Synthesis of High-Quality AgSbSe2 and AgBiSe2 Nanocrystals with Antimony and Bismuth Silylamide Reagents

Silver dimetal chalcogenides (Ag-V-VI2) are ternary semiconductors that have potential alternative energy applications due to their optimal band gaps and large extinction coefficients. The synthesis of these materials is challenging due to the lack of effective pnictide precursors. We report the use of tris[N,N-bis(trimethylsily)amido]antimony (Sb [N(SiMe3)(2)](3)) and tris [N,N-bis (trimethylsilyl) amido]bis-muth (Bi[(N(SiMe3)(2)](3)) to synthesize nanocrystalline AgSbSe2 and AgBiSe2 quantum dots. The use of these reagents results in the creation of high quality nanomaterials with good crystallinity and narrow size distributions. Furthermore, electrical measurements on monolithic pellets of processed AgSbSe2 and AgBiSe2 nanomaterials demonstrate linear current voltage behavior at room temperature, which indicates potential for use in electrical applications

Sex- And age-specific normal values for automated quantitative pixel-wise myocardial perfusion cardiovascular magnetic resonance

Aims Recently developed in-line automated cardiovascular magnetic resonance (CMR) myocardial perfusion mapping has been shown to be reproducible and comparable with positron emission tomography (PET), and can be easily integrated into clinical workflows. Bringing quantitative myocardial perfusion CMR into routine clinical care requires knowledge of sex- and age-specific normal values in order to define thresholds for disease detection. This study aimed to establish sex- and age-specific normal values for stress and rest CMR myocardial blood flow (MBF) in healthy volunteers. Methods and results A total of 151 healthy volunteers recruited from two centres underwent adenosine stress and rest myocardial perfusion CMR. In-line automatic reconstruction and post processing of perfusion data were implemented within the Gadgetron software framework, creating pixel-wise perfusion maps. Rest and stress MBF were measured, deriving myocardial perfusion reserve (MPR) and were subdivided by sex and age. Mean MBF in all subjects was 0.62 ± 0.13 mL/g/min at rest and 2.24 ± 0.53 mL/g/min during stress. Mean MPR was 3.74 ± 1.00. Compared with males, females had higher rest (0.69 ± 0.13 vs. 0.58 ± 0.12 mL/g/min, P < 0.01) and stress MBF (2.41 ± 0.47 vs. 2.13 ± 0.54 mL/g/min, P = 0.001). Stress MBF and MPR showed significant negative correlations with increasing age (r = −0.43, P < 0.001 and r = −0.34, P < 0.001, respectively). Conclusion Fully automated in-line CMR myocardial perfusion mapping produces similar normal values to the published CMR and PET literature. There is a significant increase in rest and stress MBF, but not MPR, in females and a reduction of stress MBF and MPR with advancing age, advocating the use of sex- and age-specific reference ranges for diagnostic use