Topological analysis of polymeric melts: Chain length effects and fast-converging estimators for entanglement length

Primitive path analyses of entanglements are performed over a wide range of chain lengths for both bead spring and atomistic polyethylene polymer melts. Estimators for the entanglement length N_e which operate on results for a single chain length N are shown to produce systematic O(1/N) errors. The mathematical roots of these errors are identified as (a) treating chain ends as entanglements and (b) neglecting non-Gaussian corrections to chain and primitive path dimensions. The prefactors for the O(1/N) errors may be large; in general their magnitude depends both on the polymer model and the method used to obtain primitive paths. We propose, derive and test new estimators which eliminate these systematic errors using information obtainable from the variation of entanglement characteristics with chain length. The new estimators produce accurate results for N_e from marginally entangled systems. Formulas based on direct enumeration of entanglements appear to converge faster and are simpler to apply.Comment: Major revisions. Developed near-ideal estimators which operate on multiple chain lengths. Now test these on two very different model polymers

Survey of Ground-Dwelling Predaceous and Parasitic Arthropods in Cabbage Fields in Upstate New York

During 1979 and 1981, populations of ground-dwelling predators and parasites in research and commercial cabbage fields in upstate New York were assessed by pitfall trapping to determine species composition, abundance, phenology, and the impact of insecticides on them. Staphylinidae, Phalangida, Carabidae, and Araneida were consistently the most abundant predaceous taxa. Carabids and Staphylinids together comprised 75.9 and 74.1% of all predaceous or parasitic insects in commercial fields during 1979 and 1981, respectively. One of the 32 species of Carabidae captured, Pterostichus melanarius (Illiger), accounted for >50% of the total number of Carabidae. Total number of predators and parasites tended to decline from July through September in both treated and untreated fields, but this decline was hastened by the use of broad-spectrum insecticide

Difficulties in Laboratory Studies and Astronomical Observations of Organic Molecules: Hydroxyacetone and Lactic Acid

For the past 35 years, radio astronomy has revealed a rich organic chemistry in the interstellar gas, which is exceptionally complex towards active star-forming regions. New solar systems condense out of this gas and may influence the evolution of life on newly formed planets. Much of the biologically important functionality is present among the some 130 gas-phase molecules found to date, including alcohols, aldehydes, ketones, acids, amines, amides and even the simplest sugar - glycolaldehyde. Still, many unidentified interstellar radio signals remain, and their identification relies on further laboratory study. The molecules hydroxyacetone and lactic acid are relatively small organic molecules, but possess rather complex rotational spectra owing to their high asymmetry. Hydroxyacetone is particularly problematic because it possess a very low barrier to internal rotation, and exhibits strong coupling of the free-rotor states with the overall rotation of the molecule. As in the case of acetamide, a full decomposition method was employed to order the resultant eigenstates onto normal asymmetric top eigenvectors

Transition Probabilities for Trichoplusia ni (Lepidoptera: Noctuidae) Larvae on Cabbage as a Function of Microclimate

To identify factors affecting the spatial dynamics of Trichoplusia ni (Hübner) on cabbage, the movements of individual larvae were monitored. Larvae were marked with 32p and released individually, one per plant, on cabbage plants in research plots. Their movements were monitored by recording their position on the plant daily, locating them with a Geiger counter. In the same plots, hourly measurements of temperature and relative humidity were recorded in three different parts of the crop canopy. Transition probabilities for the larvae from and to each of five vertical plant strata were modeled as definite integrals of the Beta probability density function (pdf). The shape parameters for these Beta pdf's were modeled as a function of microclimate, and the necessary parameters to do so were estimated by the method of maximum likelihood. This model predicted the data well and was more efficient than logistic regression. The model predicts that under high temperatures and low vapor pressure deficit (vpd), larvae move down to the shaded, cooler, lower parts of the plant; whereas under low temperatures and high vpd, they moved upward toward the economically important wrapper leaves and cabbage head

Integrating Time Into Family Business Research: Using Random Coefficient Modeling to Examine Temporal Influences on Family Firm Ambidexterity

Organizational ambidexterity refers to a firm’s ability to pursue both exploitation and exploration orientations. Despite research that suggests ambidexterity is a critical phenomenon in family firms, few studies directly examine the role of ambidexterity over time in family business. This study examines how family firm ambidexterity changes over time as a result of temporal-, firm-, and industry-level factors. We find that family firm ambidexterity is stable over time, punctuated by dramatic changes. We also find that the level of innovation required to compete in an industry is a predictor of changes in exploration versus exploitation over time among family firms.Yeshttps://us.sagepub.com/en-us/nam/manuscript-submission-guideline

Use of the Global Alliance for Musculoskeletal Health survey module for estimating the population prevalence of musculoskeletal pain: Findings from the Solomon Islands

Background: Musculoskeletal (MSK) conditions are common and the biggest global cause of physical disability. The objective of the current study was to estimate the population prevalence of MSK-related pain using a standardized global MSK survey module for the first time. Methods: A MSK survey module was constructed by the Global Alliance for Musculoskeletal Health Surveillance Taskforce and the Global Burden of Disease MSK Expert Group. The MSK module was included in the 2015 Solomon Islands Demographic and Health Survey. The sampling design was a two-stage stratified, nationally representative sample of households. Results: A total of 9214 participants aged 15-49 years were included in the analysis. The age-standardized four-week prevalence of activity-limiting low back pain, neck pain, and hip and/or knee pain was 16.8, 8.9, and 10.8%, respectively. Prevalence tended to increase with age, and be higher in those with lower levels of education. Conclusions: Prevalence of activity-limited pain was high in all measured MSK sites. This indicates an important public health issue for the Solomon Islands that needs to be addressed. Efforts should be underpinned by integration with strategies for other non-communicable diseases, aging, disability, and rehabilitation, and with other sectors such as social services, education, industry, and agriculture. Primary prevention strategies and strategies aimed at self-management are likely to have the greatest and most cost-effective impact

A qualitative study of the experiences and perceptions of adults with chronic musculoskeletal conditions following a 12-week Pilates exercise programme

Introduction The aim of the present study was to explore the experiences and perceptions of adult patients with chronic musculoskeletal conditions following a Pilates exercise programme. A qualitative approach was taken to both data collection and analysis, with alignment to the philosophy of interpretive phenomenology. Participants included 15 women and seven men with a range of chronic musculoskeletal conditions, including nonspecific low back pain, peripheral joint osteoarthritis and a range of postsurgical conditions. The age range was from 36 years to 83 years, and the mean age was 57 years (standard deviation 14.1 years). Methods Data were collected via digital recordings of four focus groups in three North‐West of England physiotherapy clinics. The data were transcribed verbatim and then analysed using a thematic framework. Data were verified by a researcher and randomly selected participants, and agreement was achieved between all parties. Results The results were organized into five main themes: physical improvements; Pilates promotes an active lifestyle: improved performance at work and hobbies; psychosocial benefits and improved confidence; increased autonomy in managing their own condition; and motivation to continue with exercise. Conclusion The study was the first to investigate individual perceptions of the impact of Pilates on the daily lives of people with chronic conditions. The Pilates‐based exercise programme enabled the participants to function better and manage their condition more effectively and independently. Further to previous work, the study revealed psychological and social benefits which increase motivation to adhere to the programme and promote a healthier lifestyle

Effect of Intraplant Insect Movement on Economic Thresholds

A simulation model was constructed to examine the effects of intraplant spatial dynamics of the lepidopteran pest complex of cabbage on direct damage to the marketable parts of the plant. Diurnal fluctuations in microclimate for different parts of the crop canopy were simulated with sine functions. Larval development rates for each species were simulated with logistic functions of temperature, the development process with time-varying distributed delays, and feeding rates with exponential functions of temperature and larval age. Larval transition probabilities within the crop canopy were modeled with either constants or definite integrals of the Beta probability density function, the shape parameters of which were modeled as functions of temperature. The model provided a good fit to data on changes in intraplant distribution of these larvae and intraplant distribution of feeding damage. Evaluation of model predictions suggests that a threshold population density used for management decisions should not be static, but should be a complex function of species, larval age distribution, and forecast temperatures. A model like the one presented here could serve as that complex functio

Strain Hardening of Polymer Glasses: Entanglements, Energetics, and Plasticity

Simulations are used to examine the microscopic origins of strain hardening in polymer glasses. While stress-strain curves for a wide range of temperature can be fit to the functional form predicted by entropic network models, many other results are fundamentally inconsistent with the physical picture underlying these models. Stresses are too large to be entropic and have the wrong trend with temperature. The most dramatic hardening at large strains reflects increases in energy as chains are pulled taut between entanglements rather than a change in entropy. A weak entropic stress is only observed in shape recovery of deformed samples when heated above the glass transition. While short chains do not form an entangled network, they exhibit partial shape recovery, orientation, and strain hardening. Stresses for all chain lengths collapse when plotted against a microscopic measure of chain stretching rather than the macroscopic stretch. The thermal contribution to the stress is directly proportional to the rate of plasticity as measured by breaking and reforming of interchain bonds. These observations suggest that the correct microscopic theory of strain hardening should be based on glassy state physics rather than rubber elasticity.Comment: 15 pages, 12 figures: significant revision

Fabrication and Properties of an Anisotropic TiO 2 Dielectric Composite

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/65849/1/j.1551-2916.2006.01134.x.pd