inner disc region that comprises active galactic nuclei it is necessary to understand the pattern in which the disc is illuminated (the emissivity profile) by X-rays emitted from the continuum source above the black hole (corona). The differences in the emissivity profiles produced by various corona geometries are explored via general relativistic ray tracing simulations. Through the analysis of various parameters of the geometries simulated it is found that emissivity profiles produced by point source and extended geometries such as cylindrical slabs and spheroidal coronae placed on the accretion disc are distinguishable. Profiles produced by point source and conical geometries are not significantly different, requiring an analysis of reflection fraction to differentiate the two geometries. Beamed point and beamed conical sources are also simulated in an effort to model jet-like coronae, though the differences here are most evident in the reflection fraction. For a point source we determine an approximation for the measured reflection fraction with the source height and velocity. Simulating spectra from the emissivity profiles produced by the various geometries produce distinguishable differences. Overall spectral differences between the geometries do not exceed 15 per cent in the most extreme cases. It is found that emissivity profiles can be useful in distinguishing point source and extended geometries given high quality spectral data of extreme, bright sources over long exposure times. In combination with reflection fraction, timing, and spectral analysis we may use emissivity profiles to discern the geometry of the X-ray source.Comment: 15 pages, 12 figures. Accepted for publication in MNRA

Synthesis, characterisation and biological activity of gold(III) catecholate and related complexes

The reactions of the cyclometallated gold(III) complexes [LAuCl₂] [L=2-(dimethylaminomethyl)phenyl, 2-benzylpyridyl or 2-anilinopyridyl] with catechol, tetrachlorocatechol, or the cyclic α,β-diketone SCH(CO2Et)C(O)C(O)CH(CO2Et) give stable complexes containing five-membered Au-O-C-C-O rings. These represent the first examples of well-characterised gold(III) catecholate complexes. Similarly, reactions with 2-acetamidophenol [HOC₆H₄NHC(O)CH₃] give complexes with the related Au---N---C---C---O ring. The complexes were characterised by NMR spectroscopy, electrospray ionisation mass spectrometry, elemental microanalysis, and in the case of the complex [(2-benzylpyridyl)Au{OC₆H₄NC(O)CH₃}] by an X-ray crystal structure determination. Several complexes show high activity towards P388 murine leukemia cells

Caught in the act: Measuring the changes in the corona that cause the extreme variability of 1H 0707-495

The X-ray spectra of the narrow line Seyfert 1 galaxy, 1H 0707-495, obtained with XMM-Newton, from time periods of varying X-ray luminosity are analysed in the context of understanding the changes to the X-ray emitting corona that lead to the extreme variability seen in the X-ray emission from active galactic nuclei (AGN). The emissivity profile of the accretion disc, illuminated by the X-ray emitting corona, along with previous measurements of reverberation time lags are used to infer the spatial extent of the X-ray source. By fitting a twice-broken power law emissivity profile to the relativistically-broadened iron K fluorescence line, it is inferred that the X-ray emitting corona expands radially, over the plane of the accretion disc, by 25 to 30 per cent as the luminosity increases, contracting again as the luminosity decreases, while increases in the measured reverberation lag as the luminosity increases would require also variation in the vertical extent of the source above the disc. The spectrum of the X-ray continuum is found to soften as the total X-ray luminosity increases and we explore the variation in reflected flux as a function of directly-observed continuum flux. These three observations combined with simple, first-principles models constructed from ray tracing simulations of extended coron self-consistently portray an expanding corona whose average energy density decreases, but with a greater number of scattering particles as the luminosity of this extreme object increases.Comment: 12 pages, 4 figures. Accepted for publication in MNRA

Novel six-coordinate Aryl- and Alkyltin complexes

Organo-tin compounds have wide applications as pesticides and as intermediates for organic synthesis.¹ They are invariably Sn(IV) derivatives and are generally four-coordinate.² The mixed organo/chioro compounds of the type RnSnCI4-n do however have the ability to expand their coordination numbers to five or six. This depends critically on the substituents - with four organic groups, R₄Sn, there is no tendency at all to coordinate extra ligands, while at the other extreme SnCl₄ readily forms six-coordinate [SnC1₄L₂] complexes since the electronegative halo groups increase the Lewis acidity of the tin centre

Management of the Rice Tungro Virus Vector \u3ci\u3eNephotettix virescens\u3c/i\u3e (Homoptera: Cicadellidae) with Controlled-Release Formulations of Carbofuran

Field trials were conducted in lowland flooded rice in the Philippines to evaluate a number of carbofuran controlled-release formulations in comparison with commercial formulations. The test formulations were based on a biodegradable matrix of pine kraft lignin and were used as granules of different sizes and also in the form of small strips. The release rates were assessed under field conditions by bioassaying rice plants in the field, using adult rice green leafhopper, Nephotettix virescens Distant. The lignin formulations with a high level of active ingredient (15–45% by weight) gave as good or better control than the commercial 3% granules in tests based on three application techniques: broadcast into the floodwater, soil incorporation, and root zone injection. The improvements in control levels of green leafhoppers were most marked with soil incorporation and root zone application. The best lignin-based formulation reduced levels of tungro virus infection from 23% for a conventional flowable carbofuran formulation to 1.0% at an application rate of 0.5 kg (AI)/ha. At the same rate, the grain yield was increased from 3.56 t/ha to 5.5 t/ha, using the controlled-released formulation

Effects of morphology on phonons of nanoscopic silver grains

The morphology of nanoscopic Ag grains significantly affects the phonons. Atomistic simulations show that realistic nanograin models display complex vibrational properties. (1) Single-crystalline grains. Nearly-pure torsional and radial phonons appear at low frequencies. For low-energy, faceted models, the breathing mode and acoustic gap (lowest frequency) are about 10% lower than predicted by elasticity theory (ET) for a continuum sphere of the same volume. The sharp edges and the atomic lattice split the ET-acoustic-gap quintet into a doublet and triplet. The surface protrusions associated with nearly spherical, high-energy models produce a smaller acoustic gap and a higher vibrational density of states (DOS) at frequencies \nu<2 THz. (2) Twined icosahedra. In contrast to the single-crystal case, the inherent strain produce a larger acoustic gap, while the core atoms yield a DOS tail extending beyond the highest frequency of single-crystalline grains. (3) Mark's decahedra, in contrast to (1) and (2), do not have a breathing mode; although twined and strained, do not exhibit a high-frequency tail in the DOS. (4) Irregular nanograins. Grain boundaries and surface disorder yield non-degenerate phonon frequencies, and significantly smaller acoustic gap. Only these nanograins exhibit a low-frequency \nu^2 DOS in the interval 1-2 THz.Comment: Version published in Phys. Rev.

Scaling study of Si/SiGe MODFETs for RF applications

Based on the successful calibration on a 0.25 /spl mu/m strained Si/SiGe n-type MODFET, this paper presents a gate length scaling study of double-side doped Si/SiGe MODFETs. Our simulations show that gate length scaling improves device RF performance. However, the short channel effects (SCE) along with the parasitic delays limit the device performance improvements. We find that it is necessary to consider scaling (dimensions and doping) of both the lateral and vertical architecture in order to optimize the device design

An Apparatus for Measuring the Thermal Conductivity of Cast Insulation Materials

A steady-state apparatus has been developed for measuring the thermal conductivity of cast materials. The design has employed a novel thermal symmetry arrangement which can permit total electrical isolation of the test material from its surroundings. © 1980 American Institute of Physic

Universal zero-bias conductance for the single electron transistor. II: Comparison with numerical results

A numerical renormalization-group survey of the zero-bias electrical conductance through a quantum dot embedded in the conduction path of a nanodevice is reported. The results are examined in the light of a recently derived linear mapping between the temperature-dependent conductance and the universal function describing the conductance for the symmetric Anderson model. A gate potential applied to the conduction electrons is known to change markedly the transport properties of a quantum dot side-coupled to the conduction path; in the embedded geometry here discussed, a similar potential is shown to affect only quantitatively the temperature dependence of the conductance. As expected, in the Kondo regime the numerical results are in excellent agreement with the mapped conductances. In the mixed-valence regime, the mapping describes accurately the low-temperature tail of the conductance. The mapping is shown to provide a unified view of conduction in the single-electron transistor.Comment: Sequel to arXiv:0906.4063. 9 pages with 8 figure