A New Iron Pnictide Oxide (Fe2As2)(Ca5(Mg,Ti)4Oy) and a New Phase in Fe-As-Ca-Mg-Ti-O system

A new layered iron arsenide oxide (Fe2As2)(Ca5(Mg,Ti)4Oy) and its structural derivative were found in the Fe-As-Ca-Mg-Ti-O system. The crystal structure of (Fe2As2)(Ca5(Mg,Ti)4Oy) is identical to that of (Fe2As2)(Ca5(Sc,Ti)4Oy), which was reported in our previous study. The lattice constants of this compound are a = 3.86(4) A and c = 41.05(2) A. In addition, another phase with a thicker blocking layer was found. The structure of the compound and its derivative was tentatively assigned through STEM observation as (Fe2As2)(Ca8(Mg,Ti)6Oy) with sextuple perovskite-type sheets divided by a rock salt layer. The interlayer Fe-Fe distance of this compound is ~30 A. The compound and its derivative exhibited bulk superconductivity, as found from magnetization and resistivity measurements.Comment: 9 pages, 7 figure

Suppression of Magnetic Order by Pressure in BaFe2As2

We performed the dc resistivity and the ZF 75As-NMR measurement of BaFe2As2 under high pressure. The T-P phase diagram of BaFe2As2 determined from resistivity anomalies and the ZF 75As-NMR clearly revealed that the SDW anomaly is quite robust against P.Comment: 2 pages, 2 figure

Uniform Mixing of High-Tc Superconductivity and Antiferromagnetism on a Single CuO2 Plane in Hg-based Five-layered Cuprate

We report a site selective Cu-NMR study on under-doped Hg-based five-layered high-$T_{\rm c}$ cuprate HgBa2Ca4Cu5Oy with a Tc=72 K. Antiferromagnetism (AF) has been found to take place at TN=290 K, exhibiting a large antiferromagnetic moment of 0.67-0.69uB at three inner planes (IP's). This value is comparable to the values reported for non-doped cuprates, suggesting that the IP may be in a nearly non-doped regime. Most surprisingly, the AF order is also detected with M(OP)=0.1uB even at two outer planes (OP's) that are responsible for the onset of superconductivity (SC). The high-Tc SC at Tc = 72 K can uniformly coexist on a microscopic level with the AF at OP's. This is the first microscopic evidence for the uniform mixed phase of AF and SC on a single CuO2 plane in a simple environment without any vortex lattice and/or stripe order.Comment: 4 pages, 4 figures. To be published in Phys.Rev.Let

Microwave Penetration Depth and Quasiparticle Conductivity in PrFeAsO_1-y Single Crystals : Evidence for a Full-Gap Superconductor

In-plane microwave penetration depth $\lambda_{ab}$ and quaiparticle conductivity at 28 GHz are measured in underdoped single crystals of the Fe-based superconductor PrFeAsO$_{1-y}$ ($T_c\approx 35$ K) by using a sensitive superconducting cavity resonator. $\lambda_{ab}(T)$ shows flat dependence at low temperatures, which is incompatible with the presence of nodes in the superconducting gap $\Delta({\bf k})$. The temperature dependence of the superfluid density demonstrates that the gap is non-zero ($\Delta/k_BT_c\gtrsim 1.6$) all over the Fermi surface. The microwave conductivity below $T_c$ exhibits an enhancement larger than the coherence peak, reminiscent of high-$T_c$ cuprate superconductors.Comment: 4 pages, 3 figures. Version accepted for publication in Phys. Rev. Lett. For related results of hole-doped 122 system, see arXiv:0810.350

Planar CuO_2 hole density estimation in multilayered high-T_c cuprates

We report that planar CuO_2 hole densities in high-T_c cuprates are consistently determined by the Cu-NMR Knight shift. In single- and bi-layered cuprates, it is demonstrated that the spin part of the Knight shift K_s(300 K) at room temperature monotonically increases with the hole density $p$ from underdoped to overdoped regions, suggesting that the relationship of K_s(300 K) vs. p is a reliable measure to determine p. The validity of this K_s(300 K)-p relationship is confirmed by the investigation of the p-dependencies of hyperfine magnetic fields and of spin susceptibility for single- and bi-layered cuprates with tetragonal symmetry. Moreover, the analyses are compared with the NMR data on three-layered Ba_2Ca_2Cu_3O_6(F,O)_2, HgBa_2Ca_2Cu_3O_{8+delta}, and five-layered HgBa_2Ca_4Cu_5O_{12+delta}, which suggests the general applicability of the K_s(300 K)-p relationship to multilayered compounds with more than three CuO_2 planes. We remark that the measurement of K_s(300 K) enables us to separately estimate p for each CuO_2 plane in multilayered compounds, where doped hole carriers are inequivalent between outer CuO_2 planes and inner CuO_2 planes.Comment: 7 pages, 5 figures, 2 Tables, to be published in Physical Review

Commensurate Itinerant Antiferromagnetism in BaFe2As2: 75As-NMR Studies on a Self-Flux Grown Single Crystal

We report results of 75As nuclear magnetic resonance (NMR) experiments on a self-flux grown single crystal of BaFe2As2. A first-order antiferromagnetic (AF) transition near 135 K was detected by the splitting of NMR lines, which is accompanied by simultaneous structural transition as evidenced by a sudden large change of the electric field gradient tensor at the As site. The NMR results lead almost uniquely to the stripe spin structure in the AF phase. The data of spin-lattice relaxation rate indicate development of anisotropic spin fluctuations of the stripe-type with decreasing temperature in the paramagnetic phase.Comment: 7 pages, 7 figures, accepted for publication in J. Phys. Soc. Jp